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US4098972A
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Method for bulk polymerization of vinyl chloride
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1976-03-16
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Granted: 1978-07-04
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Expires: 1996-03-16
Abstract
Abstract Vinyl chloride monomers or a monomeric mixture composed mainly of vinyl chloride is bulk-polymerized in a polymerization vessel. The inner walls and other surfaces of said vessel, coming into contact with the monomer or monomers, are coated with one or more specifically selected inorganic or organic compounds having a solubility greater than 0.5 g in 100 g of water at 25° C and a boiling point higher than 60° C. This bulk polymerization method serves to greatly reduce the deposition of polymer scale on the vessel walls and other surfaces. In addition the polymer scale deposited can be readily separated and removed by merely washing with water or gas under pressure. The present method provides high quality polymers.
Inventors
- 👤 Kinya Ogawa
- 👤 Kazuhiko Kurimoto
- 👤 Yoshitugu Eguchi
- 👤 Satoshi Kuwata
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 09:36
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/002; C08F2/004; B; B01; B01J; B01J19/00; B01J19/0053; B01J19/0066; B01J19/02; B05; B05D; B05D5/00; B05D5/08; B05D7/00; B05D7/22; B05D7/227; B01J2219/00; B01J2219/02; B01J2219/0204; B01J2219/0236
Claims Analysis
Total Claims: 37
Claim 1
Independent Claim
79 words
A method for the bulk polymerization of a vinyl chloride monomer or a monomeric mixture thereof with a copolymerizable monomer or monomers which comprises carrying out the polymerization in a polymerization reactor in which the inner walls and other surfaces coming into contact with the monomer or monomers are provided with coatings of a compound having a solubility greater than 0.5 g in 100 g of water at 25° C. and having a boiling point higher than 60° C.
Claim 2
Independent Claim
79 words
A method for the bulk polymerization of a vinyl chloride monomer or a monomeric mixture thereof with a copolymerizable monomer or monomers which comprises carrying out the polymerization in a polymerization reactor in which the inner walls and other surfaces coming into contact with the monomer or monomers are provided with coatings of a compound having a solubility greater than 0.5 g in 100 g of water at 25° C. and having a boiling point higher than 60° C.
Claim 3
Dependent Claim
20 words
The method of claim 1 wherein said compound is a hydroxide of an alkali metal or an alkaline earth metal.
Claim 4
Dependent Claim
24 words
The method of claim 1 wherein said compound is a boron-containing acid, a silicon-containing acid, a metal-containing acid or an alkali metal salt thereof.
Claim 5
Dependent Claim
12 words
The method of claim 1 wherein said compound is a phosphorus-containing acid.
Claim 6
Dependent Claim
31 words
The method of claim 1 wherein said compound is an alkali metal salt of an acid selected from the group consisting of carbonic acid, phosphoric acid, polymetaphosphoric acids and polyphosphoric acids.
Claim 7
Dependent Claim
39 words
The method of claim 1 wherein said compound is a salt selected from the group consisting of sulfates, nitrates and halides of metals other than the metals belonging to Group V of the Periodic Table and double salts thereof.
Claim 8
Dependent Claim
28 words
The method of claim 1 wherein said compound is a salt selected from the group consisting of thiocyanates, ferrocyanides and ferricyanides of alkali metals and double salts thereof.
Claim 9
Dependent Claim
30 words
The method of claim 1 wherein said compound is an acid selected from the group consisting of carboxylic acids, aminocarboxylic acids, organic sulfonic acids, and an alkali metal salt thereof.
Claim 10
Dependent Claim
13 words
The method of claim 1 wherein said compound is a polyvalent aliphatic alcohol.
Claim 11
Dependent Claim
13 words
The method of claim 1 wherein said compound is a water-soluble high polymer.
Claim 12
Dependent Claim
14 words
The method of claim 1 wherein said compound is a water-soluble surface active agent.
Claim 13
Dependent Claim
13 words
The method of claim 1 wherein said compound is a water-soluble organic dye.
Claim 14
Dependent Claim
26 words
The method of claim 2 wherein said hydroxide is selected from the group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, strontium hydroxide and barium hydroxide.
Claim 15
Dependent Claim
12 words
The method of claim 3 wherein said boron-containing acid is boric acid.
Claim 16
Dependent Claim
37 words
The method of claim 3 wherein said alkali metal salt of said acids is selected from the group consisting of borates, silicates, titanates, chromates, bichromates, manganates, permanganates, molybdates, tungstates, phosphotungstates, phosphomolybdates, aluminates and stannates of alkali metals.
Claim 17
Dependent Claim
35 words
The method of claim 4 wherein said phosphorus-containing acid is selected from the group consisting of phosphoric acid, hypophosphorous acid, phosphorous acid, diphosphorous acid, pyrophosphorous acid, hypophosphoric acid, ultraphosphoric acid, polymetaphosphoric acids and polyphosphoric acids.
Claim 18
Dependent Claim
53 words
The method of claim 6 wherein said sulfate is selected from the group consisting of lithium sulfate, sodium sulfate, potassium sulfate, copper sulfate, magnesium sulfate, zinc sulfate, aluminum sulfate, titanium sulfate, tin sulfate, iron sulfate, nickel sulfate, cobalt sulfate, chromium sulfate, manganese sulfate, platinum sulfate, sulfates of rare earth elements and zirconium sulfate.
Claim 19
Dependent Claim
59 words
The method of claim 6 wherein said nitrate is selected from the group consisting of lithium nitrate, sodium nitrate, potassium nitrate, copper nitrate, silver nitrate, magnesium nitrate, calcium nitrate, barium nitrate, zinc nitrate, aluminum nitrate, tin nitrate, iron nitrate, nickel nitrate, cobalt nitrate, chromium nitrate, manganese nitrate, platinum nitrate, strontium nitrate, nitrates of rare earth elements and zirconium nitrate.
