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US4093580A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for treating aqueous mediums containing magnesium sulfite trihydrate

Assignee: Veolia WTS USA Inc
•
Filing: 1976-08-05
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Granted: 1978-06-06
•
Expires: 1996-08-05
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Abstract

Abstract A method is disclosed for treating an aqueous medium containing magnesium sulfite tri-hydrate under precipitating conditions comprising adding in combination to the aqueous medium an effective amount for the purpose of an oligomer and a copolymer of a 1-olefin and an unsaturated anhydride.

Inventors

  • 👤 Robert L. Jones
  • 👤 Lewis Volgenau
  • 👤 Philip S. Davis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 01:56
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501; C; C02; C02F; C02F5/00; C02F5/08; C02F5/10; Y; Y10; Y10S; Y10S526/00; Y10S526/91; Y10S526/911

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 227 words
A method for dispersing magnesium sulfite tri-hydrate contained in an aqueous medium comprising adding in combination to the medium an effective amount for the purpose as a dispersant of (i) an oligomer having the formula: ##STR5## where R 1 , R 2 , R 3 and R 4 are the same or different and are selected from the group consisting of hydrogen, methyl and ethyl, Y is at least one member selected from the group consisting of --COOH, --COOM, --CONH 2 , --OCH 3 , --OC 2 H 5 , --CH 2 OH, and ##STR6## X is one or more members selected from the group consisting of --COOC 2 H 4 OH, --COOC 3 H 6 OH, --CONHCH 2 OH, --CONHCH 3 , --CONHC 2 H 5 , --CONHC 3 H 7 , --CONHC 8 H 17 , --COOCH 3 , --COOC 2 H 5 , --CN, --OOCCH 3 , --OOCC 2 H 5 , and --CONHC(CH 3 ) 2 --CH 2 COCH 3 , a+b is 4 to 250, a/(a+b) is between 0.0 and 0.6, and M is a water soluble cation of a bisulfite salt; and (ii) an effective metal salt of a copolymer of a 1-olefin having from 4 to 16 carbon atoms and a compound having the formula: ##STR7## where R is individually selected from the group consisting of hydrogen, methyl and ethyl.
Claim 2
Independent Claim 227 words
A method for dispersing magnesium sulfite tri-hydrate contained in an aqueous medium comprising adding in combination to the medium an effective amount for the purpose as a dispersant of (i) an oligomer having the formula: ##STR5## where R 1 , R 2 , R 3 and R 4 are the same or different and are selected from the group consisting of hydrogen, methyl and ethyl, Y is at least one member selected from the group consisting of --COOH, --COOM, --CONH 2 , --OCH 3 , --OC 2 H 5 , --CH 2 OH, and ##STR6## X is one or more members selected from the group consisting of --COOC 2 H 4 OH, --COOC 3 H 6 OH, --CONHCH 2 OH, --CONHCH 3 , --CONHC 2 H 5 , --CONHC 3 H 7 , --CONHC 8 H 17 , --COOCH 3 , --COOC 2 H 5 , --CN, --OOCCH 3 , --OOCC 2 H 5 , and --CONHC(CH 3 ) 2 --CH 2 COCH 3 , a+b is 4 to 250, a/(a+b) is between 0.0 and 0.6, and M is a water soluble cation of a bisulfite salt; and (ii) an effective metal salt of a copolymer of a 1-olefin having from 4 to 16 carbon atoms and a compound having the formula: ##STR7## where R is individually selected from the group consisting of hydrogen, methyl and ethyl.
Claim 3
Dependent Claim 46 words
The method of claim 1, wherein a + b is about 1 to 100, Y is selected from the group consisting of --COOM, --COOH, --CONH 2 , --OCH 3 , --OC 2 H 5 , and --CH 2 OH, and wherein X is the group --CN.
Claim 4
Dependent Claim 9 words
The method of claim 2, wherein Y is --COOM.
Claim 5
Dependent Claim 9 words
The method of claim 3, wherein Y is --COONa.
Claim 6
Dependent Claim 14 words
The method of claim 2, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 7
Dependent Claim 14 words
The method of claim 3, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 8
Dependent Claim 14 words
The method of claim 4, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 9
Dependent Claim 25 words
The method of claim 1, wherein the oligomer is present in the combination in an amount of from about 10% to about 90% by weight.
Claim 10
Dependent Claim 46 words
The method of claim 8, wherein a + b is about 1 to 100, Y is selected from the group consisting of --COOM, --COOH, --CONH 2 , --OCH 3 , --OC 2 H 5 , and --CH 2 OH, and wherein X is the group --CN.
Claim 11
Dependent Claim 9 words
The method of claim 9, wherein Y is --COOM.
Claim 12
Dependent Claim 9 words
The method of claim 10, wherein Y is --COONa.
Claim 13
Dependent Claim 14 words
The method of claim 9, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 14
Dependent Claim 14 words
The method of claim 10, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 15
Dependent Claim 14 words
The method of claim 11, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 16
Dependent Claim 31 words
The method of claim 8, wherein the combination is added to the aqueous medium in an amount of from about 1 to about 1,000 parts per million parts of aqueous medium.
Claim 17
Dependent Claim 31 words
The method of claim 15, wherein the combination is added to the aqueous medium in an amount of from about 5 to about 100 parts per million parts of aqueous medium.
Claim 18
Dependent Claim 21 words
The method of claim 1, wherein the aqueous medium is the scrubber medium for a magnesium oxide based gas scrubber system.
Claim 19
Dependent Claim 46 words
The method of claim 17, wherein a + b is about 10 to 100, Y is selected from the group consisting of --COOM, --COOH, --CONH 2 , --OCH 3 , --OC 2 H 5 , and --CH 2 OH, and wherein X is the group --CN.
Claim 20
Dependent Claim 9 words
The method of claim 18, wherein Y is --COOM.
Claim 21
Dependent Claim 9 words
The method of claim 19, wherein Y is --COONa.
Claim 22
Dependent Claim 14 words
The method of claim 18, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 23
Dependent Claim 14 words
The method of claim 19, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 24
Dependent Claim 14 words
The method of claim 20, wherein the 1-olefin is diisobutylene and R is hydrogen.
Claim 25
Dependent Claim 25 words
The method of claim 17, wherein the oligomer is present in the combination in an amount of from about 10% to about 90% by weight.
Claim 26
Dependent Claim 31 words
The method of claim 17, wherein the combination is added to the aqueous medium in an amount of from about 1 to about 1,000 parts per million parts of aqueous medium.
Claim 27
Dependent Claim 31 words
The method of claim 17, wherein the combination is added to the aqueous medium in an amount of from about 5 to about 100 parts per million parts of aqueous medium.
Claim 28
Dependent Claim 19 words
The method of claim 1, wherein the pH of the aqueous medium is from about 7 to about 9.
Claim 29
Dependent Claim 19 words
The method of claim 17, wherein the pH of the aqueous medium is from about 7 to about 9.
Claim 30
Dependent Claim 19 words
The method of claim 21, wherein the pH of the aqueous medium is from about 7 to about 9.
Claim 31
Dependent Claim 19 words
The method of claim 24, wherein the pH of the aqueous medium is from about 7 to about 9.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-05 1981-12-05 1982-06-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-05 1985-12-05 1986-06-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-05 1989-12-05 1990-06-06 $7700.00 Window Closed / Lapsed

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