Patent US4086178A successfully refreshed from Google Patents.
US4086178A
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US
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Glass cleaning formulation
Assignee: Bentley Motors Ltd
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Filing: 1975-05-27
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Granted: 1978-04-25
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Expires: 1995-05-27
Abstract
Abstract A glass cleaning formulation comprises a mixture of the sodium salts of sulphated alkyl phenoxy polyethoxy ethanols which are anionic in classification, citric acid and a fluorinated hydrocarbon surface active agent blended in an alcoholic base.
Inventors
- 👤 David Richard William Walker
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 21:20
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D1/00; C11D1/004; C11D7/00; C11D7/02; C11D7/04; C11D7/08
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
291 words
A stable glass cleaning fluid concentrate which, when diluted, does not attack rubber seals and surrounding paint while, in use, and is devoid of smearing and hazing of automobile windshields under night driving conditions, said concentrate consisting essentially of: (a) an anionic surface active agent selected from the group consisting of: (i) an anionic sulphated alkyl phenoxy polyethoxy ethanol; and (ii) an anionic di-sodium salt of the half ester of sulphosuccinic acid; (b) a fluorinated hydrocarbon surface active agent selected from the group consisting of: (i) an anionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion having a branched chain structure with aliphatic per-fluorocarbon groups at one end of the molecule; (ii) a non-ionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion exhibiting a branched structure and represented by the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.n OR.sub.f wherein R f is C 8 F 15 , C 10 F 19 or C 12 F 23 and n is 10-30; (iii) a non-ionic fluorinated hydrocarbon with a branched fluorinated hydrocarbon portion having the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.m OR wherein R is lower alkyl and m is 2-20; and (iv) an anionic fluorinated hydrocarbon surface active agent wherein the fluoronated hydrocarbon portion exhibits a straight chain structure and has aliphatic per-fluorocarbon groups at one end of the chain; (c) citric acid or sodium citrate (d) components (a), (b) and (c) blended together in an alcohol carrier wherein the proportion, in parts by weight, of (a) to (b) is in the ratio of 3.5:1 to 13.7:1 and the ratio, in parts by weight, of component (c) to the over-all blend is about 1:3.365, the cleaning fluid concentrate having a surface tension range of about 20-25 dynes/cm and a pH of about 3.0-4.0.
Claim 2
Dependent Claim
291 words
A stable glass cleaning fluid concentrate which, when diluted, does not attack rubber seals and surrounding paint while, in use, and is devoid of smearing and hazing of automobile windshields under night driving conditions, said concentrate consisting essentially of: (a) an anionic surface active agent selected from the group consisting of: (i) an anionic sulphated alkyl phenoxy polyethoxy ethanol; and (ii) an anionic di-sodium salt of the half ester of sulphosuccinic acid; (b) a fluorinated hydrocarbon surface active agent selected from the group consisting of: (i) an anionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion having a branched chain structure with aliphatic per-fluorocarbon groups at one end of the molecule; (ii) a non-ionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion exhibiting a branched structure and represented by the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.n OR.sub.f wherein R f is C 8 F 15 , C 10 F 19 or C 12 F 23 and n is 10-30; (iii) a non-ionic fluorinated hydrocarbon with a branched fluorinated hydrocarbon portion having the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.m OR wherein R is lower alkyl and m is 2-20; and (iv) an anionic fluorinated hydrocarbon surface active agent wherein the fluoronated hydrocarbon portion exhibits a straight chain structure and has aliphatic per-fluorocarbon groups at one end of the chain; (c) citric acid or sodium citrate (d) components (a), (b) and (c) blended together in an alcohol carrier wherein the proportion, in parts by weight, of (a) to (b) is in the ratio of 3.5:1 to 13.7:1 and the ratio, in parts by weight, of component (c) to the over-all blend is about 1:3.365, the cleaning fluid concentrate having a surface tension range of about 20-25 dynes/cm and a pH of about 3.0-4.0.
Claim 3
Dependent Claim
22 words
The glass cleaning fluid concentrate of claim 1 wherein the anionic surface active agent is an anionic sulphated alkyl phenoxy polyethoxy ethanol.
Claim 4
Dependent Claim
26 words
The glass cleaning fluid concentrate of claim 1 wherein the anionic surface active agent is an anionic di-sodium salt of the half ester of sulphosuccinic acid.
Claim 5
Dependent Claim
42 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is an anionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion having a branched chain structure with aliphatic per-fluorocarbon groups at one end of the molecule.
Claim 6
Dependent Claim
62 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is a non-ionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion exhibiting a branched structure and represented by the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.n OR.sub.f wherein R f is C 8 F 15 , C 10 F 19 or C 12 F 23 and n is 10-30.
Claim 7
Dependent Claim
44 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is a non-ionic fluorinated hydrocarbon surface active agent with a branched fluorinated hydrocarbon portion having the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.m OR wherein R is lower alkyl and m is 2-20.
Claim 8
Dependent Claim
43 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is an anionic fluorinated hydrocarbon surface active agent wherein the fluorinated hydrocarbon portion exhibits a straight chain structure and has aliphatic per-fluorocarbon groups at one end of the chain.
Claim 9
Dependent Claim
14 words
The glass cleaning fluid concentrate of claim 1 wherein component (c) is citric acid.
Claim 10
Dependent Claim
14 words
The glass cleaning fluid concentrate of claim 1 wherein component (c) is sodium citrate.
Claim 11
Dependent Claim
16 words
The glass cleaning fluid concentrate of claim 1 wherein the alcohol carrier (d) is isoproyl alcohol.
Claim 12
Dependent Claim
26 words
The glass cleaning fluid concentrate of claim 1 wherein the proportion, in parts by weight, of (a) to (b) is in a ratio of about 8.125:1.
Claim 13
Dependent Claim
19 words
The glass cleaning fluid concentrate of claim 1 wherein the alcohol carrier (d) includes isopropyl alcohol and ethyl hexanol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-04-24 | 1981-10-24 | 1982-04-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-04-24 | 1985-10-24 | 1986-04-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-04-24 | 1989-10-24 | 1990-04-25 | $7700.00 | Window Closed / Lapsed |