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US4093614A
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Metal complexes of nitrogen compounds
Assignee: Mobil Oil AS
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Filing: 1975-12-09
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Granted: 1978-06-06
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Expires: 1995-12-09
Abstract
Abstract Multiple metal complexes of nitrogen compounds are prepared by reacting in any desired order (1) an organic reactant, preferably an alkenylsuccinic acid or anhydride or a polyalkylphenol-aldehyde reaction mixture, or a halogenated polyolefin; (2) a polyamine, having one nitrogen atom reactive with the organic reactant and at least one additional nitrogen atom such as an ethylene polyamine and the imidazoline or imidazolidine derivative thereof; (3) and at least two metal compounds, one of which is a metal of Groups IB, IIB, IVA, IVB, VB, VIB, VIIB or VIII of the Periodic Table, capable of both forming a coordinated complex of the Werner type with the polyamine and also forming a complex with the second metal compound, and the said metal compound of metals of the above groups plus alkali and alkaline earth metals. The reactants may be reacted in any order, such as the above order, or the amine reactant may be precomplexed. Lubricant, grease, fuel and aqueous compositions are provided detergency and anti-wear properties by the presence of these multiple complexes.
Inventors
- 👤 Sheldon Chibnik
- 👤 Ferdinand P. Otto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 11:51
CPC Classifications
C; C10; C10L; C10L10/00; C10L10/08; C07; C07F; C07F19/00; C07F19/005; C10L1/00; C10L1/10; C10L1/14; C10L1/22; C10L1/221; C10L1/24; C10L1/2493; C10L1/26; C10L1/2691; C10L10/04; C10M; C10M159/00; C10M159/12; C10M159/18; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/14; C10M2215/22; C10M2215/221; C10M2215/223; C10M2215/224; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/30; C10M2217/00; C10M2217/04; C10M2217/042; C10M2217/043; C10M2217/046; C10M2217/06; C10M2219/00; C10M2219/04; C10M2219/044; C10M2219/08; C10M2219/082; C10M2219/087; C10M2219/088; C10M2219/089; C10M2221/00; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/042; C10M2223/06; C10M2223/061; C10M2223/065; C10N; C10N2010/00; C10N2010/02; C10N2010/04; C10N2010/08; C10N2010/12; C10N2010/14; C10N2010/16; C10N2040/00; C10N2040/08; C10N2050/00; C10N2050/10; F; F02; F02B; F02B75/00; F02B75/02; F02B2075/022; F02B2075/027
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
171 words
A double complex salt product which is a complex of a coordinated complex of the Werner type, said double complex salt product consisting essentially of the reaction product of (1) an alkenyl succinic anhydride in which the alkenyl group contains from 8 to about 500 carbon atoms, (2) a member selected from the group consisting of ##STR10## wherein n is a number from 1 to 10, m is a number from 2 to 10, p is a number from 3 to 10, R' is alkylene of 2 to 5 carbon atoms and R" is hydrogen or a hydrocarbyl group of 1 to 30 carbon atoms, (3) a first metal compound consisting essentially of a metal of Periodic Groups IB, IIB, IVA, IVB, VB VIB, VIIB, or VIII which forms a complex with reactant (2) and (4) a second metal compound, different from (3), selected from the group consisting of (3), and alkali and alkaline earth metal oxides, hydroxides, halides and carboxylates of monocarboxylic acids having from 1 to 30 carbon atoms.
Claim 2
Dependent Claim
171 words
A double complex salt product which is a complex of a coordinated complex of the Werner type, said double complex salt product consisting essentially of the reaction product of (1) an alkenyl succinic anhydride in which the alkenyl group contains from 8 to about 500 carbon atoms, (2) a member selected from the group consisting of ##STR10## wherein n is a number from 1 to 10, m is a number from 2 to 10, p is a number from 3 to 10, R' is alkylene of 2 to 5 carbon atoms and R" is hydrogen or a hydrocarbyl group of 1 to 30 carbon atoms, (3) a first metal compound consisting essentially of a metal of Periodic Groups IB, IIB, IVA, IVB, VB VIB, VIIB, or VIII which forms a complex with reactant (2) and (4) a second metal compound, different from (3), selected from the group consisting of (3), and alkali and alkaline earth metal oxides, hydroxides, halides and carboxylates of monocarboxylic acids having from 1 to 30 carbon atoms.
