Patent US4078390A successfully refreshed from Google Patents.
US4078390A
Expired / Lapsed
US
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Removal and recovery of sulfur dioxide from stack gases
Assignee: Individual
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Filing: 1976-10-29
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Granted: 1978-03-14
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Expires: 1996-10-29
Abstract
Abstract An improved method and apparatus for the removal and recovery of sulfur dioxide and water vapor from gaseous effluent is disclosed. Sulfur dioxide and water vapor entrained in stack gases, emanated upon combustion of sulfur-bearing materials, are selectively liquefied under the combined influence of a reduction in temperature and an increase in pressure of the gaseous effluent. System efficiency is enhanced through proper routing of effluent gases and condensate and the incorporation of a condensate spray curtain.
Inventors
- 👤 Lee J. Duvall
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 07:22
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/48; C01B17/50; C01B17/60; Y; Y10; Y10S; Y10S62/00; Y10S62/922
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
266 words
The method for modification of a gaseous effluent, emitted upon combustion of sulfur-containing materials in a furnace having a predetermined optimum flow rate of air thereto for most efficient operation thereof, by removal and recovery of sulfur dioxide and water vapor from said effluent prior to discharge thereof to the atmosphere, said method comprising the steps of: a. cooling said gaseous effluent; b. compressing said gaseous effluent; c. sensing the pressure of the cooled and compressed effluent; d. sensing the temperature of the cooled and compressed effluent; e. liquifying sulfur dioxide and water vapor entrained in said effluent by maintaining the temperature/pressure relationship of said cooled and compressed effluent below the thermodynamic equilibrium point for liquefaction of sulfur dioxide and water vapor from said effluent, to yield a modified residuum effluent essentially free from sulfur dioxide and water; f. controlledly discharging sad modified residuum effluent to the atmosphere through discharge flow means in response to the sensed pressure and temperature of said cooled and compressed effluent whereby said temperature/pressure relationship is maintained by adjusting the volume flow rate of modified residuum effluent discharged; g. admitting a volume of air through damper flow means to said effluent upstream of said discharge flow means to directly compensate for increases and decreases in the volume flow rate of modified residuum effluent discharged, whereby surging through the furnace is precluded, thus maintaining constant said optimum flow rate of air thereto while allowing the adjustment of the volume flow rate of modified residuum effluent discharged; and, h. contacting said effluent with sulfur dioxide and water condensate prior to said liquifying step.
Claim 2
Independent Claim
266 words
The method for modification of a gaseous effluent, emitted upon combustion of sulfur-containing materials in a furnace having a predetermined optimum flow rate of air thereto for most efficient operation thereof, by removal and recovery of sulfur dioxide and water vapor from said effluent prior to discharge thereof to the atmosphere, said method comprising the steps of: a. cooling said gaseous effluent; b. compressing said gaseous effluent; c. sensing the pressure of the cooled and compressed effluent; d. sensing the temperature of the cooled and compressed effluent; e. liquifying sulfur dioxide and water vapor entrained in said effluent by maintaining the temperature/pressure relationship of said cooled and compressed effluent below the thermodynamic equilibrium point for liquefaction of sulfur dioxide and water vapor from said effluent, to yield a modified residuum effluent essentially free from sulfur dioxide and water; f. controlledly discharging sad modified residuum effluent to the atmosphere through discharge flow means in response to the sensed pressure and temperature of said cooled and compressed effluent whereby said temperature/pressure relationship is maintained by adjusting the volume flow rate of modified residuum effluent discharged; g. admitting a volume of air through damper flow means to said effluent upstream of said discharge flow means to directly compensate for increases and decreases in the volume flow rate of modified residuum effluent discharged, whereby surging through the furnace is precluded, thus maintaining constant said optimum flow rate of air thereto while allowing the adjustment of the volume flow rate of modified residuum effluent discharged; and, h. contacting said effluent with sulfur dioxide and water condensate prior to said liquifying step.
Claim 3
Dependent Claim
28 words
The method of claim 1 wherein said discharging step includes routing said residuum in heat-exchange relationship with said gaseous effluent prior to discharging said residuum to the atmosphere.
Claim 4
Dependent Claim
24 words
The method of claim 1 further including the step of collecting said liquefied sulfur dioxide and recycling a portion thereof to said contacting step.
Claim 5
Dependent Claim
38 words
The method of claim 1 wherein said effluent is cooled to a temperature within the range of about 1° C. to about 5° C. and is compressed to a pressure of up to at least about 100 p.s.i.g.
