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US4077902A Expired / Lapsed US ⏱️ 0.0 years remaining

Nickel stabilizers for synthetic polymers

Assignee: Novartis Corp
•
Filing: 1976-03-03
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Granted: 1978-03-07
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Expires: 1996-03-03
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Abstract

Abstract Mixtures consisting of a compound of the formula I ##STR1## wherein either R 1 represents a hydroxyl group and R 2 represents hydrogen or R 1 represents hydrogen and R 2 represents a hydroxyl group, R 3 and R 4 independently of one another represent hydrogen or alkyl, and n represents a value from 0 to 2, and a compound of the formula II ##STR2## wherein R 5 represents alkyl, cycloalkyl, aralkyl, aryl or aralkyl or aryl groups which are mono-, di or tri-substituted by hydroxyl, alkyl, chlorine and/or alkoxy groups, alkoxy, cycloalkoxy, aralkoxy, aryloxy or aralkoxy or aryloxy which are mono-substituted or di-substituted in the aryl radical by alkyl, chlorine and/or alkoxy, R 6 represents hydrogen, alkyl, cycloalkyl, aralkyl, aryl or aralkyl or aryl groups which are mono-, di- or tri-substituted by hydroxyl, alkyl, chlorine and/or alkoxy groups, alkoxy, cycloalkoxy, aralkoxy, aryloxy or aralkoxy or aryloxy which are mono-substituted or di-substituted in the aryl radical by alkyl, chlorine and/or alkoxy, and m represents a value from 0 to 2.5, are valuable for stabilizing polymeric substrates.

Inventors

  • 👤 Paul Moser
  • 👤 Jean Rody

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 09:41
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0091

