Patent US4101478A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4101478A Expired / Lapsed US ⏱️ 0.0 years remaining

Synthetic rubber mix

Assignee: Individual
•
Filing: 1976-04-12
•
Granted: 1978-07-18
•
Expires: 1996-04-12
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract The present invention relates to a rubber mix based on synthetic rubbers and containing vulcanizing agents, organic accelerators, vulcanization promotors, fillers, dispersing agents, plasticizers and an alkylphenolamine resin prepared by condensation of aminomethylating agents with a mixture consisting of 70-97% by weight of monoalkylphenols with the aklyls being C 4 -C 12 and 3 to 30% by weight of dialkylphenols with the alkyls being C 4 -C 12 at a temperature within the range of from 120° to 180° C; said alkylphenolamine resin corresponds to the formula: ##STR1## wherein R is a C 4 -C 12 alkyl; R' is hydrogen or substituted hydroxybenzyl; R" is hydrogen, a C 4 -C 12 alkyl, N(dimethyl) methylenamine; n = 0.1-5.0; m = 0 - 4; z = 0 - 0.5 And has a molecular weight within the range of from 500 to 2,000, a softening point of from 50° to 130° C and a nitrogen content of from 0.4 to 5%. The components are incorporated in said rubber mix in the following proportions (parts by weight): ______________________________________ synthetic rubber 100 vulcanizing agents 1.5-3 organic accelerators 1-2.5 vulcanization promotors 3-5 fillers 40-70 dispersing agents 1-2 plasticizers 5-20 alkylphenolamine resin 0.5-10. ______________________________________ The rubber mix of the above composition features a high tackiness. Vulcanizates produced from said rubber mix possess high degree of vulcanization and stability against thermal ageing. The rubber mix of this composition is useful in the production of tires, mechanicals and other types of rubber goods.

Inventors

  • 👤 Vladimir Mitrofanovich Kostjuchenko
  • 👤 Evgeny Petrovich Panov
  • 👤 Arkady Grigorievich Shvarts
  • 👤 Nadezhda Arkadievna Pruzhanskaya
  • 👤 Natalya Yakovlevna Vasilievykh
  • 👤 Galina Vasilievna Fateeva

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:47
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/17; C08G; C08G8/00; C08L; C08L21/00

