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Aqueous soluble mixed complex organic salts of aluminum sulfate

Assignee: Alcolac Inc
•
Filing: 1975-09-08
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Granted: 1978-03-07
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Expires: 1995-09-08
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Abstract

Abstract Mixed complex organic salts of aluminum sulfate are prepared. The mixed complex salts are soluble in aqueous solutions and have surface active properties. The organic portion of the mixed salts is derived from a member selected from the group of a neutralized salt of an aliphatic alcohol sulfate; an alkylaryl sulfate; an alkyl, aryl, or alkylaryl sulfonate; a dialkyl or alkyloxyalkylene sulfosuccinate; an N-acyl-N-alkyl taurate; a sulfoalkyl ester of a fatty acid; and a sulfated ethylene oxide-propylene oxide block copolymer. Ethylene oxide, propylene oxide, or butylene oxide, or polymers thereof, can be introduced into the organic portion of the mixed salt to obtain a mixed complex aluminum salt which is completely soluble upon any degree of dilution. Non-ethoxylated salts, non-propoxylated and non-butoxylated salts become insoluble upon dilution at specific dilution points depending on the cation of the neutralized salt used to form the mixed complex salt.

Inventors

  • 👤 George W. Panzer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 18:01
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/19; A61K8/26; A61K8/27; A61K8/30; A61K8/58; A61Q; A61Q15/00; A61Q19/00; A61Q19/10; A61Q5/00; A61Q5/02; A61Q5/12; C; C07; C07F; C07F5/00; C07F5/06; C07F5/069; D; D06; D06P; D06P1/00; D06P1/44; D06P1/673; D06P1/67333; D06P1/67341; A61K2800/00; A61K2800/40; A61K2800/58; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/03; Y10S516/05

