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Process for the coloration of polyamides with pigments derived from carboxyamido-polyimides

Assignee: Produits Chimiques Ugine Kuhlmann
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Filing: 1975-08-04
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Granted: 1978-05-16
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Expires: 1995-08-04
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Abstract

Abstract Linear polyamides are colored with pigments of the formula: ##STR1## wherein R represents the tetravalent residue of a substituted mono- or poly-cyclic aromatic hydrocarbon or a substituted or unsubstituted perinone, R 1 represents a substituted or unsubstituted aliphatic, benzene, naphthalene or heterocyclic radical, R 2 represents a substituted or unsubstituted aliphatic, aromatic or heterocyclic radical and Y represents an amino or haloformyl group. A copolycondensate results.

Inventors

  • 👤 Philippe Yves Edouard Gangneux

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 16:26
CPC Classifications
C; C07; C07D; C07D487/00; C07D487/02; C07D487/04; C07D471/00; C07D471/02; C07D471/06; C08; C08G; C08G69/00; C08G69/02; C08G73/00; C08G73/06; C08G73/10; C08G73/14; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3437; C09; C09B; C09B5/00; C09B5/62; C09B57/00; C09B57/08

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 166 words
Process for the coloration of a linear polyamide which comprises effecting polycondensation of at least one amide monomer and a pigment that is insoluble in organic solvents, said pigment being of the polycyclic polycarboximide series containing 2 primary amine or haloformyl functional groups, wherein the pigment has the formula: ##STR7## wherein R represents the tetravalent residue of a substituted mono- or poly-cyclic aromatic hydrocarbon or a substituted or unsubstituted perinone, R 1 represents a substituted or unsubstituted aliphatic, benzene, naphthalene or heterocyclic radical, R 2 represents a substituted or unsubstituted aliphatic, aromatic or heterocyclic radical and Y represents an amino or haloformyl group; said pigment being copolycondensed in the polymer chain of said polyamide; wherein the proportion of said pigment is from 1%. (1 to 1000) to 2% (2 per 100) by weight of the monomer or monomers; and said at least one monomer is selected from the group consisting of 11-amino-undecanoic acid; ε-caprolactam; p-phenylenediamine, decamethylenediamine or hexamethylenediamine together with terephthalic, isophthalic, adipic or sebacic acid.
Claim 2
Dependent Claim 166 words
Process for the coloration of a linear polyamide which comprises effecting polycondensation of at least one amide monomer and a pigment that is insoluble in organic solvents, said pigment being of the polycyclic polycarboximide series containing 2 primary amine or haloformyl functional groups, wherein the pigment has the formula: ##STR7## wherein R represents the tetravalent residue of a substituted mono- or poly-cyclic aromatic hydrocarbon or a substituted or unsubstituted perinone, R 1 represents a substituted or unsubstituted aliphatic, benzene, naphthalene or heterocyclic radical, R 2 represents a substituted or unsubstituted aliphatic, aromatic or heterocyclic radical and Y represents an amino or haloformyl group; said pigment being copolycondensed in the polymer chain of said polyamide; wherein the proportion of said pigment is from 1%. (1 to 1000) to 2% (2 per 100) by weight of the monomer or monomers; and said at least one monomer is selected from the group consisting of 11-amino-undecanoic acid; ε-caprolactam; p-phenylenediamine, decamethylenediamine or hexamethylenediamine together with terephthalic, isophthalic, adipic or sebacic acid.
Claim 3
Dependent Claim 78 words
Process for the coloration of a linear polyamide which comprises effecting polycondensation of the monomer or monomers and a pigment that is insoluble in organic solvents, said pigment being obtained by condensing a compound of the formula (I) given in claim 1 wherein Y is a haloformyl group with a diamine of the formula: ##STR8## wherein R and R 2 have the meanings given in claim 1; said pigment being copolycondensed in the polymer chain of said polyamide.
Claim 4
Dependent Claim 29 words
Process according to claim 2 wherein the proportion of pigment is from 1% (1 to 1000) to 2% (2 per 100 ) by weight of the monomer or monomers.
Claim 5
Dependent Claim 11 words
A copolycondensate obtained according to the process claimed in claim 1.
Claim 6
Dependent Claim 11 words
A copolycondensate obtained according to the process claimed in claim 2.
Claim 7
Dependent Claim 31 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment having the formula: ##STR9##
Claim 8
Dependent Claim 31 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment having the formula: ##STR9##
Claim 9
Dependent Claim 31 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment having the formula: ##STR10##
Claim 10
Dependent Claim 31 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment having the formula: ##STR10##
Claim 11
Dependent Claim 31 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment having the formula: ##STR11##
Claim 12
Dependent Claim 31 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment having the formula: ##STR11##
Claim 13
Dependent Claim 45 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment consisting of a mixture of a cis form having the formula: ##STR12## and of the trans form thereof.
Claim 14
Dependent Claim 45 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment consisting of a mixture of a cis form having the formula: ##STR12## and of the trans form thereof.
Claim 15
Dependent Claim 57 words
A copolycondensate obtained according to the process for the coloration of a linear polyamide which comprises effecting the polycondensation of amide monomer or monomers and a pigment which is a hexa-imide resulting from the reaction of 1 mole of the dichloride of formula (V) in claim 11 with 2 moles of a diamine of the formula: ##STR13##

References Cited (Backward Citations)

US2668815A Cited
GB986556A Cited
US3658747A Cited
US3809670A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-15 1981-11-14 1982-05-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-15 1985-11-14 1986-05-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-15 1989-11-14 1990-05-16 $7700.00 Window Closed / Lapsed

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