Isolongifolene Prins reaction compounds in perfumery

Claim 2

A compound having the formula XY, wherein X is a polycyclic monovalent radical selected from the group consisting of II, III and IV: ##STR14## Y is --C(OR' n ) (H) n R, n is 0 or 1, R is selected from the group consisting of hydrogen and alkyl groups having from 1 to 5 carbon atoms and R' is selected from the group consisting of hydrogen and alkanoic acid residues having from 1 to 6 carbon atoms.

Claim 3

A compound as claimed in claim 1 wherein X is a radical selected from the group consisting of II and III, n is 0 and R is hydrogen.

Claim 4

A compound as claimed in claim 1 wherein X is a radical selected from the group consisting of II and III, n is 0 and R is an alkyl group having from 1 to 5 carbon atoms.

Claim 5

A compound as claimed in claim 1 wherein X is a radical selected from the group consisting of II and III, n is 1, R' is hydrogen and R is hydrogen.

Claim 6

A compound as claimed in claim 1 wherein X is a radical selected from the group consisting of II and III, n is 1, R is hydrogen and R' is an alkanoic acid residue having from 1 to 6 carbon atoms.

Claim 7

A compound according to claim 5 wherein R' is a formyl residue.

Claim 8

A compound according to claim 5 wherein R' is an acetyl residue.

Claim 9

A compound as claimed in claim 1 wherein X is a radical selected from the group consisting of II and III, n is 1, R' is hydrogen and R is an alkyl group having from 1 to 5 carbon atoms.

Claim 10

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of the compounded perfumery composition, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i); said ingredient (i) being at least one compound as claimed in claim 1.

Claim 11

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of said compounded perfumery composition and being at least one compound as claimed in claim 2, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i).

Claim 12

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of said compounded perfumery composition and being at least one compound as claimed in claim 3, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i).

Claim 13

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of said compounded perfumery composition and being at least one compound as claimed in claim 4, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i).

Claim 14

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of said compounded perfumery composition and being at least one compound as claimed in claim 5, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i).

Claim 15

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of said compounded perfumery composition and being at least one compound as claimed in claim 6, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i).

Claim 16

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of said compounded perfumery composition and being at least one compound as claimed in claim 7, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i).

Claim 17

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of said compounded perfumery composition and being at least one compound as claimed in claim 8, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i).

Claim 18

The compounded perfumery composition of claim 9 wherein said ingredient (ii) contains odiferous ingredients selected from the group consisting of 2,6 -dimethyl-2-alkoxy octan-7-ol, vetivert oil, vetiverol, vetiveryl acetate, guaiac wood oil, guaiac wood acetate, coumarin musk ketone, lauric aldehyde, benzyl acetate, lemon oil, dimethyl benzyl carbinol, dimethyl benzyl carbinyl acetate, rose absolute, jasmin absolute, ionones, iso-nonyl acetate, methyl phenyl acetate, styrallyl acetate, B phenyl ethanol, citronellol, citronellal, hydroxy citronellal, geranium oil, geraniol, linalol, nerol, lavandin oil, lanalyl acetate, patchouli oil, petitgrain oil, bergamot oil, heliotropin, ethylene brassylate, undecyl aldehyde, cinnamaldehyde, benzyl salicylate, cinnamyl alcohol, clove bud oil, bay oil, nutmeg oil, pimento berry oil, terpineol, ylang oil, benzyl benzoate, sandalwood oil, clary sage oil, amyl salicylate, labdanum resin, methyl ionones, dihydromyrcenol, orange oil, vanillin, ethylvanillin, olibanum resin, musk ambrette, rhodinol, mandarin oil, methylnonyl acetaldehyde, neroli oil, cedrol, oakmoss, isovalanone, eugenol, iso-eugenol, cedarwood oil, and p-tert-butyl cyclohexyl acetate.

Claim 19

The compounded perfumery composition of claim 9 wherein said ingredient (ii) contains odiferous ingredients selected from the group consisting of cedarwood, sandalwood, vetiver, lavender, bergamot, geranium, patchouli, oakmoss, clary sage, musk ambrette, musk ketone, musk xylene, cedrol, cedryl acetate, acetyl cedrene, vetiverol, vetiveryl acetate, methyl ionone, coumarin, linalool, linalyl acetate, geraniol, citronellol, phenyl ethyl alcohol, benzyl acetate, eugenol, isoeugenol, amyl - and hexylcinnamin aldehyde, and hydroxycitronellal.

Claim 20

A compound as claimed in claim 1 wherein X is a radical selected from the group consisting of II and III, and R' is a C 1-6 alkanoic acid residue.

Claim 21

A compound as claimed in claim 19 wherein n is 1.

Claim 22

A compound as claimed in claim 1 wherein X is the radical III.

Claim 23

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of the compounded perfumery composition, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i); said ingredient (i) being at least one compound as claimed in claim 21.

Claim 24

A mixture of at least two polycyclic compounds comprising (i) a polycyclic compound XY wherein X is the radical ##STR15## Y is --C (OR' n ) (H) n R, n is 0 or 1, R is selected from the group consisting of hydrogen and alkyl groups having from 1 to 5 carbon atoms and R' is selected from the group consisting of hydrogen and alkanoic acid residues having from 1 to 6 carbon atoms; and (ii) a polycyclic compound X'Y wherein X' is the radical ##STR16## and Y is the same as in compound (i).

Claim 25

A mixture of at least two polycyclic compounds comprising (i) a polycyclic compound XY wherein X is the radical ##STR15## Y is --C (OR' n ) (H) n R, n is 0 or 1, R is selected from the group consisting of hydrogen and alkyl groups having from 1 to 5 carbon atoms and R' is selected from the group consisting of hydrogen and alkanoic acid residues having from 1 to 6 carbon atoms; and (ii) a polycyclic compound X'Y wherein X' is the radical ##STR16## and Y is the same as in compound (i).

Claim 26

A compounded perfumery composition comprising ingredient (i) in an amount between 0.01 and 20% by weight of the compounded perfumery composition, and ingredient (ii) a plurality of odiferous ingredients in addition to said ingredient (i); said ingredient (i) being the mixture as claimed in claim 23.