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Heteryl-azo-phenyl disperse dyestuffs containing a z-substituted benzolyloxyalkyl radical, wherein z is 2-cyanovinyl 2-cyanoethyl or 2-chloro-2-cyanoethyl

Assignee: Produits Chimiques Ugine Kuhlmann
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Filing: 1976-04-27
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Granted: 1978-08-08
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Expires: 1996-04-27
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Abstract

Abstract A dyestuff of the formula: ##STR1## in which A is thiazolyl, isothiazolyl, benzothiazolyl, benzisothiazolyl, thiadiazolyl, thienyl, or imidazolyl which is unsubstituted or substituted by one to three substituents selected from chlorine, bromine, methyl, phenyl, nitro, cyano, thiocyano, acetyl, carbalkoxy containing 2 to 5 carbon atoms and alkylsulfonyl containing 1 to 4 carbon atoms; X is hydrogen, chlorine, methyl, ethyl, methoxy, ethoxy, formylamino, acetylamino, propanoylamino, benzoylamino or cinnamoylamino; Y is hydrogen, methyl, ethyl, methoxy or ethoxy; R is hydrogen, alkyl containing 1 to 4 carbon atoms or the group of formula: ##STR2## said alkyl being unsubstituted or substituted by one hydroxy, alkoxy containing 1 to 4 carbon atoms, phenoxy, acetyloxy, cyano, alkylsulfonyl containing 1 to 4 carbon atoms, carbalkoxy containing 2 to 5 carbon atoms or alkoxycarbonyloxy containing 2 to 5 carbon atoms; N is equal to 1, 2 or 3; and Z is 2-cyanovinyl, 2-cyanoethyl or 2-chloro-2-cyanoethyl and which are useful as dispersion dyestuffs for dyeing and printing fibers of fibrous materials which are based on organic substances with high molecular weight, are hydrophobic and are wholly or partially synthetic.

Inventors

  • 👤 Claude M. H. E. Brouard
  • 👤 Bernard Dupont
  • 👤 Jean-Marie L. Leroy
  • 👤 Jean-Pierre H. Stiot

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-10 01:53
CPC Classifications
C; C09; C09B; C09B43/00; C09B43/18; C09B43/20; C09B43/22; C09B29/00; C09B29/06; C09B29/08; C09B29/0805; C09B29/0807; C09B29/0809; C09B29/0811; C09B29/0813; C09B31/00; C09B31/02; C09B31/04; C09B31/043

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 147 words
A dyestuff of the formula: ##STR14## in which A is thiazolyl, isothiazolyl, benzothiazolyl, benzisothiazolyl, thiadiazolyl, thienyl, or imidazolyl which is unsubstituted or substituted by one to three substituents selected from chlorine, bromine, methyl, phenyl, nitro, cyano, thiocyano, acetyl, carbalkoxy containing 2 to 5 carbon atoms and alkylsulfonyl containing 1 to 4 carbon atoms; X is hydrogen, chlorine, methyl, ethyl, methoxy, ethoxy, formylamino, acetylamino, propanoylamino, benzoylamino or cinnamoylamino; Y is hydrogen, methyl, ethyl, methoxy or ethoxy; R is hydrogen, alkyl containing 1 to 4 carbon atoms or the group of formula: ##STR15## said alkyl being unsubstituted or substituted by one hydroxy, alkoxy containing 1 to 4 carbon atoms, phenoxy, acetyloxy, cyano, alkylsulfonyl containing 1 to 4 carbon atoms, carbalkoxy containing 2 to 5 carbon atoms or alkoxycarbonyloxy containing 2 to 5 carbon atoms; n is equal to 1, 2, or 3; and Z is 2-cyanovinyl, 2-cyanoethyl or 2-chloro-2-cyanoethyl.
Claim 2
Dependent Claim 147 words
A dyestuff of the formula: ##STR14## in which A is thiazolyl, isothiazolyl, benzothiazolyl, benzisothiazolyl, thiadiazolyl, thienyl, or imidazolyl which is unsubstituted or substituted by one to three substituents selected from chlorine, bromine, methyl, phenyl, nitro, cyano, thiocyano, acetyl, carbalkoxy containing 2 to 5 carbon atoms and alkylsulfonyl containing 1 to 4 carbon atoms; X is hydrogen, chlorine, methyl, ethyl, methoxy, ethoxy, formylamino, acetylamino, propanoylamino, benzoylamino or cinnamoylamino; Y is hydrogen, methyl, ethyl, methoxy or ethoxy; R is hydrogen, alkyl containing 1 to 4 carbon atoms or the group of formula: ##STR15## said alkyl being unsubstituted or substituted by one hydroxy, alkoxy containing 1 to 4 carbon atoms, phenoxy, acetyloxy, cyano, alkylsulfonyl containing 1 to 4 carbon atoms, carbalkoxy containing 2 to 5 carbon atoms or alkoxycarbonyloxy containing 2 to 5 carbon atoms; n is equal to 1, 2, or 3; and Z is 2-cyanovinyl, 2-cyanoethyl or 2-chloro-2-cyanoethyl.
Claim 3
Dependent Claim 12 words
Dyestuff as claimed in claim 1 wherein n is equal to 2.
Claim 4
Dependent Claim 24 words
A dyestuff as claimed in claim 1, in which A is 5-nitro-2-thiazolyl, 3-methyl-4-nitro-5-isothiazolyl, 6-carbethoxy-2-benzothiazolyl, 6-thiocyano-2-benzothiazolyl, 6-methylsulfonyl-2-benzothiazolyl, 6-cyano-2-benzothiazolyl, 6-nitro-2-benzothiazolyl, 5-nitro-2,1-benzothiazol-3-yl, 5-nitro-1,3,4-thiadiazol-2-yl, 3-methylsulfonyl-1,2,4-thiadiazol-5-yl, 3-phenyl-1,2,4-thiadiazol-5-yl or 3-nitro-5-acetyl-2-thienyl.
Claim 5
Dependent Claim 26 words
Dyestuff as claimed in claim 1 wherein, Y is hydrogen, X is hydrogen, chlorine, methyl or acetylamino, R is ethyl or β-cyanoethyl and n is 2.
Claim 6
Dependent Claim 17 words
A dyestuff of the formula: ##STR16## wherein A, n and Z are as defined in claim 1.
Claim 7
Dependent Claim 6 words
The dyestuff of the formula: ##STR17##
Claim 8
Dependent Claim 6 words
The dyestuff of the formula: ##STR17##

References Cited (Backward Citations)

US3661889A Cited
GB1067040A Cited
GB1172154A Cited
US3578654A Cited
US3707533A Cited
US4008213A Cited
US3971771A Cited
US3869442A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-07 1982-02-06 1982-08-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-07 1986-02-06 1986-08-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-07 1990-02-06 1990-08-08 $7700.00 Window Closed / Lapsed

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