Hot-melt adhesive compound and method for the production of the same

Claim 2

A hot-melt adhesive compound, to be applied to a carrier in a molten state, having a molecular weight from about 100,000 to about 1,000,000, said compound consisting essentially of a polymeric component, which is partially transversely cross-linked by cross-linkage bridges, the degree of cross-linkage being from about 0.1 to 10%, said polymeric component being selected from the group consisting of polybutadiene, polystyrene, polyisoprene, natural rubber, chlorinated butyl rubber, polyethylene, polypropylene, copolymers thereof and a mixture thereof; and a cross-linking component forming cross-linkage bridges, selected from at least one member of the group consisting of oxygen, nitrogen, urea, urethane, and methylene.

Claim 3

A hot-melt adhesive compound, as claimed in claim 1, wherein the cross-linkage is formed by at least one member of the group consisting of oxygen, and methylene.

Claim 4

A hot-melt adhesive compound, as claimed in claim 1, wherein the cross-linkage bridge is formed by at least one member of the group consisting of nitrogen, urea and urethane.

Claim 5

A hot-melt adhesive compound in accordance with claim 1, having a viscosity of about 10 6 to 10 9 cp at 120° to 130° C. and a high degree of continuous load and stress resistance.

Claim 6

A hot-melt adhesive compound in accordance with claim 1, wherein said polymeric component is selected from the group consisting of butadiene-styrene, block-polystyrene, isoprene-ethylene-propylene polymer, butadiene polymer, natural rubber, chloro-butyl rubber and mixtures thereof.

Claim 7

A process for preparing an adhesive compound having a molecular weight of from about 100,000 to about 1,000,000, wherein said adhesive compound is to be applied subsequently to a carrier in a molten state, comprising the steps homogenizing at a temperature range of from about 100° C to about 160° C at least one polymer component selected from the group consisting of polybutadiene, polystyrene, polyisoprene, natural rubber, chlorinated butyl rubber, polyethylene, polypropylene, copolymers thereof and a mixture thereof; reacting the polymeric component with a cross-linking agent selected from the group consisting of mono-isocyanates, di-isocyanates, tri-isocyanates, poly-isocyanates, aliphatic peroxides, and aromatic peroxides; bringing the temperature of said thus reacted polymeric component into the range of from about 80° C to about 120° C; and thereafter adding a cross-linking accelerator.

Claim 8

A process for preparing an adhesive compound having a molecular weight of from about 100,000 to about 1,000,000, wherein said adhesive compound is to be applied subsequently to a carrier in a molten state, comprising the steps homogenizing at a temperature range of from about 100° C to about 160° C at least one polymer component selected from the group consisting of polybutadiene, polystyrene, polyisoprene, natural rubber, chlorinated butyl rubber, polyethylene, polypropylene, copolymers thereof and a mixture thereof; reacting the polymeric component with a cross-linking agent selected from the group consisting of mono-isocyanates, di-isocyanates, tri-isocyanates, poly-isocyanates, aliphatic peroxides, and aromatic peroxides; bringing the temperature of said thus reacted polymeric component into the range of from about 80° C to about 120° C; and thereafter adding a cross-linking accelerator.

Claim 9

A process, as claimed in claim 6, wherein said cross-linking accelerator is a compound chosen from the group consisting of an ammonium salt of dithiocarbamic acid, sodium dithiocarbamate, zinc dithiocarbamate, mercapto-accelerators, sulfonamide-accelerators, aldehyde-amide-accelerators and p-benzoquinone dioxime.

Claim 10

A process, as claimed in claim 6, wherein the temperature range maintained during homogenization step is 130°-160° C and the temperature maintained during addition of the cross-linking accelerator is 100°-110° C.

Claim 11

A process, as claimed in claim 6, wherein said polymeric compound consists essentially of a mixture of butadiene-styrene polymer and isoprene; the temperature maintained during homogenization of the mixture being about 150° C; the temperature thereafter being brought to about 100° C; and subsequently the cross-linking agent consisting essentially of p-benzoquinone dioxide, is added.

Claim 12

A process, as claimed in claim 6, wherein the homogenizing step includes mastication.

Claim 13

A self-adhesive product comprising a carrier; and a hot-melt adhesive compound coated on said carrier and consisting essentially of a polymeric component, which is partially transversely cross-linked by cross-linkage bridges, the degree of cross-linkage being about 0.1 to 10%, said polymeric component being selected from the group consisting of polybutadiene, polystyrene, polyisoprene, natural rubber, chlorinated butyl rubber, polyethylene and polypropylene, copolymers thereof and a mixture thereof; and a cross-linking component forming the cross-linkage bridges selected from at least one member of the group consisting of oxygen, nitrogen, urea, urethane, and methylene.

Claim 14

A self-adhesive product comprising a carrier; and a hot-melt adhesive compound coated on said carrier and consisting essentially of a polymeric component, which is partially transversely cross-linked by cross-linkage bridges, the degree of cross-linkage being about 0.1 to 10%, said polymeric component being selected from the group consisting of polybutadiene, polystyrene, polyisoprene, natural rubber, chlorinated butyl rubber, polyethylene and polypropylene, copolymers thereof and a mixture thereof; and a cross-linking component forming the cross-linkage bridges selected from at least one member of the group consisting of oxygen, nitrogen, urea, urethane, and methylene.

Claim 15

A process for preparing an adhesive compound as claimed in claim 6, wherein said polymeric component is reacted with a cross-linking agent selected from the group consisting of aliphatic peroxides and aromatic peroxides.

Claim 18

A process for preparing an adhesive compound as claimed in claim 6, wherein said polymeric component is reacted with a cross-linking agent selected from the group consisting of mono-isocyanate, di-isocyanates, tri-isocyanates and poly-isocyanates.