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US4087405A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyhydrazides as stabilizers for polyolefins

Assignee: Eastman Chemical Co
•
Filing: 1977-08-26
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Granted: 1978-05-02
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Expires: 1997-08-26
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Abstract

Abstract Polyhydrazides of 3,3'-thiodipropionylhydrazide and bis(acid chlorides) are useful as hydrogen peroxide decomposers and copper deactivators for the thermooxidative stabilization of polyolefins.

Inventors

  • 👤 Richard H. S. Wang
  • 👤 Gether Irick, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 10:03
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/42; C08K; C08K5/00; C08K5/36; C08K5/37; C08K5/372; C08K5/3725

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 79 words
Polyhydrazide compounds useful as stabilizers in polyolefin compositions having the formulas ##STR20## wherein R is hydrogen or ##STR21## R' is alkyl having 1 to about 20 carbon atoms, benzyl, phenyl, phenyl substituted with alkyl having 1 to about 12 carbon atoms, hydroxy, or alkoxy having 1 to about 8 carbon atoms; n is an integer of 1 to about 10; and X is alkylene having 1 to about 8 carbon atoms, phenylene or phenylene substituted with methyl or hydroxy.
Claim 2
Dependent Claim 79 words
Polyhydrazide compounds useful as stabilizers in polyolefin compositions having the formulas ##STR20## wherein R is hydrogen or ##STR21## R' is alkyl having 1 to about 20 carbon atoms, benzyl, phenyl, phenyl substituted with alkyl having 1 to about 12 carbon atoms, hydroxy, or alkoxy having 1 to about 8 carbon atoms; n is an integer of 1 to about 10; and X is alkylene having 1 to about 8 carbon atoms, phenylene or phenylene substituted with methyl or hydroxy.
Claim 3
Dependent Claim 56 words
Compound of claim 1 wherein R' is methyl, lauryl, stearyl, phenyl, or phenyl substituted with methyl, t-butyl, hydroxyl, methoxy or octoxy, or ethyl substituted with phenyl, or 3,5-di-tert-butyl-4-hydroxyphenyl; X is alkylene of 2 to about 4 carbon atoms, phenylene, or phenylene substituted with methyl or hydroxy; and n is an integer of 1 to about 5.
Claim 4
Dependent Claim 23 words
Compound of claim 2 wherein R' is methyl, phenyl or lauryl, X is phenylene or tetramethylene, and n is an integer of 1-2.
Claim 5
Dependent Claim 28 words
A composition comprising (A) at least one poly-α-olefin; (B) a stabilizing amount of a phenolic primary antioxidant; and (C) a stabilizing amount of a compound of claim 1.
Claim 6
Dependent Claim 14 words
The composition of claim 4 wherein component C is a compound of claim 2.
Claim 7
Dependent Claim 14 words
The composition of claim 5 wherein component C is a compound of claim 3.

References Cited (Backward Citations)

US2615862A Cited
US3130182A Cited
US3260746A Cited
US3549572A Cited
US3734885A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-05-01 1981-10-31 1982-05-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-05-01 1985-10-31 1986-05-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-05-01 1989-10-31 1990-05-02 $7700.00 Window Closed / Lapsed

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