Patent US4093278A successfully refreshed from Google Patents.
US4093278A
Expired / Lapsed
US
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Dye solvents for pressure-sensitive copying systems
Assignee: Monsanto Co
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Filing: 1976-12-27
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Granted: 1978-06-06
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Expires: 1996-12-27
Abstract
Abstract Solvents useful to dissolve dyes employed in pressure-sensitive copying systems comprise aryl esters of benzoic or substituted benzoic acid having the structure: <IMAGE> wherein R1 is hydrogen, methyl or ethyl; R2 is hydrogen or C1 to C9 alkyl; R3 is hydrogen, methyl or ethyl; and n is zero or 1.
Inventors
- 👤 James Kern Sears
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-10 01:34
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/165; B41M5/1655; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/25; Y10T428/252; Y10T428/254; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
111 words
A pressure-sensitive recording system comprising (a) supporting sheet material, (b) mark forming components arranged in contiguous juxtaposition and supported by said sheet material, said components comprising a chromogenic material held within microcapsules and an electron accepting material of the Lewis acid type reactive with said chromogenic material to produce a mark when brought into reactive contact, and (c) a pressure releasable solvent for said chromogenic mark forming component, said solvent comprising an aryl ester represented by the structure ##STR5## wherein R 1 is hydrogen, methyl or ethyl; R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 2
Dependent Claim
111 words
A pressure-sensitive recording system comprising (a) supporting sheet material, (b) mark forming components arranged in contiguous juxtaposition and supported by said sheet material, said components comprising a chromogenic material held within microcapsules and an electron accepting material of the Lewis acid type reactive with said chromogenic material to produce a mark when brought into reactive contact, and (c) a pressure releasable solvent for said chromogenic mark forming component, said solvent comprising an aryl ester represented by the structure ##STR5## wherein R 1 is hydrogen, methyl or ethyl; R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 3
Dependent Claim
28 words
A system of claim 1 wherein the electron accepting material of the Lewis acid type is selected from the group consisting of acidic clay and acidic organic polymers.
Claim 4
Dependent Claim
28 words
A system of claim 1 wherein the chromogenic material is dissolved in the solvent prior to bringing said chromogenic material and said electron accepting material into reactive contact.
Claim 5
Dependent Claim
21 words
A system of claim 1 wherein the mark forming components and the solvent are present on a single support paper sheet.
Claim 6
Dependent Claim
13 words
A system of claim 1 wherein the chromogenic material comprises a phthalide compound.
Claim 7
Dependent Claim
19 words
A system of claim 2 wherein the electron accepting material of the Lewis acid type is a phenolic polymer.
Claim 8
Dependent Claim
26 words
A system of claim 1 wherein R 1 is hydrogen; R 2 is methyl, ethyl or t-butyl; R 3 is hydrogen; and n is a 1.
Claim 9
Dependent Claim
14 words
A system of claim 1 wherein the solvent is represented by the structure ##STR6##
Claim 10
Dependent Claim
133 words
A pressure-sensitive recording system comprising (a) a first support sheet having disposed thereon a coating of a pressure releasable marking fluid held within microcapsules, and (b) A second supporting sheet having disposed thereon a coating of an electron accepting material of the Lewis acid type arranged in contiguous juxtaposition with the coating on said first supporting sheet, said marking fluid comprising a solvent and a colorless or substantially colorless chromogenic material dissolved therein, said chromogenic material being reactive with said Lewis acid type material to produce a colored mark and said solvent comprising an aryl ester represented by the structure ##STR7## wherein R 1 is hydrogen, methyl or ethyl, R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 11
Dependent Claim
133 words
A pressure-sensitive recording system comprising (a) a first support sheet having disposed thereon a coating of a pressure releasable marking fluid held within microcapsules, and (b) A second supporting sheet having disposed thereon a coating of an electron accepting material of the Lewis acid type arranged in contiguous juxtaposition with the coating on said first supporting sheet, said marking fluid comprising a solvent and a colorless or substantially colorless chromogenic material dissolved therein, said chromogenic material being reactive with said Lewis acid type material to produce a colored mark and said solvent comprising an aryl ester represented by the structure ##STR7## wherein R 1 is hydrogen, methyl or ethyl, R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 12
Dependent Claim
25 words
A system of claim 9 wherein R 1 is hydrogen; R 2 is methyl, ethyl or t-butyl; R 3 is hydrogen, and n is 1.
Claim 13
Dependent Claim
13 words
A system of claim 9 wherein the chromogenic material comprises a phthalide compound.
Claim 14
Dependent Claim
19 words
A system of claim 9 wherein the electron accepting material of the Lewis acid type is a phenolic polymer.
Claim 15
Dependent Claim
11 words
A system of claim 9 wherein the solvent is benzyl benzoate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-06-05 | 1981-12-05 | 1982-06-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-06-05 | 1985-12-05 | 1986-06-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-06-05 | 1989-12-05 | 1990-06-06 | $7700.00 | Window Closed / Lapsed |