Claim 20
Dependent Claim
73 words
The method of claim 6 wherein said halide is selected from the group consisting of lithium chloride, sodium chloride, potassium chloride, copper chloride, magnesium chloride, calcium chloride, barium chloride, zinc chloride, aluminum chloride, tin chloride, iron chloride, nickel chloride, cobalt chloride, chromium chloride, molybdenum chloride, manganese chloride, platinum chloride, strontium chloride, chlorides of rare earth elements, zirconium chloride, tungsten chloride, sodium fluoride, sodium bromide, sodium iodide, potassium fluoride, potassium bromide and potassium iodide.
Claim 21
Dependent Claim
28 words
The method of claim 6 wherein said double salt is selected from the group consisting of Mohr's salt, potassium alum, sodium alum, ammonium alum and ammonium iron alum.
Claim 22
Dependent Claim
12 words
The method of claim 7 wherein said double salt is Reinecke's salt.
Claim 23
Dependent Claim
35 words
The method of claim 8 wherein said carboxylic acid is selected from the group consisting of formic acid, acetic acid, oxalic acid, tartaric acid, succinic acid, maleic acid, salicylic acid, glycolic acid and gluconic acid.
Claim 24
Dependent Claim
12 words
The method of claim 8 wherein said aminocarboxylic acid is glutamic acid.
Claim 25
Dependent Claim
22 words
The method of claim 8 wherein said organic sulfonic acid is selected from the group consisting of 1-naphthylamine-2-sulfonic acid and 2-nitrobenzenesulfonic acid.
Claim 26
Dependent Claim
41 words
The method of claim 8 wherein said alkali metal salt is selected from the group consisting of the alkali metal salts of formic acid, acetic acid, oxalic acid, tartaric acid, succinic acid, maleic acid, salicylic acid, glycolic acid and gluconic acid.
Claim 27
Dependent Claim
27 words
The method of claim 8 wherein said alkali metal salt is selected from the group consisting of the alkali metal salts of glutamic acid and ethylenediaminetetraacetic acid.
Claim 28
Dependent Claim
27 words
The method of claim 8 wherein said alkali metal salt is selected from the group consisting of the alkali metal salts of 1-naphthylamine-2-sulfonic acid and 2-nitrobenzenesulfonic acid.
Claim 29
Dependent Claim
25 words
The method of claim 9 wherein said polyvalent aliphatic alcohol is selected from the group consisting of glycerin, mannitol, sorbitol, glucose, ethyleneglycol, propyleneglycol and sucrose.
Claim 30
Dependent Claim
34 words
The method of claim 10 wherein said water-soluble high polymer is selected from the group consisting of gelatin, gum Arabic, starch, sodium salt of carboxymethylcellulose, methylcellulose, polyethylene oxide, polyvinyl alcohol, polyacrylic acid and polyacrylamide.
Claim 31
Dependent Claim
66 words
The method of claim 11 wherein said water-soluble surface active agent is selected from the group consisting of polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monolaurate, polyoxyethylene stearate, polyoxyethylene laurate, polyoxyethylene lauryl ether, polyoxyethylene cetylether, polyoxyethylene nonyl phenyl ether, polyoxyethylene octyl phenyl ether, polyoxyethylene glycerin monostearate, sodium stearate, sodium 4-dodecylbenzene sulfonate, sodium laurylsulfate, laurylamine hydrochloride, dodecylamine acetate, cetyl pyridiniun bromide, cetyl pyridinium chloride, alkyldimethylbenzylammonium chloride and cetyltrimethylammonium bromide.
Claim 32
Dependent Claim
108 words
The method of claim 12 wherein said water-soluble organic dye is selected from the group consisting of Acid Fast Black BR, Acid Complex Green BL, Acid Cyanamine Green G, Light Green SF, Soluble Blue I, Chrome Yellow G, Chrome Yellow M, Chrome Blue Black BC, Chrome Brown RH, Fast Light Yellow G, Acid Fast Yellow R, Alizarin Red, Astrazon Yellow 3G, Astrazon Yellow 5G, Basic Cyanine 6G, Methylene Blue, Basic Furanin 8G, Methyl Violet, Direct Fast Brown, Brown RT, Direct Dark Green B, Direct Copper Blue BB, Direct Sky Blue 5B, Direct Fast Blue G, Direct Violet N, Procion Yellow HA, Remazol Yellow G and Remazol Red 3B.
Claim 33
Dependent Claim
24 words
The method of claim 1 wherein said compound is selected from the group consisting of purpureo salt, aniline anhydrochloride, guanidine carbonate and sulfamic acid.
Claim 34
Dependent Claim
25 words
The method of claim 1 wherein the amount of said coatings is in the range of from about between 0.005 to 500 g/m 2 .
Claim 35
Dependent Claim
25 words
The method of claim 1 wherein the amount of said coatings is in the range of from about between 0.05 to 100 g/m 2 .
Claim 36
Dependent Claim
11 words
The method of claim 1 wherein said compound is a phenol.
Claim 37
Dependent Claim
23 words
The method of claim 35 wherein said phenol compound is selected from the group consisting of hydroquinone, resorcinol, pyrocatechol, pyrogallol, 2-aminophenol and 3-aminophenol.
References Cited (Backward Citations)
US3515709A
Cited
FR2105579A5
Cited
US3778423A
Cited
DE2357869A1
Cited
US3926910A
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US4016341A
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US4024330A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-03 | 1982-01-02 | 1982-07-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-03 | 1986-01-02 | 1986-07-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-03 | 1990-01-02 | 1990-07-04 | $7700.00 | Window Closed / Lapsed |