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US4086178A Expired / Lapsed US ⏱️ 0.0 years remaining

Glass cleaning formulation

Assignee: Bentley Motors Ltd
•
Filing: 1975-05-27
•
Granted: 1978-04-25
•
Expires: 1995-05-27
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Abstract

Abstract A glass cleaning formulation comprises a mixture of the sodium salts of sulphated alkyl phenoxy polyethoxy ethanols which are anionic in classification, citric acid and a fluorinated hydrocarbon surface active agent blended in an alcoholic base.

Inventors

  • 👤 David Richard William Walker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 20:35
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D1/00; C11D1/004; C11D7/00; C11D7/02; C11D7/04; C11D7/08

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 291 words
A stable glass cleaning fluid concentrate which, when diluted, does not attack rubber seals and surrounding paint while, in use, and is devoid of smearing and hazing of automobile windshields under night driving conditions, said concentrate consisting essentially of: (a) an anionic surface active agent selected from the group consisting of: (i) an anionic sulphated alkyl phenoxy polyethoxy ethanol; and (ii) an anionic di-sodium salt of the half ester of sulphosuccinic acid; (b) a fluorinated hydrocarbon surface active agent selected from the group consisting of: (i) an anionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion having a branched chain structure with aliphatic per-fluorocarbon groups at one end of the molecule; (ii) a non-ionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion exhibiting a branched structure and represented by the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.n OR.sub.f wherein R f is C 8 F 15 , C 10 F 19 or C 12 F 23 and n is 10-30; (iii) a non-ionic fluorinated hydrocarbon with a branched fluorinated hydrocarbon portion having the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.m OR wherein R is lower alkyl and m is 2-20; and (iv) an anionic fluorinated hydrocarbon surface active agent wherein the fluoronated hydrocarbon portion exhibits a straight chain structure and has aliphatic per-fluorocarbon groups at one end of the chain; (c) citric acid or sodium citrate (d) components (a), (b) and (c) blended together in an alcohol carrier wherein the proportion, in parts by weight, of (a) to (b) is in the ratio of 3.5:1 to 13.7:1 and the ratio, in parts by weight, of component (c) to the over-all blend is about 1:3.365, the cleaning fluid concentrate having a surface tension range of about 20-25 dynes/cm and a pH of about 3.0-4.0.
Claim 2
Dependent Claim 291 words
A stable glass cleaning fluid concentrate which, when diluted, does not attack rubber seals and surrounding paint while, in use, and is devoid of smearing and hazing of automobile windshields under night driving conditions, said concentrate consisting essentially of: (a) an anionic surface active agent selected from the group consisting of: (i) an anionic sulphated alkyl phenoxy polyethoxy ethanol; and (ii) an anionic di-sodium salt of the half ester of sulphosuccinic acid; (b) a fluorinated hydrocarbon surface active agent selected from the group consisting of: (i) an anionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion having a branched chain structure with aliphatic per-fluorocarbon groups at one end of the molecule; (ii) a non-ionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion exhibiting a branched structure and represented by the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.n OR.sub.f wherein R f is C 8 F 15 , C 10 F 19 or C 12 F 23 and n is 10-30; (iii) a non-ionic fluorinated hydrocarbon with a branched fluorinated hydrocarbon portion having the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.m OR wherein R is lower alkyl and m is 2-20; and (iv) an anionic fluorinated hydrocarbon surface active agent wherein the fluoronated hydrocarbon portion exhibits a straight chain structure and has aliphatic per-fluorocarbon groups at one end of the chain; (c) citric acid or sodium citrate (d) components (a), (b) and (c) blended together in an alcohol carrier wherein the proportion, in parts by weight, of (a) to (b) is in the ratio of 3.5:1 to 13.7:1 and the ratio, in parts by weight, of component (c) to the over-all blend is about 1:3.365, the cleaning fluid concentrate having a surface tension range of about 20-25 dynes/cm and a pH of about 3.0-4.0.
Claim 3
Dependent Claim 22 words
The glass cleaning fluid concentrate of claim 1 wherein the anionic surface active agent is an anionic sulphated alkyl phenoxy polyethoxy ethanol.
Claim 4
Dependent Claim 26 words
The glass cleaning fluid concentrate of claim 1 wherein the anionic surface active agent is an anionic di-sodium salt of the half ester of sulphosuccinic acid.
Claim 5
Dependent Claim 42 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is an anionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion having a branched chain structure with aliphatic per-fluorocarbon groups at one end of the molecule.
Claim 6
Dependent Claim 62 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is a non-ionic fluorinated hydrocarbon surface active agent with the fluorinated hydrocarbon portion exhibiting a branched structure and represented by the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.n OR.sub.f wherein R f is C 8 F 15 , C 10 F 19 or C 12 F 23 and n is 10-30.
Claim 7
Dependent Claim 44 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is a non-ionic fluorinated hydrocarbon surface active agent with a branched fluorinated hydrocarbon portion having the formula: R.sub.f (OCH.sub.2 CH.sub.2).sub.m OR wherein R is lower alkyl and m is 2-20.
Claim 8
Dependent Claim 43 words
The glass cleaning concentrate of claim 1 wherein the fluorinated hydrocarbon surface active agent is an anionic fluorinated hydrocarbon surface active agent wherein the fluorinated hydrocarbon portion exhibits a straight chain structure and has aliphatic per-fluorocarbon groups at one end of the chain.
Claim 9
Dependent Claim 14 words
The glass cleaning fluid concentrate of claim 1 wherein component (c) is citric acid.
Claim 10
Dependent Claim 14 words
The glass cleaning fluid concentrate of claim 1 wherein component (c) is sodium citrate.
Claim 11
Dependent Claim 16 words
The glass cleaning fluid concentrate of claim 1 wherein the alcohol carrier (d) is isoproyl alcohol.
Claim 12
Dependent Claim 26 words
The glass cleaning fluid concentrate of claim 1 wherein the proportion, in parts by weight, of (a) to (b) is in a ratio of about 8.125:1.
Claim 13
Dependent Claim 19 words
The glass cleaning fluid concentrate of claim 1 wherein the alcohol carrier (d) includes isopropyl alcohol and ethyl hexanol.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-04-24 1981-10-24 1982-04-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-04-24 1985-10-24 1986-04-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-04-24 1989-10-24 1990-04-25 $7700.00 Window Closed / Lapsed

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