US4081522A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Regeneration of sulfated metal oxides and carbonates
Assignee: United States Department of Energy
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Filing: 1976-10-07
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Granted: 1978-03-28
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Expires: 1996-10-07
Abstract
Abstract Alkali metal or alkaline earth metal carbonates such as calcium carbonate and magnesium carbonate found in dolomite or limestone are employed for removal of sulfur dioxide from combustion exhaust gases. The sulfated carbonates are regenerated to oxides through use of a solid-solid reaction, particularly calcium sulfide with calcium sulfate to form calcium oxide and sulfur dioxide gas. The regeneration is performed by contacting the sulfated material with a reductant gas such as hydrogen within an inert diluent to produce calcium sulfide in mixture with the sulfate under process conditions selected to permit the sulfide-sulfate, solid-state reaction to occur.
Inventors
- 👤 Bill R. Hubble
- 👤 Stanley Siegel
- 👤 Paul T. Cunningham
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 13:30
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
134 words
A process for the regeneration of sulfated calcium oxide comprising contacting at a temperature of about 700°-800° C., solid particles containing calcium sulfate and calcium oxide with a reductant gas at a concentration of 2% to 8% by volume within an inert diluent gas to react with only a portion of said solid calcium sulfate and thereby produce solid calcium sulfide in intimate mixture with remaining calcium sulfate; and subsequently contacting said particles at a temperature of 900°-1000° C. with a reductant gas of not more than 0.1 volume % within said inert diluent gas to further reduce calcium sulfate to calcium sulfide in a neutral to slightly reducing atmosphere while simultaneously reacting said solid metal sulfate with said solid metal sulfide within said particles to produce SO 2 gas and regenerated calcium oxide.
Claim 2
Dependent Claim
134 words
A process for the regeneration of sulfated calcium oxide comprising contacting at a temperature of about 700°-800° C., solid particles containing calcium sulfate and calcium oxide with a reductant gas at a concentration of 2% to 8% by volume within an inert diluent gas to react with only a portion of said solid calcium sulfate and thereby produce solid calcium sulfide in intimate mixture with remaining calcium sulfate; and subsequently contacting said particles at a temperature of 900°-1000° C. with a reductant gas of not more than 0.1 volume % within said inert diluent gas to further reduce calcium sulfate to calcium sulfide in a neutral to slightly reducing atmosphere while simultaneously reacting said solid metal sulfate with said solid metal sulfide within said particles to produce SO 2 gas and regenerated calcium oxide.
Claim 3
Dependent Claim
36 words
The process of claim 1 wherein said reductant gas is in contact with said particles until a sulfate to sulfide ratio of about 1.0 to 2.0 is established and heating said particles to said second temperature.
Claim 4
Dependent Claim
83 words
The process of claim 1 wherein solid particles containing calcium sulfate and calcium oxide are contacted with a gas of about 6% by volume hydrogen gas at about 750° C. to provide a calcium sulfate to calcium sulfide ratio of about 1.5; and heating said particles at a temperature of about 950° C. out of contact with said hydrogen gas to react the calcium sulfide with the calcium sulfate in the solid particles and produce evolved sulfur dioxide gas and regenerated calcium oxide.
Claim 5
Dependent Claim
113 words
A process for the regeneration of sulfated calcium oxide comprising contacting solid particles containing calcium sulfate and calcium oxide at a temperature of about 750°-800° C. with a gas mixture consisting of not less than 6 volume % reductant gas and a major proportion of an inert diluent gas to provide a calcium sulfate to calcium sulfide ratio of about 1 to 2; subsequently contacting the solid particles at 900°-1000° C. with a reductant gas of not more than 0.1 volume % in an inert diluent gas for maintaining a neutral to slightly reducing atmosphere while simultaneously reacting the calcium sulfide with calcium sulfate to form solid calcium oxide and sulfur dioxide gas.
Claim 6
Dependent Claim
113 words
A process for the regeneration of sulfated calcium oxide comprising contacting solid particles containing calcium sulfate and calcium oxide at a temperature of about 750°-800° C. with a gas mixture consisting of not less than 6 volume % reductant gas and a major proportion of an inert diluent gas to provide a calcium sulfate to calcium sulfide ratio of about 1 to 2; subsequently contacting the solid particles at 900°-1000° C. with a reductant gas of not more than 0.1 volume % in an inert diluent gas for maintaining a neutral to slightly reducing atmosphere while simultaneously reacting the calcium sulfide with calcium sulfate to form solid calcium oxide and sulfur dioxide gas.
Claim 7
Dependent Claim
59 words
The process of claim 4 wherein a calcium sulfate to calcium sulfide ratio of about 1.5 is provided by heating the particles containing calcium sulfate and calcium oxide in contact with a gas mixture consisting of not less than 6% by volume reductant gas and a major proportion of an inert diluent gas at about 750° - 800° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-27 | 1981-09-26 | 1982-03-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-27 | 1985-09-26 | 1986-03-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-27 | 1989-09-26 | 1990-03-28 | $7700.00 | Window Closed / Lapsed |