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US4093278A Expired / Lapsed US ⏱️ 0.0 years remaining

Dye solvents for pressure-sensitive copying systems

Assignee: Monsanto Co
•
Filing: 1976-12-27
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Granted: 1978-06-06
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Expires: 1996-12-27
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Abstract

Abstract Solvents useful to dissolve dyes employed in pressure-sensitive copying systems comprise aryl esters of benzoic or substituted benzoic acid having the structure: <IMAGE> wherein R1 is hydrogen, methyl or ethyl; R2 is hydrogen or C1 to C9 alkyl; R3 is hydrogen, methyl or ethyl; and n is zero or 1.

Inventors

  • 👤 James Kern Sears

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-10 01:23
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/124; B41M5/165; B41M5/1655; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/25; Y10T428/252; Y10T428/254; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 111 words
A pressure-sensitive recording system comprising (a) supporting sheet material, (b) mark forming components arranged in contiguous juxtaposition and supported by said sheet material, said components comprising a chromogenic material held within microcapsules and an electron accepting material of the Lewis acid type reactive with said chromogenic material to produce a mark when brought into reactive contact, and (c) a pressure releasable solvent for said chromogenic mark forming component, said solvent comprising an aryl ester represented by the structure ##STR5## wherein R 1 is hydrogen, methyl or ethyl; R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 2
Dependent Claim 111 words
A pressure-sensitive recording system comprising (a) supporting sheet material, (b) mark forming components arranged in contiguous juxtaposition and supported by said sheet material, said components comprising a chromogenic material held within microcapsules and an electron accepting material of the Lewis acid type reactive with said chromogenic material to produce a mark when brought into reactive contact, and (c) a pressure releasable solvent for said chromogenic mark forming component, said solvent comprising an aryl ester represented by the structure ##STR5## wherein R 1 is hydrogen, methyl or ethyl; R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 3
Dependent Claim 28 words
A system of claim 1 wherein the electron accepting material of the Lewis acid type is selected from the group consisting of acidic clay and acidic organic polymers.
Claim 4
Dependent Claim 28 words
A system of claim 1 wherein the chromogenic material is dissolved in the solvent prior to bringing said chromogenic material and said electron accepting material into reactive contact.
Claim 5
Dependent Claim 21 words
A system of claim 1 wherein the mark forming components and the solvent are present on a single support paper sheet.
Claim 6
Dependent Claim 13 words
A system of claim 1 wherein the chromogenic material comprises a phthalide compound.
Claim 7
Dependent Claim 19 words
A system of claim 2 wherein the electron accepting material of the Lewis acid type is a phenolic polymer.
Claim 8
Dependent Claim 26 words
A system of claim 1 wherein R 1 is hydrogen; R 2 is methyl, ethyl or t-butyl; R 3 is hydrogen; and n is a 1.
Claim 9
Dependent Claim 14 words
A system of claim 1 wherein the solvent is represented by the structure ##STR6##
Claim 10
Dependent Claim 133 words
A pressure-sensitive recording system comprising (a) a first support sheet having disposed thereon a coating of a pressure releasable marking fluid held within microcapsules, and (b) A second supporting sheet having disposed thereon a coating of an electron accepting material of the Lewis acid type arranged in contiguous juxtaposition with the coating on said first supporting sheet, said marking fluid comprising a solvent and a colorless or substantially colorless chromogenic material dissolved therein, said chromogenic material being reactive with said Lewis acid type material to produce a colored mark and said solvent comprising an aryl ester represented by the structure ##STR7## wherein R 1 is hydrogen, methyl or ethyl, R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 11
Dependent Claim 133 words
A pressure-sensitive recording system comprising (a) a first support sheet having disposed thereon a coating of a pressure releasable marking fluid held within microcapsules, and (b) A second supporting sheet having disposed thereon a coating of an electron accepting material of the Lewis acid type arranged in contiguous juxtaposition with the coating on said first supporting sheet, said marking fluid comprising a solvent and a colorless or substantially colorless chromogenic material dissolved therein, said chromogenic material being reactive with said Lewis acid type material to produce a colored mark and said solvent comprising an aryl ester represented by the structure ##STR7## wherein R 1 is hydrogen, methyl or ethyl, R 2 is hydrogen or C 1 to C 9 alkyl; R 3 is hydrogen, methyl or ethyl; and n is zero or 1.
Claim 12
Dependent Claim 25 words
A system of claim 9 wherein R 1 is hydrogen; R 2 is methyl, ethyl or t-butyl; R 3 is hydrogen, and n is 1.
Claim 13
Dependent Claim 13 words
A system of claim 9 wherein the chromogenic material comprises a phthalide compound.
Claim 14
Dependent Claim 19 words
A system of claim 9 wherein the electron accepting material of the Lewis acid type is a phenolic polymer.
Claim 15
Dependent Claim 11 words
A system of claim 9 wherein the solvent is benzyl benzoate.

References Cited (Backward Citations)

US2646367A Cited
US3427180A Cited
US3684549A Cited
US4018728A Cited
US3968320A Cited
US4021059A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-06-05 1981-12-05 1982-06-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-06-05 1985-12-05 1986-06-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-06-05 1989-12-05 1990-06-06 $7700.00 Window Closed / Lapsed

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