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 327 words
An aqueous solution of from about 10 weight % to about 60 weight % of a soluble mixed complex salt of aluminum sulfate and a neutralized organic salt selected from the group consisting of: (a) an aliphatic alcohol sulfate; an alkylaryl sulfate, an alkyl, aryl or alkyaryl sulfonate; a sulfosuccinate; an N-acyl-N-alkyl taurate; and a sulfoalkyl ester of a fatty acid; which mixed complex salt has the formula: [R--(OC.sub.y H.sub.2y).sub.n --A.sub.m --(O).sub.p --SO.sub.3 ].sub.x m.I[Al.sub.2 (SO.sub.4).sub.3 ] in which R is an aliphatic radical containing 1 to 30 carbon atoms or alkylaryl hydrophobic residue having an alkyl radical containing 1 to 30 carbon atoms; n is the number of alkylene oxide groups and can be from 0 to about 100; y is a number from 2 to 4; A is a radical selected from the group consisting of ##STR6## in which R' is H or an alkyl group of 1 to 4 carbon atoms; R" is an alkali metal or an alkyl group having from 8 to 22 carbon atoms; m and p are each the numbers 0 or 1, M is a cation having a valence of x, and is selected from the group of alkali metal, alkaline earth metal, manganese, zinc, copper, iron, cobalt, nickel, or nitrogen containing base radicals; x is the hydrogen equivalence value of M and can be 1 or 2; and I can be a number from about 0.001 to about 6; and (b) a sulfated ethylene oxide-propylene oxide block polymer, which mixed salt has the formula: I Al.sub.2 (SO.sub.4).sub.3.M.sub.d [(H).sub.f (SO.sub.4).sub.d (C.sub.2 H.sub.4 O).sub.a (C.sub.3 H.sub.6 O).sub.b (C.sub.2 H.sub.4 O).sub.c (SO.sub.3).sub.e H.sub.g ].sub.x M.sub.e.I Al.sub.2 (SO.sub.4).sub.3 in which b is an integer from 15 to 60; a and c are each at least 1 and a+c is an integer from 4 to 300; M, x and I are as defined above; f+d and e+g are equal to 1; and d and e are each a number from 0.1 to 1.0.
Claim 2
Dependent Claim 327 words
An aqueous solution of from about 10 weight % to about 60 weight % of a soluble mixed complex salt of aluminum sulfate and a neutralized organic salt selected from the group consisting of: (a) an aliphatic alcohol sulfate; an alkylaryl sulfate, an alkyl, aryl or alkyaryl sulfonate; a sulfosuccinate; an N-acyl-N-alkyl taurate; and a sulfoalkyl ester of a fatty acid; which mixed complex salt has the formula: [R--(OC.sub.y H.sub.2y).sub.n --A.sub.m --(O).sub.p --SO.sub.3 ].sub.x m.I[Al.sub.2 (SO.sub.4).sub.3 ] in which R is an aliphatic radical containing 1 to 30 carbon atoms or alkylaryl hydrophobic residue having an alkyl radical containing 1 to 30 carbon atoms; n is the number of alkylene oxide groups and can be from 0 to about 100; y is a number from 2 to 4; A is a radical selected from the group consisting of ##STR6## in which R' is H or an alkyl group of 1 to 4 carbon atoms; R" is an alkali metal or an alkyl group having from 8 to 22 carbon atoms; m and p are each the numbers 0 or 1, M is a cation having a valence of x, and is selected from the group of alkali metal, alkaline earth metal, manganese, zinc, copper, iron, cobalt, nickel, or nitrogen containing base radicals; x is the hydrogen equivalence value of M and can be 1 or 2; and I can be a number from about 0.001 to about 6; and (b) a sulfated ethylene oxide-propylene oxide block polymer, which mixed salt has the formula: I Al.sub.2 (SO.sub.4).sub.3.M.sub.d [(H).sub.f (SO.sub.4).sub.d (C.sub.2 H.sub.4 O).sub.a (C.sub.3 H.sub.6 O).sub.b (C.sub.2 H.sub.4 O).sub.c (SO.sub.3).sub.e H.sub.g ].sub.x M.sub.e.I Al.sub.2 (SO.sub.4).sub.3 in which b is an integer from 15 to 60; a and c are each at least 1 and a+c is an integer from 4 to 300; M, x and I are as defined above; f+d and e+g are equal to 1; and d and e are each a number from 0.1 to 1.0.
Claim 3
Dependent Claim 141 words
The aqueous solution of claim 1, wherein said mixed salt is of aluminum sulfate and an aliphatic alcohol sulfate or an alkylaryl hydrophobe sulfate, and said soluble mixed complex salt has the formula: [R--(OC y CH 2y ) n --OSO 3 ] x M.I[Al 2 (SO 4 ) 3 ] in which R represents the residue of an aliphatic alcohol or an alkylaryl hydrophobe having from 1 to 30 carbon atoms; n is a number from 1 to 100; y is a number from 2 to 4; M is a cation having a valence of x selected from the group consisting of alkali metal, alkaline earth metal, manganese, zinc, copper, iron, cobalt, nickel, and nitrogen containing base radicals, x is the hydrogen equivalence value of M and can be 1 or 2, and I is a number from 0.001 to 6.
Claim 4
Dependent Claim 13 words
The aqueous solution of claim 2, wherein I is from 0.167 to 1.
Claim 5
Dependent Claim 18 words
The aqueous solution of claim 2, wherein R is a lauryl, oleyl, 2-ethyl hexyl, myristyl, nonyl phenoxyethoxy radical.
Claim 6
Dependent Claim 19 words
The aqueous solution of claim 2, wherein R is an alkyl group of from 8 to 22 carbon atoms.
Claim 7
Dependent Claim 13 words
The aqueous solution of claim 2, wherein n is from 0.5 to 100.
Claim 8
Dependent Claim 10 words
The aqueous solution of claim 2, wherein m is 1.
Claim 9
Dependent Claim 13 words
The aqueous solution of claim 2, wherein n is from 1 to 50.
Claim 10
Dependent Claim 8 words
The aqueous solution of claim 2, wherein n=0.
Claim 11
Dependent Claim 8 words
The aqueous solution of claim 2, wherein m=0.
Claim 12
Dependent Claim 29 words
The aqueous solution of claim 2, wherein the amount of complex salt is between about 10 weight % and 35 weight %, based on the weight of the solution.
Claim 13
Dependent Claim 23 words
The aqueous solution of claim 2, wherein M is selected from the group consisting of sodium, potassium, ammonium, magnesium, manganese, and alkyol amines.
Claim 14
Dependent Claim 20 words
The aqueous solution of claim 1, wherein the said complex salt is of aluminum sulfate and a neutralized dialkyl sulfosuccinate.
Claim 15
Dependent Claim 17 words
The aqueous solution of claim 1, wherein said complex salt is aluminum sulfate and a neutralized alkylethoxysulfosuccinate.
Claim 16
Dependent Claim 22 words
The aqueous solution of claim 1, wherein said complex salt is of aluminum sulfate and a neutralized alkyl, aryl, or alkylaryl sulfonate.
Claim 17
Dependent Claim 19 words
The aqueous solution of claim 1, wherein said complex salt is of aluminum sulfate and a neutralized N-acyl-N-alkyl taurate.
Claim 18
Dependent Claim 23 words
The aqueous solution of claim 1, wherein said complex salt is of aluminum sulfate and a neutralized sulfoalkyl ester of a fatty acid.
Claim 19
Dependent Claim 177 words
The aqueous solution of claim 1, wherein said complex salt is of aluminum sulfate and a neutralized, sulfated ethylene oxide-propylene oxide block polymer, and said soluble mixed complex salt has the formula: I AL 2 (SO 4 ) 3 .M d [(H) f (SO 4 ) d (C 2 H 4 O) a (C 3 H 6 O) b (C 2 H 4 O) c (SO 3 ) e H g ] x M e .I Al 2 (SO 4 ) 3 in which b represents an integer from 15 to 60; a and c are each at least 1 and a+c represents an integer from 4 to 300; f+d and e+g equal 1; d and e represent a number from 0.1 to 1; M represents a cation having a valence of x selected from the group consisting of alkali metal, alkaline earth metal, manganese, zinc, copper, iron, cobalt, nickel, and nitrogen containing base radicals, x is the equivalent value of M and can be 1 or 2; and I is a number from 0.001 to 6.

References Cited (Backward Citations)

US2304230A Cited
US2757193A Cited
US2766212A Cited
US3011977A Cited
US3133946A Cited
US3910978A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-06 1981-09-05 1982-03-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-06 1985-09-05 1986-03-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-06 1989-09-05 1990-03-07 $7700.00 Window Closed / Lapsed

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