Patent US4100269A successfully refreshed from Google Patents.
US4100269A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Anticalculus dentifrice
Assignee: CPPD Inc A CORP OF
•
Filing: 1977-05-06
•
Granted: 1978-07-11
•
Expires: 1997-05-06
Abstract
Abstract An improved method for the control of calculus is disclosed employing one or more insoluble zinc compounds as the active agent. Dentifrice formulations and mouthwash formulations for use in the novel method are also disclosed. The mouthwash compositions comprise from 1/10% to about 25% by weight of the zinc compound while the dentifrice compositions comprise 1/4% to about 25% by weight of said compound.
Inventors
- 👤 Morton Pader
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 18:45
CPC Classifications
A; A61; A61Q; A61Q11/00; A61K; A61K8/00; A61K8/18; A61K8/19; A61K8/20; A61K8/21; A61K8/27; A61K8/30; A61K8/33; A61K8/36; A61K8/365
Claims Analysis
Total Claims: 35
Claim 1
Independent Claim
143 words
A method for the control of calculus on tooth surfaces comprising contacting the tooth surfaces at regular intervals with at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc- 2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable carrier therefor, said carrier being selected from the group consisting of a mouthwash and a dentifrice composition wherein the abrasives in said dentifrice compositions are substantially free of phosphate and calcium, and wherein said dentifrice has a minimum dentin abrasion value of about 50, the concentration of said zinc compound being effective to reduce the rate of accumulation of calculus, and wherein the maximum concentration of zinc is about 5% by weight of the total composition.
Claim 2
Independent Claim
143 words
A method for the control of calculus on tooth surfaces comprising contacting the tooth surfaces at regular intervals with at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc- 2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable carrier therefor, said carrier being selected from the group consisting of a mouthwash and a dentifrice composition wherein the abrasives in said dentifrice compositions are substantially free of phosphate and calcium, and wherein said dentifrice has a minimum dentin abrasion value of about 50, the concentration of said zinc compound being effective to reduce the rate of accumulation of calculus, and wherein the maximum concentration of zinc is about 5% by weight of the total composition.
Claim 3
Dependent Claim
15 words
A method according to claim 1 wherein said compound is applied at least once daily.
Claim 4
Independent Claim
104 words
A method for the control of calculus on tooth surfaces comprising contacting the tooth surfaces at regular intervals with at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc-2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc oxide, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable mouthwash, the concentration of such zinc compound in said mouthwash being effective to reduce the rate of accumulation of calculus, and wherein the maximum concentration of zinc is about 5% by weight of the total composition.
Claim 5
Independent Claim
104 words
A method for the control of calculus on tooth surfaces comprising contacting the tooth surfaces at regular intervals with at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc-2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc oxide, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable mouthwash, the concentration of such zinc compound in said mouthwash being effective to reduce the rate of accumulation of calculus, and wherein the maximum concentration of zinc is about 5% by weight of the total composition.
Claim 6
Dependent Claim
13 words
A method according to claim 1 wherein said carrier is a dentifrice composition.
Claim 7
Dependent Claim
136 words
A dental composition for controlling the accumulation of calculus on tooth surfaces comprising at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc-2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable carrier therefor, said carrier being selected from the group consisting of a mouthwash and a dentifrice composition, wherein the abrasives in said dentifrice composition are substantially free of phosphate and calcium, and wherein said dentifrice has a minimum dentin abrasion value of about 50, the concentration of said zinc compound being effective to reduce the rate of accumulation of calculus, and wherein the maximum concentration of zinc is about 5% by weight of the dental composition.
Claim 8
Dependent Claim
136 words
A dental composition for controlling the accumulation of calculus on tooth surfaces comprising at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc-2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable carrier therefor, said carrier being selected from the group consisting of a mouthwash and a dentifrice composition, wherein the abrasives in said dentifrice composition are substantially free of phosphate and calcium, and wherein said dentifrice has a minimum dentin abrasion value of about 50, the concentration of said zinc compound being effective to reduce the rate of accumulation of calculus, and wherein the maximum concentration of zinc is about 5% by weight of the dental composition.
Claim 9
Dependent Claim
93 words
A dental composition for controlling the accumulation of calculus on tooth surfaces comprising at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc-2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc oxide, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable mouthwash, the concentration of said zinc compound being effective to reduce the rate of accumulation of calculus, the maximum concentration of zinc being about 5% by weight of said mouthwash composition.
