Abstract Attrition resistant and stable catalyst composition comprising crystalline aluminosilicate zeolites e.g. rare earth exchanged zeolites dispersed in an inorganic matrix containing synthetic amorphous silica-alumina and clay are prepared by a process which reduces the level of polluting ammonium salts by eliminating the use of ammonium hydroxide in the steps prior to primary filtration. During the synthesis of the amorphous inorganic matrix wherein alkali metal silicate and aluminum salt solutions are gelled and subsequently combined with zeolitic materials, the ammonia reagent is replaced by non-polluting additives such as magnesium or calcium hydroxides (or oxides) prior to a primary filtration stage without decreasing the catalytic activity of the resulting zeolite promoted hydrocarbon conversion catalysts.
In a process for preparing a hydrocarbon conversion catalyst which includes the steps of: (a) combining a alkali metal silicate solution with an aluminum salt solution to provide an aqueous slurry of silica-alumina hydrogel having a pH of about 4, (b) adjusting the pH of said slurry to a level of about 5 to 7, and (c) adding a crystalline alumino silicate zeolite to the slurry prior to processing the mixture to form a particulate catalyst, the improvement comprising: adjusting said pH at Step (b) to a level of about 5 to 7 by addition of an alkaline earth metal component selected from the group consisting of hydroxides and oxides of magnesium, calcium and mixtures thereof to produce a catalyst which contains alkaline earth metal oxides in amounts up to 3% by weight of said catalyst.
Claim 2
Dependent Claim
136 words
In a process for preparing a hydrocarbon conversion catalyst which includes the steps of: (a) combining a alkali metal silicate solution with an aluminum salt solution to provide an aqueous slurry of silica-alumina hydrogel having a pH of about 4, (b) adjusting the pH of said slurry to a level of about 5 to 7, and (c) adding a crystalline alumino silicate zeolite to the slurry prior to processing the mixture to form a particulate catalyst, the improvement comprising: adjusting said pH at Step (b) to a level of about 5 to 7 by addition of an alkaline earth metal component selected from the group consisting of hydroxides and oxides of magnesium, calcium and mixtures thereof to produce a catalyst which contains alkaline earth metal oxides in amounts up to 3% by weight of said catalyst.
Claim 3
Dependent Claim
12 words
The process of claim 1 wherein said zeolite is Type Y zeolite.
Claim 4
Dependent Claim
15 words
The process of claim 1 wherein said catalyst composition is exchanged with rare earth ions.
Claim 5
Dependent Claim
11 words
The process of claim 1 wherein said salt is aluminum sulfate.
Claim 6
Dependent Claim
16 words
The process of claim 1 wherein said catalyst contains up to 30 percent by weight clay.
Claim 7
Dependent Claim
19 words
The process of claim 1 wherein alkali metal aluminate is added to said slurry prior to adjusting said pH.