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US4086183A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat stable colored chemiluminescent compositions

Assignee: Individual
•
Filing: 1976-06-24
•
Granted: 1978-04-25
•
Expires: 1996-06-24
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Abstract

Abstract An improved process of generating visible yellow, orange, red light from the visible violet, blue, green light produced by a selected tetraaminoethylene and oxygen reaction wherein the improvement comprises first uniformly applying a selected fluorescent dye on a selected substrate having a relative permitivity in excess of 3 and less than 96, and then uniformly applying the selected tetraaminoethylene on the selected substrate.

Inventors

  • 👤 Alfred F. Tatyrek

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 16:58
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/06; C09K11/07

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 49 words
An improved process of generating visible light of yellow, orange, or red color from the blue-green visible light produced by the reaction of a tetraaminoethylene with oxygen wherein the improvement comprises first uniformly applying a fluorescent dye on a substrate and then uniformly applying the tetraaminoethylene on the substrate.
Claim 2
Dependent Claim 49 words
An improved process of generating visible light of yellow, orange, or red color from the blue-green visible light produced by the reaction of a tetraaminoethylene with oxygen wherein the improvement comprises first uniformly applying a fluorescent dye on a substrate and then uniformly applying the tetraaminoethylene on the substrate.
Claim 3
Dependent Claim 28 words
The process of claim 1 wherein the tetraaminoethylene is selected from the group consisting of tetrakis(dimethylamino)ethylene; tetrakis N-(pyrrolidinyl)ethylene; 1,3'-diethyl-1',3-dimethyl-Δ2,2'-bi(imidazolidine); 1,1',3,3'-tetra-n-propyl-Δ 2,2'-bi(imidazolidine); 1,1',3,3'-tetramethyl-Δ 2,2'-bi(imidazolidine); 1,1',3,3'-tetramethyl-Δ 2,2,'-bi(imidazolidine); and 1,1',3,3'-tetramethyl-Δ 2,2'-bi(hexahydropyrimidine).
Claim 4
Dependent Claim 10 words
The process of claim 1 wherein the tetraaminoethylene is tetrakis(dimethylamino)ethylene.
Claim 5
Dependent Claim 11 words
The process of claim 1 wherein the tetraaminoethylene is tetrakis N-(pyrrolidinyl)ethylene.
Claim 6
Dependent Claim 10 words
The process of claim 1 wherein the tetraaminoethylene is 1,3'-diethyl-1',3-dimethyl-Δ2,2'-bi(imidazolidine).
Claim 7
Dependent Claim 11 words
The process of claim 1 wherein the tetraaminoethylene is 1,1',3.3'-tetra-n-propyl-Δ 2,2'-bi(imidazolidine).
Claim 8
Dependent Claim 10 words
The process of claim 1 wherein the tetraaminoethylene is 1,1',3,3'-tetramethyl-Δ2,2'-bi(imidazolidine).
Claim 9
Dependent Claim 10 words
The process of claim 1 wherein the tetraaminoethylene is 1,1',3,3'-tetraethyl-Δ2,2'-bi(imidazolidine).
Claim 10
Dependent Claim 10 words
The process of claim 1 wherein the tetraaminoethylene is 1,1',3,3'-tetramethyl-Δ2,2'-bi(hexahydropyrimidine).
Claim 11
Dependent Claim 40 words
The process of claim 1 wherein the fluorescent dye is selected from the Methine and Polymethine group in the Colour Index consisting of 48010, 48013, 48035, 48040, 48070, 48015 and CI Basic Red 14 Chemical Class: Cyanine Bright Red (fluorescent).
Claim 12
Dependent Claim 21 words
The process of claim 1 wherein the fluorescent dye is selected from the group in the Color Index consisting of: ##STR18##
Claim 13
Dependent Claim 12 words
The process of claim 1 wherein the substrate is white glass paper.
Claim 14
Dependent Claim 13 words
The process of claim 1 wherein the substrate is a free-from-halogens polyacrylonitrile cloth.
Claim 15
Dependent Claim 16 words
The process of claim 13 wherein the fluorescent dye is rhodamine red dye, Rhodamine B 45170B.
Claim 16
Dependent Claim 11 words
The process of claim 1 wherein the substrate is nylon flock.
Claim 17
Dependent Claim 14 words
The process of claim 15 wherein the fluorescent dye is rhodamine orange dye (45165).
Claim 18
Dependent Claim 25 words
The process of claim 1 wherein the substrate is a free-from-halogens polyacrylonitrile/acrylic copolymer having a relative permittivity in excess of 3 and less than 6.1.
Claim 19
Dependent Claim 24 words
The process of claim 1 wherein the substrate is a white glass paper spray coated with an aqueous suspension of a commercial fluorescent pigment.
Claim 20
Dependent Claim 13 words
The process of claim 1 wherein the substrate is the polymeric substrate polyacrylonitrile.
Claim 21
Dependent Claim 25 words
The process of claim 1 wherein the substrate is a polymeric material substrate having a relative permittivity in excess of 3 and less than 96.
Claim 22
Dependent Claim 40 words
The process of claim 19 wherein the polymeric substrate is selected from the group consisting of polyacrylonitrile, polyamides, polyester, cellulose acetate, cellulose nitrate, cellulose propionate, polyacrylic ester, urea formaldehyde resin, vinyl polymer, vinyl copolymers, and physical mixtures from said group.
Claim 23
Dependent Claim 41 words
The process of claim 19 wherein the polymeric substrate is modified in chemical attachment of electrically polarizing radicals selected from the group consisting of nitrile, sulfonyl, nitro, nitrate, anhydride, carbonyl, ester, phosphate, amide, branched alkyl, amide, amine, hydrazino, alcohol and ether.
Claim 24
Dependent Claim 40 words
The process of claim 21 wherein the polymeric substrate is modified by chemical attachment of electrically polarizing radicals selected from the group consisting of nitrile, sulfonyl, nitro, nitrate, anhydride, carbonyl, ester, phosphate, amide, branched alkyl, amine, hydrazino, alcohol and ether.

References Cited (Backward Citations)

US3753919A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-04-24 1981-10-24 1982-04-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-04-24 1985-10-24 1986-04-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-04-24 1989-10-24 1990-04-25 $7700.00 Window Closed / Lapsed

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