US4107218A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Decoloration of bisphenol-A recycle stream with cation exchange resin
Assignee: Chiyoda Corp
•
Filing: 1977-05-06
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Granted: 1978-08-15
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Expires: 1997-05-06
Abstract
Abstract All or part of bisphenol-A process mother liquor recycle stream is contacted with acidic cation exchange resin to remove color bodies. The acidic cation exchange resin is periodically washed and reactivated after use by a mixed phenol/water wash.
Inventors
- 👤 Frederick Miller Konrad
- 👤 Stephen Howard Mason
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 01:05
CPC Classifications
C; C07; C07C; C07C39/00; C07C39/12; C07C39/15; C07C39/16
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
176 words
A process for removing color bodies from 4,4'-bisphenol-A process recycle stream wherein a stoichiometric excess of phenol is reacted with acetone in a reaction mixture containing an acid catalyst to produce a product mixture containing phenol and 4,4'-bisphenol-A, wherein said product mixture is separated into a 4,4'-bisphenol-A/phenol adduct and a mother liquor recycle stream, wherein said mother liquor recycle stream is recycled to said reaction mixture, wherein at least a portion of said mother liquor recycle stream is contacted with an adsorbent comprising a substantially insoluble acidic cationic exchange resin for a period of time and at a temperature sufficient to reduce the content of color bodies contained in said mother liquor recycle stream, said temperature being within the range of from about 40° to about 150° C., prior to recycling said mother liquor to said reaction mixture, wherein said absorbent is periodically washed with a phenol/water mixture to remove absorbed color bodies therefrom, and wherein the water content of said absorbent is substantially in equilibrium with the water content of said mother liquor recycle stream.
Claim 2
Dependent Claim
176 words
A process for removing color bodies from 4,4'-bisphenol-A process recycle stream wherein a stoichiometric excess of phenol is reacted with acetone in a reaction mixture containing an acid catalyst to produce a product mixture containing phenol and 4,4'-bisphenol-A, wherein said product mixture is separated into a 4,4'-bisphenol-A/phenol adduct and a mother liquor recycle stream, wherein said mother liquor recycle stream is recycled to said reaction mixture, wherein at least a portion of said mother liquor recycle stream is contacted with an adsorbent comprising a substantially insoluble acidic cationic exchange resin for a period of time and at a temperature sufficient to reduce the content of color bodies contained in said mother liquor recycle stream, said temperature being within the range of from about 40° to about 150° C., prior to recycling said mother liquor to said reaction mixture, wherein said absorbent is periodically washed with a phenol/water mixture to remove absorbed color bodies therefrom, and wherein the water content of said absorbent is substantially in equilibrium with the water content of said mother liquor recycle stream.
Claim 3
Dependent Claim
19 words
The process of claim 1 wherein the phenol/water mixture contains from about 2 to about 70 weight percent water.
Claim 4
Dependent Claim
19 words
The process of claim 1 wherein the phenol/water mixture contains from about 20 to about 50 weight percent water.
Claim 5
Dependent Claim
19 words
The process of claim 1 wherein the phenol/water mixture contains from about 20 to about 30 weight percent water.
References Cited (Backward Citations)
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Cited
US2911363A
Cited
US3049568A
Cited
US3049569A
Cited
US3221061A
Cited
US3896006A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-08-14 | 1982-02-13 | 1982-08-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-08-14 | 1986-02-13 | 1986-08-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-08-14 | 1990-02-13 | 1990-08-15 | $7700.00 | Window Closed / Lapsed |