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US4101516A Expired / Lapsed US ⏱️ 0.0 years remaining

Clear and colorless epoxide dianhydride cured resins

Assignee: Gulf Research and Development Co
•
Filing: 1976-12-10
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Granted: 1978-07-18
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Expires: 1996-12-10
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Abstract

Abstract A clear, colorless cured resin is prepared from a solid epoxy resin and 5-phenyl-5-methylhexane-1,2,3,4-tetracarboxylic acid dianhydride.

Inventors

  • 👤 Walter P. Barie, Jr.
  • 👤 James T. Eurich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:11
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/42; C08G59/4223

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 56 words
A powdered resin mixture which will cure to a clear, substantially colorless hard resin comprising 5-phenyl-5-methylhexane-1,2,3,4-tetracarboxylic acid dianhydride and an epoxy resin having an epoxy equivalent value greater than one and an epoxy equivalent weight between about 400 and about 4,000, and a ratio of anhydride equivalents to epoxy equivalents of between 1.0 and about 1.5.
Claim 2
Dependent Claim 56 words
A powdered resin mixture which will cure to a clear, substantially colorless hard resin comprising 5-phenyl-5-methylhexane-1,2,3,4-tetracarboxylic acid dianhydride and an epoxy resin having an epoxy equivalent value greater than one and an epoxy equivalent weight between about 400 and about 4,000, and a ratio of anhydride equivalents to epoxy equivalents of between 1.0 and about 1.5.
Claim 3
Dependent Claim 22 words
A powdered resin mixture in accordance with claim 1 in which the epoxy equivalent weight is between about 500 and about 2,500.
Claim 4
Dependent Claim 21 words
A powdered resin mixture in accordance with claim 1 in which the epoxy resin is the diglycidyl ether of bisphenol A.
Claim 5
Dependent Claim 19 words
A powdered resin mixture in accordance with claim 1 comprising tin octanoate or zinc acetylacetonate as a reaction accelerator.
Claim 6
Independent Claim 71 words
A method of making a clear, substantially colorless, cured resin comprising curing at a temperature between about 140° C. and about 190° C., a powdered mixture of 5-phenyl-5-methylhexane-1,2,3,4-tetracarboxylic acid dianhydride, and an epoxy resin having an epoxy equivalent value greater than one and an epoxy equivalent weight between about 400 and about 4,000, the ratio of anhydride equivalents to epoxy equivalents in said powdered mixture being between 1.0 and about 1.5.
Claim 7
Independent Claim 71 words
A method of making a clear, substantially colorless, cured resin comprising curing at a temperature between about 140° C. and about 190° C., a powdered mixture of 5-phenyl-5-methylhexane-1,2,3,4-tetracarboxylic acid dianhydride, and an epoxy resin having an epoxy equivalent value greater than one and an epoxy equivalent weight between about 400 and about 4,000, the ratio of anhydride equivalents to epoxy equivalents in said powdered mixture being between 1.0 and about 1.5.
Claim 8
Dependent Claim 20 words
A method in accordance with claim 5 in which the epoxy equivalent weight is between about 500 and about 2,500.
Claim 9
Dependent Claim 19 words
A method in accordance with claim 5 in which the epoxy resin is the diglycidyl ether of bisphenol A.
Claim 10
Dependent Claim 22 words
A method in accordance with claim 5 in which the powdered mixture comprises zinc acetylacetonate or tin octanoate as a reaction accelerator.
Claim 11
Dependent Claim 58 words
A clear, substantially colorless, cured resin comprising the copolymer of 5-phenyl-5-methylhexane-1,2,3,4-tetracarboxylic acid dianhydride and an epoxy resin having a 1,2-epoxy equivalent value greater than one and an epoxy equivalent weight between about 400 and about 4,000 and a ratio of anhydride equivalent in said dianhydride to epoxy equivalents in said epoxy resin of between 1.0 and about 1.5.
Claim 12
Dependent Claim 58 words
A clear, substantially colorless, cured resin comprising the copolymer of 5-phenyl-5-methylhexane-1,2,3,4-tetracarboxylic acid dianhydride and an epoxy resin having a 1,2-epoxy equivalent value greater than one and an epoxy equivalent weight between about 400 and about 4,000 and a ratio of anhydride equivalent in said dianhydride to epoxy equivalents in said epoxy resin of between 1.0 and about 1.5.
Claim 13
Dependent Claim 21 words
A cured resin in accordance with claim 9 in which the epoxy equivalent weight is between about 500 and about 2,500.
Claim 14
Dependent Claim 20 words
A cured resin in accordance with claim 9 in which the epoxy resin is the diglycidyl ether of bisphenol A.

References Cited (Backward Citations)

US2989500A Cited
US2965610A Cited
US3297723A Cited
US3556920A Cited
US3842035A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-17 1982-01-16 1982-07-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-17 1986-01-16 1986-07-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-17 1990-01-16 1990-07-18 $7700.00 Window Closed / Lapsed

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