Claim 10
Dependent Claim
93 words
A dental composition for controlling the accumulation of calculus on tooth surfaces comprising at least one physiologically acceptable zinc compound selected from the group consisting of zinc tribromosalicylanilide, zinc-2-hexyl-5-chlorosalicylanilide, zinc soap of the C 8 to C 22 fatty acids, zinc carbonate, zinc benzoate, zinc dl-lactate trihydrate, zinc citrate, zinc oxide, zinc hexafluorosilicate, zinc stannate and zinc silicate, in a physiologically acceptable mouthwash, the concentration of said zinc compound being effective to reduce the rate of accumulation of calculus, the maximum concentration of zinc being about 5% by weight of said mouthwash composition.
Claim 11
Dependent Claim
14 words
A dental composition according to claim 5 wherein said carrier is a dentifrice composition.
Claim 12
Dependent Claim
40 words
A composition according to claim 6 wherein said mouthwash comprises water and a minor amount of the physiologically acceptable suspending agent for said zinc compound, the concentration of said zinc compound being from about 1/10% to about 25% by weight.
Claim 13
Dependent Claim
32 words
A composition according to claim 5 wherein said carrier is a dentifrice comprising a dental abrasive and the concentration of said zinc compound is from about 1/4% to about 25% by weight.
Claim 14
Dependent Claim
25 words
A composition according to claim 8 wherein the amount of said zinc compound is between about 1/10% and about 5% by weight of said composition.
Claim 15
Dependent Claim
22 words
A composition according to claim 9 wherein said zinc compound is between about 1/4% and about 10% by weight of said composition.
Claim 16
Dependent Claim
13 words
A method according to claim 1 wherein said zinc compound is zinc tribromosalicylanilide.
Claim 17
Dependent Claim
12 words
A method according to claim 1 wherein said zinc compound is zinc-2-hexyl-5-chlorosalicylanilide.
Claim 18
Dependent Claim
22 words
A method according to claim 1 wherein said zinc compound is zinc soap of the C 8 to C 22 fatty acids.
Claim 19
Dependent Claim
13 words
A method according to claim 1 wherein said zinc compound is zinc carbonate.
Claim 20
Dependent Claim
13 words
A method according to claim 1 wherein said zinc compound is zinc benzoate.
Claim 21
Dependent Claim
14 words
A method according to claim 1 wherein said zinc compound is zinc dl-lactate trihydrate.
Claim 22
Dependent Claim
13 words
A method according to claim 1 wherein said zinc compound is zinc citrate.
Claim 23
Dependent Claim
13 words
A method according to claim 1 wherein said zinc compound is zinc hexafluorosilicate.
Claim 24
Dependent Claim
13 words
A method according to claim 1 wherein said zinc compound is zinc stannate.
Claim 25
Dependent Claim
13 words
A method according to claim 1 wherein said zinc compound is zinc silicate.
Claim 26
Dependent Claim
14 words
A dental composition according to claim 5 wherein said zinc compound is zinc tribromosalicylanilide.
Claim 27
Dependent Claim
13 words
A dental composition according to claim 5 wherein said zinc compound is zinc-2-hexyl-5-chlorosalicylanilide.
Claim 28
Dependent Claim
23 words
A dental composition according to claim 5 wherein said zinc compound is zinc soap of the C 8 to C 22 fatty acids.
Claim 29
Dependent Claim
14 words
A dental composition according to claim 5 wherein said zinc compound is zinc carbonate.
Claim 30
Dependent Claim
14 words
A dental composition according to claim 5 wherein said zinc compound is zinc benzoate.
Claim 31
Dependent Claim
15 words
A dental composition according to claim 5 wherein said zinc compound is zinc dl-lactate trihydrate.
Claim 32
Dependent Claim
14 words
A dental composition according to claim 5 wherein said zinc compound is zinc citrate.
Claim 33
Dependent Claim
14 words
A dental composition according to claim 5 wherein said zinc compound is zinc hexafluorosilicate.
Claim 34
Dependent Claim
14 words
A dental composition according to claim 5 wherein said zinc compound is zinc stannate.
Claim 35
Dependent Claim
14 words
A dental composition according to claim 5 wherein said zinc compound is zinc silicate.
References Cited (Backward Citations)
US1861189A
Cited
US1943467A
Cited
US2876167A
Cited
US3095356A
Cited
US3277118A
Cited
US3175951A
Cited
US3622662A
Cited
US3624199A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-10 | 1982-01-09 | 1982-07-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-10 | 1986-01-09 | 1986-07-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-10 | 1990-01-09 | 1990-07-11 | $7700.00 | Window Closed / Lapsed |