Claim 3
Dependent Claim
18 words
The product of claim 1 wherein reactant (2) has an average number of nitrogen atoms equivalent to tetraethylenepentamine.
Claim 4
Dependent Claim
31 words
The product of claim 1 wherein reactant (2) is selected from the group consisting of the imidazoline of tetraethylenepentamine and a monocarboxylic acid and the imidazolidine of tetraethylenepentamine and an aldehyde.
Claim 5
Dependent Claim
69 words
The double complex salt product of claim 1 in which (3) is a salt of an acid selected from the class consisting of: (a) R'" (COOH) n (b) sulfuric or sulfurous, (c) nitric, (d) R'"-SO 3 H (e) (R'"O) 2 -P-OH (f) ##STR11## wherein n is 1 to 100; R'" is hydrogen, or a hydrocarbyl group having from 1 to about 300 carbon atoms; and X is R'" hydroxy.
Claim 6
Dependent Claim
12 words
The product of claim 4 wherein reactant (3) is a zinc salt.
Claim 7
Dependent Claim
32 words
The product of claim 4 wherein reactant (3) is selected from the group consisting of zinc alkylbenzene sulfonate having at least 12 carbon atoms in the alkyl group and zinc methane sulfonate.
Claim 8
Dependent Claim
11 words
The product of claim 4 wherein reactant (3) is zinc oleate.
Claim 9
Dependent Claim
11 words
The product of claim 4 wherein reactant (3) is an organophosphate.
Claim 10
Dependent Claim
11 words
The product of claim 8 wherein reactant (3) is a nonylphenylphosphate.
Claim 11
Dependent Claim
23 words
The product of claim 7 wherein reactant (4) is selected from the group consisting of zinc, alkali metal and alkaline earth metal carboxylates.
Claim 12
Dependent Claim
11 words
The product of claim 7 wherein reactant (4) is zinc acetate.
Claim 13
Dependent Claim
20 words
The product of claim 4 wherein reactant (3) is provided by reacting alkenylsuccinic anhydride with a metal oxide or hydroxide.
Claim 14
Dependent Claim
44 words
The product of claim 1 wherein the amine of reactant (2) is first complexed with reactant (3), then reacted with reactant (1) to form a single complexed intermediate, and then reacting said complexed intermediate with reactant (4) to provide said double complex salt product.
Claim 15
Dependent Claim
61 words
The product of claim 1 wherein reactant (1) is an alkenylsuccinic anhydride having from 20 to 300 carbon atoms in the alkenyl group, reactant (2) is a polyamine of the formula H 2 N(CH 2 CH 2 NH) n H where n is an integer from 1 to 10, reactant (3) is zinc waxbenzene sulfonate and reactant (4) is zinc acetate.
Claim 16
Dependent Claim
100 words
A composition consisting essentially of the reaction product formed at temperatures of from about 20° C. to about 250° C. of (1) An alkenylsuccinic anhydride; (2) An alkylene polyamide having the formula H.sub.2 N--(R'NH).sub.n --H wherein n is a number from 1 to 10 and R' is an alkylene of 2 to 5 carbon atoms; (3) an organo sulfonate of a metal of Periodic Groups IB, IIB, IVA, IVB, VB, VIB, VIIB, or VIII; and (4) a carboxylate containing from 1 to 30 carbon atoms of a metal of Periodic Groups IB, IIB, IVA, IVB, VB, VIB, VIIB or VIII.
Claim 17
Dependent Claim
100 words
A composition consisting essentially of the reaction product formed at temperatures of from about 20° C. to about 250° C. of (1) An alkenylsuccinic anhydride; (2) An alkylene polyamide having the formula H.sub.2 N--(R'NH).sub.n --H wherein n is a number from 1 to 10 and R' is an alkylene of 2 to 5 carbon atoms; (3) an organo sulfonate of a metal of Periodic Groups IB, IIB, IVA, IVB, VB, VIB, VIIB, or VIII; and (4) a carboxylate containing from 1 to 30 carbon atoms of a metal of Periodic Groups IB, IIB, IVA, IVB, VB, VIB, VIIB or VIII.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-05 | 1981-12-05 | 1982-06-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-05 | 1985-12-05 | 1986-06-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-05 | 1989-12-05 | 1990-06-06 | $7700.00 | Window Closed / Lapsed |