Composition and method for drilling high temperature reservoirs

Claim 2

An aqueous clay-free foam drilling fluid for drilling a well into strata containing a high temperature fluid comprising about 99.5 to 90 volume percent of a gas and 0.5 to 10 volume percent of an aqueous dispersion containing (a) about 327 to 347 pounds per barrel of aqueous medium, (b) about 0.25 to 10 pounds per barrel of a water-soluble or water-dispersible foaming agent, (c) about 0.0005 to 1 pound per barrel of an organic agent that releases ammonia or a vaporous amine and forms a resinous residue at downhole temperature and pressure conditions comprising a tri-amine or tri-ammonium salt of an acidic triester of a C 1 to C 4 trialkanol amine as an erosion and corrosion inhibitor, said amine or ammonium salt having been formed by neutralizing said acidic triester with ammonia or a water soluble amine having from 1 to 15 carbon atoms and (d) about 0.25 to 3 pounds per barrel of a water-soluble or water-dispersible polyalkylene oxide polymer wherein the polyalkylene oxide is selected from the group consisting of polyethylene oxide, polypropylene oxide, and polybutylene oxide, said polymer having a molecular weight of from 10 5 to 10 8 , as a combination fluid loss control additive and foam stabilizer.

Claim 3

The composition defined in claim 1 wherein the high temperature fluid contained in the strata is a geothermal fluid.

Claim 4

The composition defined in claim 1 wherein the gas is selected from the group consisting of air, carbon dioxide, natural gas, combustion gases and nitrogen.

Claim 5

The composition defined in claim 1 wherein the aqueous medium is selected from the group consisting of fresh water, natural brine and synthetic brine.

Claim 6

The composition defined in claim 1 wherein the amine or ammonium salt has the formula: ##STR9## wherein R 1 is a bivalent hydrocarbyl radical containing about 8 to 44 carbon atoms, R 2 is an alkylene radical containing about 1 to 4 carbon atoms, and A is a water-soluble amine or ammonia.

Claim 7

The composition defined in claim 1 including in the aqueous dispersion about 0.03 to 1 pound per barrel of a bit lubricant comprising the condensation product of one mole of a saturated or unsaturated aliphatic monocarboxylic acid having about 8 to 20 carbon atoms with 5 to 20 moles of a lower alkene oxide.

Claim 8

The composition defined in claim 1 including in the aqueous dispersion about 1 to about 10 pounds per barrel of graphite.

Claim 9

In the method of drilling a well into subterranean strata containing a high temperature fluid wherein an aqueous clay-free foam drilling fluid is passed through the well in contact with the strata during the drilling operation, the improvement which comprises employing as the drilling fluid a composition about 99.5 to 90 volume percent of a gas and 0.5 to 10 volume percent of an aqueous dispersion containing (a) about 327 to 347 pounds per barrel of aqueous medium, (b) about 0.25 to 10 pounds per barrel of a water-soluble or water-dispersible foaming agent, (c) about 0.0005 to 1 pound per barrel of an organic agent that releases ammonia or a vaporous amine and forms a resinous residue at downhole temperature and pressure conditions comprising a tri-amine or tri-ammonium salt of an acidic triester of a C 1 to C 4 trialkanol amine as an erosion and corrosion inhibitor, said amine or ammonium salt having been formed by neutralizing said acidic triester with ammonia or a water soluble amine having from 1 to 15 carbon atoms (d) about 0.25 to 3 pounds per barrel of a water-soluble or water-dispersible polyalkylene oxide polymer wherein the polyalkylene oxide is selected from the group consisting of polyethylene oxide, polypropylene oxide and polybutylene oxide, said polymer having a molecular weight of from 10 5 to 10 8 , as a combination fluid loss control additive and foam stabilizer.

Claim 10

In the method of drilling a well into subterranean strata containing a high temperature fluid wherein an aqueous clay-free foam drilling fluid is passed through the well in contact with the strata during the drilling operation, the improvement which comprises employing as the drilling fluid a composition about 99.5 to 90 volume percent of a gas and 0.5 to 10 volume percent of an aqueous dispersion containing (a) about 327 to 347 pounds per barrel of aqueous medium, (b) about 0.25 to 10 pounds per barrel of a water-soluble or water-dispersible foaming agent, (c) about 0.0005 to 1 pound per barrel of an organic agent that releases ammonia or a vaporous amine and forms a resinous residue at downhole temperature and pressure conditions comprising a tri-amine or tri-ammonium salt of an acidic triester of a C 1 to C 4 trialkanol amine as an erosion and corrosion inhibitor, said amine or ammonium salt having been formed by neutralizing said acidic triester with ammonia or a water soluble amine having from 1 to 15 carbon atoms (d) about 0.25 to 3 pounds per barrel of a water-soluble or water-dispersible polyalkylene oxide polymer wherein the polyalkylene oxide is selected from the group consisting of polyethylene oxide, polypropylene oxide and polybutylene oxide, said polymer having a molecular weight of from 10 5 to 10 8 , as a combination fluid loss control additive and foam stabilizer.

