Abstract In the electrolysis of an alkaline earth metal-containing alkali metal brine wherein the alkaline earth metals contained in the brine are removed, the brine is subjected to electrolysis, and the residual brine is concentrated and recycled for further electrolysis along with make-up fresh brine, the improvement which comprises contacting the alkaline earth metal-containing brine with a weakly acidic cation exchanger in the Na+ form, the exchanger comprising units of at least one of acrylic acid and methacrylic acid, whereby the alkaline earth metals are adsorbed on the cation exchanger, and periodically regenerating the cation exchanger. The cation exchanger is regenerated by contact with a hydrochloric acid solution of about 5 to 10% concentration, the regenerating solution effluent from the column being combined with the redissoluted sodium sulphate which is precipitated during concentration of the cell liquor thereby to precipitate any sulphate contained in the brine as the alkaline earth metal sulphate. Advantageously the precipitation is effected at a pH above about 8 whereby any magnesium present in the brine or regenerating effluent is also precipitated as magnesium hydroxide.
In the electrolysis of an alkaline earth metal-containing alkali metal brine wherein the alkaline earth metals contained in the brine are removed, the brine is subjected to electrolysis, and the residual brine is concentrated and recycled for further electrolysis along with make-up fresh brine, the improvement which comprises contacting the alkaline earth metal-containing brine with a weakly acidic cation exchanger in the Na= form, the exchanger comprising units of at least one of acrylic and methacrylic acid, whereby the alkaline earth metals are absorbed on the cation exchanger, periodically regenerating the cation exchanger, and separating such precipitated alkaline earth metal sulphate by contact with a hydrochloric acid solution of about 5 to 10% concentration, the regenerating solution effluent from the column being combined with the brine during concentration, thereby to precipitate any sulphate contained in the brine as the alkaline earth metal sulphate.
Claim 2
Dependent Claim
143 words
In the electrolysis of an alkaline earth metal-containing alkali metal brine wherein the alkaline earth metals contained in the brine are removed, the brine is subjected to electrolysis, and the residual brine is concentrated and recycled for further electrolysis along with make-up fresh brine, the improvement which comprises contacting the alkaline earth metal-containing brine with a weakly acidic cation exchanger in the Na= form, the exchanger comprising units of at least one of acrylic and methacrylic acid, whereby the alkaline earth metals are absorbed on the cation exchanger, periodically regenerating the cation exchanger, and separating such precipitated alkaline earth metal sulphate by contact with a hydrochloric acid solution of about 5 to 10% concentration, the regenerating solution effluent from the column being combined with the brine during concentration, thereby to precipitate any sulphate contained in the brine as the alkaline earth metal sulphate.
Claim 3
Dependent Claim
33 words
The process as claimed in claim 1, wherein the weakly acidic cation exchanger is initially in the H+- form and is converted to the Na+- form by passage of sodium chloride solution therethrough.
Claim 4
Dependent Claim
38 words
A process as claimed in claim 1, wherein the alkaline earth metal sulphate precipitation is effected at a pH above about 8 whereby any magnesium present in the brine or regenerating effluent is also precipitated as magnesium hydroxide.