Claim 6
Dependent Claim
58 words
The method of claim 1 further comprising the step of regulating the environment under which said method is practiced by selectively routing said residuum and/or said gaseous effluent in heat-exchange relationship of the environs wherein said method is practiced whereby the temperature of said environs is maintained within the range of from about 10° C to 16° C.
Claim 7
Independent Claim
293 words
An apparatus for modification of a gaseous effluent, emitted upon combustion of sulfur-containing materials in a furnace having a predetermined optimum flow rate of air thereto for most efficient operation thereof, by removal and recovery of sulfur dioxide and water vapor from said effluent prior to discharge thereof to the atmosphere, said apparatus comprising: a. means for cooling said gaseous effluent; b. means for compressing said gaseous effluent in operative communication with said cooling means; c. means for sensing the pressure of said cooled and compressed effluent; d. means for sensing the temperature of said cooled and compressed effluent; e. means for liquifying sulfur dioxide and water vapor entrained in said effluent by maintaining the temperature/pressure relationship of said cooled and compressed effluent below the thermodynamic equilibrium point for liquefaction of sulfur dioxide and water vapor from said effluent, to yield a modified residuum effluent essentially free from sulfur dioxide and water; f. means for controlledly discharging to the atmosphere said modified residuum effluent, in operative communication with said liquifying means, said discharging means being adjustable in response to the sensed pressure and temperature of said cooled and compressed effluent whereby said temperature/pressure relationship is maintained by increasing or decreasing the volume flow rate of modified residuum effluent discharged; g. means for admitting a volume of air to said effluent, upstream of said discharging means, to directly compensate for increases and decreases in the volume flow rate of modified residuum effluent discharged, whereby surging through the furnace is precluded, thus maintaining constant said optimum flow rate of air thereto while allowing the adjustment of the volume flow rate of modified residuum effluent discharged; and, h. means for contacting said gaseous effluent with liquid sulfur dioxide and water condensate upstream of said discharging means.
Claim 8
Independent Claim
293 words
An apparatus for modification of a gaseous effluent, emitted upon combustion of sulfur-containing materials in a furnace having a predetermined optimum flow rate of air thereto for most efficient operation thereof, by removal and recovery of sulfur dioxide and water vapor from said effluent prior to discharge thereof to the atmosphere, said apparatus comprising: a. means for cooling said gaseous effluent; b. means for compressing said gaseous effluent in operative communication with said cooling means; c. means for sensing the pressure of said cooled and compressed effluent; d. means for sensing the temperature of said cooled and compressed effluent; e. means for liquifying sulfur dioxide and water vapor entrained in said effluent by maintaining the temperature/pressure relationship of said cooled and compressed effluent below the thermodynamic equilibrium point for liquefaction of sulfur dioxide and water vapor from said effluent, to yield a modified residuum effluent essentially free from sulfur dioxide and water; f. means for controlledly discharging to the atmosphere said modified residuum effluent, in operative communication with said liquifying means, said discharging means being adjustable in response to the sensed pressure and temperature of said cooled and compressed effluent whereby said temperature/pressure relationship is maintained by increasing or decreasing the volume flow rate of modified residuum effluent discharged; g. means for admitting a volume of air to said effluent, upstream of said discharging means, to directly compensate for increases and decreases in the volume flow rate of modified residuum effluent discharged, whereby surging through the furnace is precluded, thus maintaining constant said optimum flow rate of air thereto while allowing the adjustment of the volume flow rate of modified residuum effluent discharged; and, h. means for contacting said gaseous effluent with liquid sulfur dioxide and water condensate upstream of said discharging means.
Claim 9
Dependent Claim
22 words
The apparatus of claim 6 further including means for collecting liquid sulfur dioxide and recycling a portion thereof to said contacting means.
Claim 10
Dependent Claim
20 words
The apparatus of claim 6 further including means for selectively routing said residuum in heat-exchange relationship with said gaseous effluent.
Claim 11
Dependent Claim
44 words
The apparatus of claim 6 further comprising means for selectively routing said residuum and/or said gaseous effluent in heat-exchange relationship with the environs of said apparatus whereby the environment thereof is regulated within a temperature range of from about 10° C to 16° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-13 | 1981-09-12 | 1982-03-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-13 | 1985-09-12 | 1986-03-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-13 | 1989-09-12 | 1990-03-14 | $7700.00 | Window Closed / Lapsed |