Claim 11

The method defined in claim 8 wherein the high temperature fluid contained in the strata is a geothermal fluid.

Claim 12

The method defined in claim 8 wherein the gas is selected from the group consisting of air, carbon dioxide, natural gas, combustion gases and nitrogen.

Claim 13

The method defined in claim 8 wherein the aqueous medium is selected from the group consisting of fresh water, natural brine and synthetic brine.

Claim 14

The method defined in claim 8 wherein the amine or ammonium salt has the formula: ##STR10## wherein R 1 is a bivalent hydrocarbyl radical containing about 8 to 44 carbon atoms, R 2 is an alkylene radical containing about 1 to 4 carbon atoms, and A is a water-soluble amine or ammonia.

Claim 15

The method defined in claim 8 including in the aqueous dispersion about 0.03 to about 1 pound per barrel of a bit lubricant comprising the condensation product of one mole of a saturated or unsaturated aliphatic monocarboxylic acid having about 8 to 20 carbon atoms with 5 to 20 moles of a lower alkene oxide.

Claim 16

The method defined in claim 8 including in the aqueous dispersion about 1 to 10 pounds per barrel graphite.

Claim 17

The method defined in claim 8 wherein the drilling fluid is prepared by combining all ingredients of the drilling fluid at the surface in an agitated mixing device prior to circulation into the well.

Claim 18

The method defined in claim 8 wherein the drilling fluid is prepared by combining the ingredients of the aqueous dispersion at the surface in an agitated mixing device and injecting the aqueous dispersion and the gas down the well simultaneously.

Claim 19

The method defined in claim 8 wherein the drilling fluid is prepared by simultaneously but separately injecting into the well the gas, the aqueous medium, the foaming agent, the erosion and corrosion inhibitor and the combination fluid loss control additive and foam stabilizer.

Claim 20

In the method of drilling a well into a subterranean geothermal formation wherein there is passed through the well and in contact with the geothermal formation an aqueous clay-free foam drilling fluid composition comprising about 99.5 to 90 volume percent air and 0.5 to 10 volume percent of an aqueous dispersion containing (a) about 327 to 347 pounds per barrel of an aqueous medium selected from the group consisting of fresh water, natural brine and synthetic brine, (b) about 0.25 to 10 pounds per barrel of a water-soluble or a water-dispersible foaming agent, (c) about 0.0005 to 1 pound per barrel of a tri-amine or tri-ammonium salt having the formula: ##STR11## where R 1 is a bivalent hydrocarbyl radical containing about 8 to 44 carbon atoms, R 2 is an alkylene radical containing about 1 to 4 carbon atoms, and A is a water-soluble amine having from 1 to 15 carbon atoms or ammonia as an erosion and corrosion inhibitor, the improvement which comprises including in the aqueous dispersion about 0.25 to 3 pounds per barrel of a water-soluble or water-dispersible polyethylene oxide polymer having a molecular weight from 10 5 to 10 8 as a combination fluid loss control additive and foam stabilizer.

Claim 21

In the method of drilling a well into a subterranean geothermal formation wherein there is passed through the well and in contact with the geothermal formation an aqueous clay-free foam drilling fluid composition comprising about 99.5 to 90 volume percent air and 0.5 to 10 volume percent of an aqueous dispersion containing (a) about 327 to 347 pounds per barrel of an aqueous medium selected from the group consisting of fresh water, natural brine and synthetic brine, (b) about 0.25 to 10 pounds per barrel of a water-soluble or a water-dispersible foaming agent, (c) about 0.0005 to 1 pound per barrel of a tri-amine or tri-ammonium salt having the formula: ##STR11## where R 1 is a bivalent hydrocarbyl radical containing about 8 to 44 carbon atoms, R 2 is an alkylene radical containing about 1 to 4 carbon atoms, and A is a water-soluble amine having from 1 to 15 carbon atoms or ammonia as an erosion and corrosion inhibitor, the improvement which comprises including in the aqueous dispersion about 0.25 to 3 pounds per barrel of a water-soluble or water-dispersible polyethylene oxide polymer having a molecular weight from 10 5 to 10 8 as a combination fluid loss control additive and foam stabilizer.

Claim 22

The method defined in claim 18 including in the aqueous dispersion about 0.03 to 1 pound per barrel of the condensation product of one mole of a saturated or unsaturated aliphatic monocarboxylic acid having from about 8 to 20 carbon atoms with 5 to 20 moles of ethylene oxide as a bit lubricant.