US4082731A
Expired / Lapsed
US
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Method for producing a high modulus polyester yarn
Assignee: Akzo Nobel UK PLC
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Filing: 1975-12-29
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Granted: 1978-04-04
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Expires: 1995-12-29
Abstract
Abstract Method taught for producing a high modulus yarn of filaments of a polyester resin consisting of at least 15 up to 50 mole percent of bibenzoate units and from 85 to 50 mole percent of terephthalate units, said yarn having been uniformly oriented and then heat-set while free-to-relax.
Inventors
- 👤 William N. Knopka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 09:52
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/181; C08G63/185; D; D01; D01F; D01F6/00; D01F6/78; D01F6/84
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
182 words
Method for producing a high modulus yarn from a copolyester resin which yarn is heat-settable without tension comprising: a. forming filaments from a copolyester resin consisting of at least 15 to 50 mole percent of an interpolymerized randomly repeating unit having the formula: ##STR5## and from 85 to 50 percent of an interpolymerized randomly repeating unit having the formula: ##STR6## wherein n for both units is an integer of from 2 to 10, the fiber resin having an intrinsic viscosity of at least about 0.55 as determined in a 60 weight percent phenol and 40 weight percent tetrachloroethane solution at 30° C; b. combining the resulting filaments into a yarn; c. uniformly orienting the resulting yarn by drawing the yarn at a temperature of about 20° C higher than its glass transition temperature and at 75% of its break-draw ratio, and d. heat-setting the oriented yarn by passing it through a heat zone maintained about 125° to 185° C for a time ranging from 1 to 10 minutes, while in a free-to-relax condition, said heat-setting being conducted without tensioning of said yarn.
Claim 2
Dependent Claim
182 words
Method for producing a high modulus yarn from a copolyester resin which yarn is heat-settable without tension comprising: a. forming filaments from a copolyester resin consisting of at least 15 to 50 mole percent of an interpolymerized randomly repeating unit having the formula: ##STR5## and from 85 to 50 percent of an interpolymerized randomly repeating unit having the formula: ##STR6## wherein n for both units is an integer of from 2 to 10, the fiber resin having an intrinsic viscosity of at least about 0.55 as determined in a 60 weight percent phenol and 40 weight percent tetrachloroethane solution at 30° C; b. combining the resulting filaments into a yarn; c. uniformly orienting the resulting yarn by drawing the yarn at a temperature of about 20° C higher than its glass transition temperature and at 75% of its break-draw ratio, and d. heat-setting the oriented yarn by passing it through a heat zone maintained about 125° to 185° C for a time ranging from 1 to 10 minutes, while in a free-to-relax condition, said heat-setting being conducted without tensioning of said yarn.
Claim 3
Dependent Claim
31 words
The method of claim 1 wherein the copolyester resin consists of 25 to 40 mole percent of said first-mentioned unit and from 75 to 60 mole percent of said second-mentioned unit.
Claim 4
Dependent Claim
23 words
The method of claim 1 wherein the copolyester resin consists of repeating units wherein n is an integer of from 2 to 4.
Claim 5
Dependent Claim
9 words
The method of claim 3 wherein n is 2.
Claim 6
Dependent Claim
42 words
The method of claim 4 wherein the copolyester resin consists of 25 to 40 mole percent of said first-mentioned unit and from 75 to 60 mole percent of said second-mentioned unit, and said resin has an intrinsic viscosity of at least 0.6.
Claim 7
Dependent Claim
22 words
The method of claim 1 wherein the copolyester resin contains up to 5 mole percent of a third randomly repeating ester unit.
Claim 8
Dependent Claim
17 words
The method of claim 1 in which the resulting yarn is in the form of staple fibers.
Claim 9
Dependent Claim
13 words
A high modulus copolyester yarn produced according to the method of claim 1.
Claim 10
Dependent Claim
43 words
The copolyester yarn of claim 8 wherein the copolyester resin consists of 25 to 40 mole percent of said first-mentioned unit, and from 75 to 60 mole percent of said second-mentioned unit, and said resin has an intrinsic viscosity of at least 0.6.
Claim 11
Dependent Claim
23 words
The copolyester yarn of claim 8 wherein the copolyester resin consists of repeating units wherein n is an integer of 2 to 4.
Claim 12
Dependent Claim
24 words
The high modulus copolyester yarn of claim 8 wherein the resin contains up to 5 mole percent of a third randomly repeating ester unit.
Claim 13
Dependent Claim
20 words
The high modulus copolyester yarn of claim 8 in which the resulting yarn is in the form of staple fibers.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-04-03 | 1981-10-03 | 1982-04-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-04-03 | 1985-10-03 | 1986-04-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-04-03 | 1989-10-03 | 1990-04-04 | $7700.00 | Window Closed / Lapsed |