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 211 words
A rubber mix comprising synthetic rubbers selected from the group consisting of cis-isoprene rubber, cis-divinyl rubber, butadiene-styrene rubber, ethylene-propylene rubber and butyl rubber, and mixtures thereof; sulfur as a vulcanizing agent; organic accelerators selected from the group consisting of di-(2-benzothiazolyl)-disulphide, 2-mercaptobenzothiazole, N-furfurolidene-benzothiazolyl-2-sulphenamide, diphenylguanidine, N-cyclohexyl-2-benzothiazolyl-sulphenamide, and tetramethylthiuramidisulphide; zinc oxide as a vulcanization promoter, fillers selected from the group consisting of carbon black, and a mixture of carbon black and a silicic-acid based filler; stearin as a dispersing agent, plasticizers selected from the group consisting of an aromatic oil with a viscosity of 35 to 40 cSt at 100° C, paraffin-naphthenic oil with a viscosity of 8.5 to 10 cSt at 100° C, petroleum bitumen, and indene-coumarone resin; and alkylphenolamine resin obtained by condensation of aminomethylating agents with a mixture comprising 70 to 97 weight percent of monoalkylphenols, with alkyls containing from 4 to 12 carbon atoms, and 3 to 30 weight percent of 2,4- and 2,6-dialkylphenols, with alkyls containing 4 to 12 carbon atoms, at a temperature of 120 to 180° C, said alkylphenolamine resin being described by the general formula: ##STR3## where: R is alkyl having 4 to 12 carbon atoms; R' is hydrogen or substituted hydroxybenzyl; R" is hydrogen, or alkyl having 4 to 12 carbon atoms, or N(dimethyl)methylene amine;
Claim 2
Dependent Claim 211 words
A rubber mix comprising synthetic rubbers selected from the group consisting of cis-isoprene rubber, cis-divinyl rubber, butadiene-styrene rubber, ethylene-propylene rubber and butyl rubber, and mixtures thereof; sulfur as a vulcanizing agent; organic accelerators selected from the group consisting of di-(2-benzothiazolyl)-disulphide, 2-mercaptobenzothiazole, N-furfurolidene-benzothiazolyl-2-sulphenamide, diphenylguanidine, N-cyclohexyl-2-benzothiazolyl-sulphenamide, and tetramethylthiuramidisulphide; zinc oxide as a vulcanization promoter, fillers selected from the group consisting of carbon black, and a mixture of carbon black and a silicic-acid based filler; stearin as a dispersing agent, plasticizers selected from the group consisting of an aromatic oil with a viscosity of 35 to 40 cSt at 100° C, paraffin-naphthenic oil with a viscosity of 8.5 to 10 cSt at 100° C, petroleum bitumen, and indene-coumarone resin; and alkylphenolamine resin obtained by condensation of aminomethylating agents with a mixture comprising 70 to 97 weight percent of monoalkylphenols, with alkyls containing from 4 to 12 carbon atoms, and 3 to 30 weight percent of 2,4- and 2,6-dialkylphenols, with alkyls containing 4 to 12 carbon atoms, at a temperature of 120 to 180° C, said alkylphenolamine resin being described by the general formula: ##STR3## where: R is alkyl having 4 to 12 carbon atoms; R' is hydrogen or substituted hydroxybenzyl; R" is hydrogen, or alkyl having 4 to 12 carbon atoms, or N(dimethyl)methylene amine;
Claim 3
Dependent Claim 7 words
n is equal to 0.1 to 5.0;
Claim 4
Dependent Claim 7 words
n is equal to 0.1 to 5.0;
Claim 5
Dependent Claim 6 words
m is equal to 0-4; and
Claim 6
Dependent Claim 6 words
m is equal to 0-4; and
Claim 7
Dependent Claim 72 words
z is equal to 0 to 0.5, and having a molecular weight of 500 to 2,000, a softening point of 50° to 130° C, and a nitrogen content of 0.4 to 5 percent, said components of the rubber mix being taken in the following proportions, in parts by weight: synthetic rubbers: 100 vulcanizing agent: 1.5-3 organic accelerators: 1-2.5 vulcanization promoter: 3-5 fillers: 40-70 dispersing agent: 1-2 plasticizers: 5-20, and alkylphenolamine resin: 0.5-10.
Claim 8
Dependent Claim 72 words
z is equal to 0 to 0.5, and having a molecular weight of 500 to 2,000, a softening point of 50° to 130° C, and a nitrogen content of 0.4 to 5 percent, said components of the rubber mix being taken in the following proportions, in parts by weight: synthetic rubbers: 100 vulcanizing agent: 1.5-3 organic accelerators: 1-2.5 vulcanization promoter: 3-5 fillers: 40-70 dispersing agent: 1-2 plasticizers: 5-20, and alkylphenolamine resin: 0.5-10.
Claim 9
Dependent Claim 29 words
A synthetic rubber mix as claimed in claim 1, wherein said alkylphenolamine resin contains petroleum wax in an amount of from 5 to 20% by weight of said resin.
Claim 10
Dependent Claim 59 words
A rubber mix as claimed in claim 2, which further contains modifying agents selected from the group consisting of a complex compound of resorcinol and hexamethylenetetramine and a mixture of 331/3 percent of N-2-methyl-2-nitropropyl-4-nitrosoaniline and 662/3 percent of an inert filler, taken in an amount of 1-2 parts by weight per 100 parts by weight of the synthetic rubber.
Claim 11
Dependent Claim 39 words
A rubber mix as claimed in claim 2, which further contains antioxidants selected from the group consisting of phenyl-β-naphthylamine, N-phenyl-N'-isopropylphenylenediamine, 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline taken in an amount of 1-2 parts by weight per 100 parts by weight of the synthetic rubber.
Claim 12
Dependent Claim 39 words
A rubber mix as claimed in claim 1, which further contains antioxidants selected from the group consisting of phenyl-β-naphthylamine, N-phenyl-N'-isopropylphenylenediamine, 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline, taken in an amount of 1-2 parts by weight per 100 parts by weight of the synthetic rubber.
Claim 13
Dependent Claim 61 words
A rubber mix as claimed in claim 1, which further contains modifying agents selected from the group consisting of a complex compound of resorcinol and hexamethylenetetramine and a mixture of 331/3 percent of N-2-methyl-2-nitropropyl--4-nitrosoaniline and 662/3 percent of an inert filler, taken in an amount of 1 to 2 parts by weight per 100 parts by weight of the synthetic rubber.
Claim 14
Dependent Claim 38 words
A rubber mix as claimed in claim 6, which contains antioxidants selected from the group consisting of phenyl-β-naphthylamine, N-phenyl-N'-isopropylphenylenediamine, 6-ethoxy-2,2,4-trimethyl-1,2-dihydroquinoline, taken in an amount of 1-2 parts by weight per 100 parts by weight of the synthetic rubber.

References Cited (Backward Citations)

US3189572A Cited
US3325429A Cited
US3708554A Cited
US3738948A Cited
US3763104A Cited
US3962156A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-17 1982-01-16 1982-07-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-17 1986-01-16 1986-07-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-17 1990-01-16 1990-07-18 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag