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US4100303A Expired / Lapsed US ⏱️ 0.0 years remaining

Isophthalic acid/P,P-sulfonyldibenzoic acid/ethylene glycol/neopentyl glycol polyester compositions and containers made therefrom

Assignee: OI Glass Inc
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Filing: 1977-01-17
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Granted: 1978-07-11
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Expires: 1997-01-17
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Abstract

Abstract Copolyesters having an oxygen permeability of less than 15 ccxmil/100 in.2xdayxatm. (at 50% relative humidity and about 73 DEG F.) and a glass transition temperature in excess of 72 DEG C. and having the following four repeating units are contemplated: C(O)C6H4SO2C6H4C(O) (a) <IMAGE> (b) OCH2CH2O (c) OCH2C(CH3)2CH2O.

Inventors

  • 👤 Santos W. Go

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 17:13
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 165 words
In a method of packaging a product comprising placing said product in a polymeric polyester container, the improvement wherein said polyester container is a container of a polyester, the repeating units of said polyester consisting essentially of ##STR6## said polyester having an oxygen permeability of less than 15 cc·mil/100 in. 2 ·day·atm. and a glass transition temperature in excess of 72° C., said (a) and (b) units and said (c) and (d) units respectively being the units formed by reactively combining polyester forming precursors thereof in an amount of at least one mole of the precursors of said (c) and (d) units per mole of precursors of said (a) and (b) units and wherein the precursors of said units in forming said polyester by said reactive combining are in a molar ratio of said (b) unit precursor to said (a) unit precursor of about 80:20 to about 20:80 and a molar ratio of said (c) unit precursor to said (d) unit precursor of about 80:20.
Claim 2
Dependent Claim 165 words
In a method of packaging a product comprising placing said product in a polymeric polyester container, the improvement wherein said polyester container is a container of a polyester, the repeating units of said polyester consisting essentially of ##STR6## said polyester having an oxygen permeability of less than 15 cc·mil/100 in. 2 ·day·atm. and a glass transition temperature in excess of 72° C., said (a) and (b) units and said (c) and (d) units respectively being the units formed by reactively combining polyester forming precursors thereof in an amount of at least one mole of the precursors of said (c) and (d) units per mole of precursors of said (a) and (b) units and wherein the precursors of said units in forming said polyester by said reactive combining are in a molar ratio of said (b) unit precursor to said (a) unit precursor of about 80:20 to about 20:80 and a molar ratio of said (c) unit precursor to said (d) unit precursor of about 80:20.
Claim 3
Dependent Claim 183 words
In a package comprising a polyester container and foodstuffs or medicines enclosed in said container, the improvement wherein said polyester container is a container formed of a polyester, the repeating units of said polyester consisting essentially of ##STR7## and (c) --O--CH 2 --CH 2 --O-- and (d) --O--CH 2 --C(CH 3 ) 2 --CH 2 --O--, said polyester having an oxygen permeability of less than 15 cc·mil/100 in. 2 ·day·atm. and a glass transition temperature in excess of 72° C., said (a) and (b) units and said (c) and (d) units respectively being the units formed by reactively combining polyester forming precursors thereof in an amount of at least one mole of the precursors of said (c) and (d) units per mole of precursors of said (a) and (b) units and wherein the precursors of said units in forming said polyester by said reactive combining are in a molar ratio of said (b) unit precursor to said (a) unit precursor of about 80:20 to about 20:80 and a molar ratio of said (c) unit precursor to said (d) unit precursor of about 80:20.
Claim 4
Dependent Claim 183 words
In a package comprising a polyester container and foodstuffs or medicines enclosed in said container, the improvement wherein said polyester container is a container formed of a polyester, the repeating units of said polyester consisting essentially of ##STR7## and (c) --O--CH 2 --CH 2 --O-- and (d) --O--CH 2 --C(CH 3 ) 2 --CH 2 --O--, said polyester having an oxygen permeability of less than 15 cc·mil/100 in. 2 ·day·atm. and a glass transition temperature in excess of 72° C., said (a) and (b) units and said (c) and (d) units respectively being the units formed by reactively combining polyester forming precursors thereof in an amount of at least one mole of the precursors of said (c) and (d) units per mole of precursors of said (a) and (b) units and wherein the precursors of said units in forming said polyester by said reactive combining are in a molar ratio of said (b) unit precursor to said (a) unit precursor of about 80:20 to about 20:80 and a molar ratio of said (c) unit precursor to said (d) unit precursor of about 80:20.
Claim 5
Dependent Claim 55 words
The improvement of claim 1 wherein said precursor mole ratio of (b) to (a) units is about 60:40 to about 20:80, said polyester having an oxygen permeability of less than about 12.4 and a glass transition temperature between about 93° C. and about 127° C. and a CO 2 permeability of less than about 95.
Claim 6
Dependent Claim 43 words
The improvement of claim 1 wherein said ratio of (b) units to (a) units is about 30:70 to about 20:80, said polyester having a glass transition temperature between about 117° and 127° C. and an oxygen permeability between about 10.2 and about 12.4.
Claim 7
Dependent Claim 12 words
The improvement of claim 1 wherein said container is a clear container.
Claim 8
Dependent Claim 54 words
The improvement of claim 2 wherein said precursor mole ratio of (b) to (a) units is about 60:40 to about 20:80, said polyester having an oxygen permeability of less than about 12.4 and a glass transition temperature between about 93° and about 127° C. and a CO 2 permeability of less than about 95.
Claim 9
Dependent Claim 43 words
The improvement of claim 2 wherein said ratio of (b) units to (a) units is about 30:70 to about 20:80, said polyester having a glass transition temperature between about 117° and 127° C. and an oxygen permeability between about 10.2 and about 12.4.
Claim 10
Dependent Claim 12 words
The improvement of claim 2 wherein said container is a clear container.

References Cited (Backward Citations)

US3790684A Cited
US3867249A Cited
US3912823A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-10 1982-01-09 1982-07-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-10 1986-01-09 1986-07-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-10 1990-01-09 1990-07-11 $7700.00 Window Closed / Lapsed

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