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 170 words
Mixtures consisting of a compound of the formula I ##STR34## wherein either R 1 represents a hydroxyl group and R 2 represents hydrogen or R 1 represents hydrogen and R 2 represents a hydroxyl group, R 3 and R 4 independently of one another represent hydrogen or alkyl, and n represents a value from 0 to 2, and a compound of the formula II ##STR35## wherein R 5 represents alkyl, cycloalkyl, aralkyl, aryl or aralkyl or aryl groups which are mono-, di- or tri-substituted by hydroxyl, alkyl, chlorine and/or alkoxy groups, alkoxy, cycloalkoxy, aralkoxy, aryloxy, or aralkoxy or aryloxy which are mono-substituted or di-substituted in the aryl radical by alkyl, chlorine and/or alkoxy, R 6 represents hydrogen, alkyl, cycloalkyl, aralkyl, aryl or aralkyl or aryl groups which are mono-, di- or tri-substituted by hydroxyl, alkyl, chlorine and/or alkoxy groups, alkoxy, cycloalkoxy, aralkoxy, aryloxy or aralkoxy or aryloxy which are mono-substituted or di-substituted in the aryl radical by alkyl, chlorine and/or alkoxy, and m represents a value from 0 to 2.5.
Claim 2
Dependent Claim 170 words
Mixtures consisting of a compound of the formula I ##STR34## wherein either R 1 represents a hydroxyl group and R 2 represents hydrogen or R 1 represents hydrogen and R 2 represents a hydroxyl group, R 3 and R 4 independently of one another represent hydrogen or alkyl, and n represents a value from 0 to 2, and a compound of the formula II ##STR35## wherein R 5 represents alkyl, cycloalkyl, aralkyl, aryl or aralkyl or aryl groups which are mono-, di- or tri-substituted by hydroxyl, alkyl, chlorine and/or alkoxy groups, alkoxy, cycloalkoxy, aralkoxy, aryloxy, or aralkoxy or aryloxy which are mono-substituted or di-substituted in the aryl radical by alkyl, chlorine and/or alkoxy, R 6 represents hydrogen, alkyl, cycloalkyl, aralkyl, aryl or aralkyl or aryl groups which are mono-, di- or tri-substituted by hydroxyl, alkyl, chlorine and/or alkoxy groups, alkoxy, cycloalkoxy, aralkoxy, aryloxy or aralkoxy or aryloxy which are mono-substituted or di-substituted in the aryl radical by alkyl, chlorine and/or alkoxy, and m represents a value from 0 to 2.5.
Claim 3
Dependent Claim 294 words
Mixtures according to claim 1, wherein R 1 denotes a hydroxyl group, R 2 denotes hydrogen, R 3 and R 4 independently of one another denote hydrogen or alkyl having 1 to 5 carbon atoms, R 5 denotes alkyl having 1 to 18 atoms, cyclohexyl, aralkyl having 7 to 11 carbon atoms, aryl having 6 to 1 carbon atoms, aralkyl or aryl groups which aremono-, di- or tri-substituted by hydroxyl, alkyl having 1 to 4 carbon atoms, chlorine and/or alkoxy groups having 1 to 4 carbon atoms, the aralkyl radical containing 7 to 11 carbon atoms and the aryl radical containing 6 to 10 carbon atoms, alkoxy having 1 to 12 carbon atoms, cyclohexoxy, aralkoxy having 7 to 11 carbon atoms, aryloxy having 6 to 10 carbon atoms, or aralkoxy or aryloxy which are substituted in the aryl radical by methyl, chlorine and/or methoxy, the aralkoxy radical containing 7 to 11 carbon atoms and the aryloxy radical containing 6 to 10 carbon atoms, and R 6 denotes hydrogen, alkyl having 1 to 18 carbon atoms, cyclohexyl, aralkyl having 7 to 11 carbon atoms, aryl having 6 to 10 carbon atoms, aralkyl or aryl which are mono-, di- or tri-substituted by hydroxyl, alkyl having 1 to 4 carbon atoms, chlorine and/or alkoxy groups having 1 to 4 carbon atoms, the aralkyl radical containing 7 to 11 carbon atoms and the aryl radical containing 6 to 10 carbon atoms, alkoxy having 1 to 12 carbon atoms, cyclohexoxy, aralkoxy having 7 to 11 carbon atoms, aryloxy having 6 to 10 carbon atoms, or aralkoxy or aryloxy which are substituted in the aryl radical by methyl, chlorine and/or methoxy, the aralkoxy radical containing 7 to 11 carbon atoms and the aryloxy radical containing 6 to 10 carbon atoms.
Claim 4
Dependent Claim 68 words
Mixtures according to claim 2, wherein R 3 and R 4 denote tert.-butyl, R 5 denotes alkyl having 2 to 18 carbon atoms, cyclohexyl, benzyl, phenyl, 4-hydroxy-3,5-di-tert.-butylbenzyl, alkoxy having 1 to 8 carbon atoms, or phenoxy, R 6 denotes hydrogen, alkyl having 2 to 12 carbon atoms, cyclohexyl, phenyl or alkoxy having 2 to 8 carbon atoms, n denotes 1 to 1.5 and m denotes 0 to 2.
Claim 5
Dependent Claim 39 words
Mixtures according to claim 3, wherein R 5 denotes alkyl having 3 to 18 carbon atoms, 4-hydroxy-3,5-di-tert.-butylbenzyl, n-butoxy or phenoxy, R 6 denotes alkoxy having 2 to 8 carbon atoms, n denotes 1.5 and m denotes 0 to 2.
Claim 6
Dependent Claim 20 words
Mixtures according to claim 1, in which the molar ratio of the compounds I and II is 1:05 to 1:2.
Claim 7
Dependent Claim 19 words
Mixtures according to claim 3, wherein the molar ratio of the compounds I and II is 1:1 to 1:2.
Claim 8
Dependent Claim 14 words
Mixture according to claim 1, consisting of ##STR36## in the molar ratio of 1:1.
Claim 9
Dependent Claim 14 words
Mixture according to claim 1, consisting of ##STR37## in the molar ratio of 1:1.
Claim 10
Dependent Claim 14 words
Mixture according to claim 1, consisting of ##STR38## in the molar ratio of 1:1.
Claim 11
Dependent Claim 14 words
Mixture according to claim 1, consisting of ##STR39## in the molar ratio of 1:1.
Claim 12
Dependent Claim 14 words
Mixture according to claim 1, consisting of ##STR40## in the molar ratio of 1:1.

References Cited (Backward Citations)

US3189630A Cited
US3312658A Cited
US3824192A Cited
US3692738A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-06 1981-09-05 1982-03-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-06 1985-09-05 1986-03-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-06 1989-09-05 1990-03-07 $7700.00 Window Closed / Lapsed

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