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US4098734A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymeric alloy composition

Assignee: Bayer Antwerpen NV
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Filing: 1977-03-17
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Granted: 1978-07-04
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Expires: 1997-03-17
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Abstract

Abstract The present invention relates to a fusible polymeric alloy composition comprising (A) a matrix interpolymer, (B) a grafted diene rubber, (C) a polymer other than (A) or (B) having a solubility parameter in the range of 8.5 to 13 and (D) an inorganic filler. Said alloy having low thermal expansion, high modulus and toughness yet unexpectedly superior processing and molding properties for highly filled alloys.

Inventors

  • 👤 Yoon C. Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:58
CPC Classifications
C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/12; C08L2205/00; C08L2205/02; C08L55/00; C08L55/02

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 86 words
A fusible polymeric alloy composition comprising a blend of: A. a matrix interpolymer comprising polymerized monovinylidene aromatic and ethylenically unsaturated nitrile monomers, B. a grafted rubber copolymer having a diene rubber as a substrate grafted with said monomers as superstrate interpolymers, C. a polymer other than (A) or (B) having a solubility parameter in the range of 8.5 to 13, said polymer (C) being selected from the group consisting of polymethylmethacrylate, polycarbonate, polyphenylene ether, cellulose butyrate, polyester, polyamide and mixtures thereof, and D. an inorganic filler.
Claim 2
Dependent Claim 86 words
A fusible polymeric alloy composition comprising a blend of: A. a matrix interpolymer comprising polymerized monovinylidene aromatic and ethylenically unsaturated nitrile monomers, B. a grafted rubber copolymer having a diene rubber as a substrate grafted with said monomers as superstrate interpolymers, C. a polymer other than (A) or (B) having a solubility parameter in the range of 8.5 to 13, said polymer (C) being selected from the group consisting of polymethylmethacrylate, polycarbonate, polyphenylene ether, cellulose butyrate, polyester, polyamide and mixtures thereof, and D. an inorganic filler.
Claim 3
Dependent Claim 36 words
A composition of claim 1 wherein (A) is present in amounts of from about 50 to 94%, (B) 2 to 35%, (C) 2 to 40% and (D) 2 to 25% by weight based on said composition.
Claim 4
Dependent Claim 20 words
A composition of claim 1 wherein said diene rubber is polybutadiene, copolymers of butadiene with styrene, acrylonitrile or mixtures thereof.
Claim 5
Dependent Claim 43 words
A composition of claim 1 wherein said graft copolymer comprises a first graft copolymer having a rubber particle size of from about 0.5 to 1.5 microns and a second graft copolymer having a rubber particle size of from about 0.01 to 0.5 microns.
Claim 6
Dependent Claim 43 words
A composition of claim 1 wherein said graft copolymer has a rubber particle size of from about 0.5 to 1.5 microns having present grafted and occluded copolymer of said monomer in amounts of from about 1 to 4 parts per part of rubber.
Claim 7
Dependent Claim 67 words
A composition of claim 1 wherein said matrix interpolymer has said monovinylidene aromatic monomer present in amounts of from about 55 to 85% by weight of said interpolymer and said ethylenically unsaturated nitrile monomer present in amounts of from about 15 to 45% by weight of said interpolymer and wherein said grafted diene rubber copolymer has grafted interpolymers of substantially the same compositions as said matrix interpolymers.
Claim 8
Dependent Claim 44 words
A composition of claim 1 wherein said filler is selected from the group consisting of clay, carbon black, silica, metals, metal oxides, metal carbonate, metal sulfate, calcium silicate, diatomaceous earth, Fuller earth, mica, talc, slate flour, volcanic ash, dolomite, barium ferrite and mixtures thereof.
Claim 9
Dependent Claim 20 words
A composition of claim 1 wherein said monovinylidene aromatic monomer is styrene and said ethylenically unsaturated nitrile monomer is acrylonitrile.
Claim 10
Dependent Claim 23 words
A composition of claim 1 wherein said grafted diene rubber has a graft superstrate to rubber substrate ratio of about 50:100 to 200:100.
Claim 11
Dependent Claim 24 words
A composition of claim 1 wherein said diene rubber contains at least about 75% by weight of a conjugated diene 1,3 rubber forming monomer.

References Cited (Backward Citations)

US3780134A Cited
US3901839A Cited
US3930073A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-07-03 1982-01-02 1982-07-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-07-03 1986-01-02 1986-07-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-07-03 1990-01-02 1990-07-04 $7700.00 Window Closed / Lapsed

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