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US4080372A
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US
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Continuous process for bleaching acid alpha-sulfo-fatty acid esters
Assignee: Henkel AG and Co KGaA
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Filing: 1976-12-06
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Granted: 1978-03-21
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Expires: 1996-12-06
Abstract
Abstract A continuous process for the bleaching of acid α-sulfo-fatty acid esters of predominantly C 16-24 fatty acids comprising continuously adding the hydrogen peroxide bleach in aqueous solution as well as from 2% to 50% by weight, based on the sulfonated esters, of a C 6-18 alkylbenzene sulfonic acid, to said raw, acid α-sulfo-fatty acid esters at a temperature of 40° to 65° C, continuously passing said mixture through a confined zone of dimensions sufficient to give a proper bleach retention time and continuously recovering bleached α-sulfo-fatty acid esters.
Inventors
- 👤 Werner Stein
- 👤 Horst Baumann
- 👤 Hans Josef Rommerskirchen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 05:27
CPC Classifications
C; C07; C07C; C07C303/00; C07C303/42
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
193 words
A continuous process for bleaching of acid α-sulfo-fatty acid esters comprising the steps of continuously mixing a mixture of (1) a raw acid α-sulfo-fatty acid ester wherein the fatty acid moiety of said ester contains at least 70% by weight of fatty acids having from 16 to 24 carbon atoms and the alcohol moiety of said ester is a member selected from the group consisting of alkanols having 1 to 3 carbon atoms, alkanediols having 2 to 3 carbon atoms and glycerine, and substantially all of the hydroxyl groups are esterified, said ester being maintained at a temperature of from above the flowability temperature to below 70° C, (2) from 1% to 5% by weight of said ester, of hydrogen peroxide on a 100% basis and added in the form of a 20% to 75% aqueous solution, and (3) from 2% to 50% by weight of said ester of an alkylbenzene sulfonic acid having from 6 to 18 carbon atoms in the alkyl, continuously passing said mixture through a bleaching zone of dimensions and at such a rate to give the preselected bleach retention time, and continuously recovering bleached acid α-sulfo-fatty acid esters.
Claim 2
Dependent Claim
193 words
A continuous process for bleaching of acid α-sulfo-fatty acid esters comprising the steps of continuously mixing a mixture of (1) a raw acid α-sulfo-fatty acid ester wherein the fatty acid moiety of said ester contains at least 70% by weight of fatty acids having from 16 to 24 carbon atoms and the alcohol moiety of said ester is a member selected from the group consisting of alkanols having 1 to 3 carbon atoms, alkanediols having 2 to 3 carbon atoms and glycerine, and substantially all of the hydroxyl groups are esterified, said ester being maintained at a temperature of from above the flowability temperature to below 70° C, (2) from 1% to 5% by weight of said ester, of hydrogen peroxide on a 100% basis and added in the form of a 20% to 75% aqueous solution, and (3) from 2% to 50% by weight of said ester of an alkylbenzene sulfonic acid having from 6 to 18 carbon atoms in the alkyl, continuously passing said mixture through a bleaching zone of dimensions and at such a rate to give the preselected bleach retention time, and continuously recovering bleached acid α-sulfo-fatty acid esters.
Claim 3
Dependent Claim
19 words
The process of claim 1 wherein said ester is maintained at a temperature of from 40° to 65° C.
Claim 4
Dependent Claim
21 words
The process of claim 1 wherein said alkylbenzene sulfonic acid has from 10 to 13 carbon atoms in the linear alkyl.
Claim 5
Dependent Claim
29 words
The process of claim 1 wherein said alkylbenzene sulfonic acid is added in amounts of from 3% to 25% by weight based on the raw acid α-sulfo-fatty acid ester.
Claim 6
Dependent Claim
28 words
The process of claim wherein said alkylbenzene sulfonic acid is added in amounts of from 3% to 15% by weight based on the raw acid α-sulfo-fatty acid ester.
Claim 7
Dependent Claim
21 words
The process of claim 1 wherein said raw acid α-sulfo-fatty acid ester has a degree of sulfonation of at least 90%.
Claim 8
Dependent Claim
21 words
The process of claim 1 wherein said raw acid α-sulfo-fatty acid ester has a degree of sulfonation of at least 96%.
Claim 9
Dependent Claim
42 words
The process of claim 1 wherein the amount of water added with said hydrogen peroxide is such that the surplus sulfur trioxide present in said raw acid ester will form with the water an at least 60% by weight sulfuric acid solution.
Claim 10
Dependent Claim
23 words
The process of claim 1 wherein said bleaching zone is cooled in order to maintain the beaching temperature at less than 90° C.
Claim 11
Dependent Claim
23 words
The process of claim 1 wherein said bleaching zone is cooled in order to maintain the bleaching temperature from 55° to 75° C.
Claim 12
Dependent Claim
17 words
The process of claim 1 wherein said bleach retention time is from 5 minutes to 1 hour.
Claim 13
Dependent Claim
17 words
The process of claim 1 wherein said bleach retention time is from 10 minutes to 20 minutes.
Claim 14
Dependent Claim
37 words
The process of claim 1 wherein part of said recovered bleached acid α-sulfo-fatty acid esters are recycled to said mixing step where the ratio of bleached returned ester to unbleached raw ester is from 10:1 to 1:1.
Claim 15
Dependent Claim
17 words
The bleached acid α-sulfo-fatty acid esters containing alkylbenzene sulfonic acid produced by the process of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-20 | 1981-09-19 | 1982-03-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-20 | 1985-09-19 | 1986-03-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-20 | 1989-09-19 | 1990-03-21 | $7700.00 | Window Closed / Lapsed |