Method of forming and growing a single crystal of a semiconductor compound

Claim 1

A method of forming a single crystal Group II-VI or Group III-V compound, which comprises: (a) positioning a quantity of a first reactant selected from the group consisting of a Group II element or a Group III element within a vertically disposed crucible house in the upper part of a vertically disposed reaction container, said crucible communicating with the interior of said reaction container through a plurality of apertures located in the lower portion of said crucible; (b) positioning in the lower part of said reaction container a source quantity of a second reactant selected from the group consisting of a Group VI element or a Group V element; (c) positioning a single crystal seed within the bottom portion of said crucible in contact with said first reactant, the interface between said first reactant and said seed being proximate the level of said plurality of apertures; (d) heating to a first temperature the lower part of said reaction container to produce a gaseous ambient comprising said second reactant, said gaseous second reactant passing through said plurality of apertures to contact said first reactant and to form a horizontal protective barrier, between said seed crystal and said first reactant; (e) heating at least the upper part of said reaction container to a second temperature to form the compound within said crucible by reaction of said first reactant and said ambient comprising said gaseous second reactant in contact therewith and to form a melt comprising said formed compound in contact with said horizontal protective barrier; (f) heating at least the lower portion of said crucible to said second temperature to assure a continuum of said melt comprising said formed compound in contact with said seed crystal; and (g) lowering at least said second temperature to a third temperature below said second temperature to expose said contacted melt and seed thereto to crystallize and grow from said contacted melt a single crystal on said seed crystal.

Claim 2

A method of forming a single crystal Group II-VI or Group III-V compound, which comprises: (a) positioning a quantity of a first reactant selected from the group consisting of a Group II element or a Group III element within a vertically disposed crucible house in the upper part of a vertically disposed reaction container, said crucible communicating with the interior of said reaction container through a plurality of apertures located in the lower portion of said crucible; (b) positioning in the lower part of said reaction container a source quantity of a second reactant selected from the group consisting of a Group VI element or a Group V element; (c) positioning a single crystal seed within the bottom portion of said crucible in contact with said first reactant, the interface between said first reactant and said seed being proximate the level of said plurality of apertures; (d) heating to a first temperature the lower part of said reaction container to produce a gaseous ambient comprising said second reactant, said gaseous second reactant passing through said plurality of apertures to contact said first reactant and to form a horizontal protective barrier, between said seed crystal and said first reactant; (e) heating at least the upper part of said reaction container to a second temperature to form the compound within said crucible by reaction of said first reactant and said ambient comprising said gaseous second reactant in contact therewith and to form a melt comprising said formed compound in contact with said horizontal protective barrier; (f) heating at least the lower portion of said crucible to said second temperature to assure a continuum of said melt comprising said formed compound in contact with said seed crystal; and (g) lowering at least said second temperature to a third temperature below said second temperature to expose said contacted melt and seed thereto to crystallize and grow from said contacted melt a single crystal on said seed crystal.