Patent FR1395480A successfully refreshed from Google Patents.
Patent US4099003A successfully refreshed from Google Patents.
US4099003A
Expired / Lapsed
US
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Non-blooming accelerator and process for vulcanization of epdm elastomers
Assignee: Pennwalt Corp
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Filing: 1976-06-11
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Granted: 1978-07-04
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Expires: 1996-06-11
Abstract
Abstract Thiuram sulfides of oxazolidines and thiazolidines are disclosed herein and shown to be useful as non-blooming accelerators in the vulcanization of ethylene-propylene-diene-terpolymers.
Inventors
- 👤 Ivan Christoff Popoff
- 👤 Everett A. Mailey
- 👤 Paul Gordon Haines
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 08:25
CPC Classifications
C; C07; C07D; C07D263/00; C07D263/02; C07D263/04; C07D277/00; C07D277/02; C07D277/04; C07D295/00; C07D295/16; C07D295/20; C07D295/21; C08; C08K; C08K5/00; C08K5/36; C08K5/39
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
239 words
A compound having the following general structure: ##STR3## wherein R, R 1 , R 2 and R 3 are independently selected from the group consisting of hydrogen; alkyl and chlorinated alkyl each having from 1 to 17 carbon atoms; alkenyl radicals having from 2 to 17 carbon atoms; phenyl, naphthyl, substituted phenyl and substituted naphthyl radicals having no more than two substitutents selected from the group consisting of --Cl, --OH, --OR 5 and --NR 5 R 6 wherein R 5 and R 6 are alkyl radicals having 1 to 8 carbon atoms; not more than one of R and R 1 or of R 2 and R 3 is phenyl, naphthyl, substituted phenyl, substituted naphthyl, t-alkyl or t-alkenyl; n is an integer of from 1 to 4; R 4 is selected from the group consisting of (a) --NR 7 R 8 wherein R 7 and R 8 are independently selected from alkyl radicals having from 1 to 18 carbon atoms and together having a total of at least 5 carbon atoms, (b) --NZ which represents a morpholino or piperidino radical, and (c) ##STR4## wherein R 9 , R 10 , R 11 and R 12 are independently selected from the same group from which R is selected and at least one of R 9 , R 10 , R 11 and R 12 is other than hydrogen; and X and X' are independently selected from oxygen and sulfur atoms.
Claim 2
Dependent Claim
239 words
A compound having the following general structure: ##STR3## wherein R, R 1 , R 2 and R 3 are independently selected from the group consisting of hydrogen; alkyl and chlorinated alkyl each having from 1 to 17 carbon atoms; alkenyl radicals having from 2 to 17 carbon atoms; phenyl, naphthyl, substituted phenyl and substituted naphthyl radicals having no more than two substitutents selected from the group consisting of --Cl, --OH, --OR 5 and --NR 5 R 6 wherein R 5 and R 6 are alkyl radicals having 1 to 8 carbon atoms; not more than one of R and R 1 or of R 2 and R 3 is phenyl, naphthyl, substituted phenyl, substituted naphthyl, t-alkyl or t-alkenyl; n is an integer of from 1 to 4; R 4 is selected from the group consisting of (a) --NR 7 R 8 wherein R 7 and R 8 are independently selected from alkyl radicals having from 1 to 18 carbon atoms and together having a total of at least 5 carbon atoms, (b) --NZ which represents a morpholino or piperidino radical, and (c) ##STR4## wherein R 9 , R 10 , R 11 and R 12 are independently selected from the same group from which R is selected and at least one of R 9 , R 10 , R 11 and R 12 is other than hydrogen; and X and X' are independently selected from oxygen and sulfur atoms.
Claim 3
Dependent Claim
9 words
The compound of claim 1 wherein X is oxygen.
Claim 4
Dependent Claim
9 words
The compound of claim 1 wherein X is sulfur.
Claim 5
Dependent Claim
14 words
The compound of claim 1 wherein R 4 and --NR 7 R 8 .
Claim 6
Dependent Claim
14 words
The compound of claim 4 wherein R 7 and R 8 are butyl radicals.
Claim 7
Dependent Claim
14 words
The compound of claim 4 wherein R 7 and R 8 are octyl radicals.
Claim 8
Dependent Claim
10 words
The compound of claim 1 wherein R 4 is --NZ.
Claim 9
Dependent Claim
11 words
The compound of claim 7 wherein --NZ represents a morpholino radical.
Claim 10
Dependent Claim
10 words
The compound of claim 1 wherein R 4 is ##STR5##
Claim 11
Dependent Claim
34 words
A mixture of two compounds of claim 1 wherein n=2, and in one of said compounds R 4 is --NR 7 R 8 and in the other of said compounds R 4 is ##STR6##
Claim 12
Dependent Claim
10 words
The compound of claim 9 wherein X 1 is oxygen.
Claim 13
Dependent Claim
10 words
The mixture of claim 10 wherein X 1 is oxygen.
Claim 14
Dependent Claim
10 words
The compound of claim 9 wherein X 1 is sulfur.
Claim 15
Dependent Claim
33 words
The compound of claim 9 wherein R and R 9 are --CCl 3 , and R 1 , R 2 , R 3 , R 10 R 11 and R 12 are hydrogen.
Claim 16
Dependent Claim
13 words
The compound of claim 14 wherein X and X 1 are both oxygen.
Claim 17
Dependent Claim
9 words
The compound of claim 15 wherein n is 2.
Claim 18
Dependent Claim
9 words
The compound of claim 15 wherein n is 1.
Claim 19
Dependent Claim
13 words
The compound of claim 14 wherein X and X 1 are both sulfur.
Claim 20
Dependent Claim
14 words
The compound of claim 14 wherein X is oxygen and X 1 is sulfur.
Claim 21
Dependent Claim
34 words
The compound of claim 9 wherein R and R 9 are phenyl and and R 1 , R 2 , R 3 , R 10 , R 11 , and R 12 are hydrogen.
Claim 22
Dependent Claim
37 words
The compound of claim 11 wherein X is oxygen, R is --CCl 3 R 9 is phenyl and R 1 , R 2 , R 3 , R 10 , R 11 and R 12 are hydrogen.
Claim 23
Dependent Claim
70 words
A mixture of two compounds of claim 9 having the general structure of claim 9 wherein n is 2, X and X 1 are oxygen, R 1 , R 2 , R 3 , R 10 , R 11 and R 12 are hydrogen, and in one of said compounds, R and R 9 are --CCl 3 and in the other of said compounds R and R 9 are phenyl.
Claim 24
Dependent Claim
39 words
The compound of claim 11 wherein X is oxygen, R and R 9 are --CCl 3 , R 2 and R 11 are phenyl and R 1 , R 3 , R 10 , and R 12 are hydrogen.
Claim 25
Dependent Claim
22 words
The compound of claim 1 wherein R is --CCl 3 , and R 1 , R 2 and R 3 are hydrogen.
Claim 26
Dependent Claim
25 words
The compound of claim 8 wherein X is oxygen, R is --CCl 3 , and R 1 , R 2 and R 3 are hydrogen.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-03 | 1982-01-02 | 1982-07-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-03 | 1986-01-02 | 1986-07-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-03 | 1990-01-02 | 1990-07-04 | $7700.00 | Window Closed / Lapsed |