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US4076911A
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Ethylene-carbon monoxide copolymers
Assignee: Union Oil Company of California
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Filing: 1975-11-05
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Granted: 1978-02-28
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Expires: 1995-11-05
Abstract
Abstract Thermoplastic, soluble ethylene-carbon monoxide copolymers are produced using a Pd(CN) 2 catalyst in the presence of an alkanoic acid substituted by a halide group on an alpha carbon. The polymers are useful for forming films and fibers and can be incorporated in the thermoplastic, coating or adhesive compositions, e.g., in hot melts, to improve the adhesion and consistency of films prepared therefrom.
Inventors
- 👤 Donald M. Fenton
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 11:20
CPC Classifications
C; C08; C08G; C08G67/00; C08G67/02
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
116 words
The process of producing a high melting point, thermoplastic telomer of ethylene and carbon monoxide having a number of repeating monomeric units within the range of 2 to about 30, which process comprises reacting ethylene and carbon monoxide in a liquid medium containing an alkanoic acid having from 2 to about 6 carbons and bearing at least one halo group on an alpha carbon under reaction conditions including a temperature of about 50° to about 205° C. and a pressure of about 1 to about 200 atmospheres, in the presence of palladium cyanide, the initial ratio of ethylene to carbon monoxide being about 1/5 to about 5/1, sufficient to produce said high melting point, thermoplastic telomer.
Claim 2
Dependent Claim
116 words
The process of producing a high melting point, thermoplastic telomer of ethylene and carbon monoxide having a number of repeating monomeric units within the range of 2 to about 30, which process comprises reacting ethylene and carbon monoxide in a liquid medium containing an alkanoic acid having from 2 to about 6 carbons and bearing at least one halo group on an alpha carbon under reaction conditions including a temperature of about 50° to about 205° C. and a pressure of about 1 to about 200 atmospheres, in the presence of palladium cyanide, the initial ratio of ethylene to carbon monoxide being about 1/5 to about 5/1, sufficient to produce said high melting point, thermoplastic telomer.
Claim 3
Dependent Claim
25 words
The method of claim 1 wherein the number of said repeating monomeric units of said telomer is in the range of 2 to about 15.
Claim 4
Dependent Claim
41 words
The method of claim 1 wherein said ratio of ethylene to carbon monoxide is within the range of about 2/3 to about 7/3 and said alkanoic acid is acetic acid having at least 1 halo group on the alpha carbon atom.
Claim 5
Dependent Claim
36 words
The method of claim 1 which comprises reacting said ethylene and carbon monoxide under said reaction conditions sufficient to produce said telomer having a melting point within the range of about 200° to about 450° C.
Claim 6
Dependent Claim
19 words
The method of claim 1 wherein said halo group is selected from the group consisting of chloro and fluoro.
Claim 7
Dependent Claim
42 words
The thermoplastic ethylenecarbon monoxide copolymer having the empirical formula ##STR3## wherein X is halo, n is a value between 2 and about 30 and R is selected from the group consisting of carboxyalkyl and carboxyhaloalkyl having from 2 to about 6 carbons.
Claim 8
Dependent Claim
42 words
The thermoplastic ethylenecarbon monoxide copolymer having the empirical formula ##STR3## wherein X is halo, n is a value between 2 and about 30 and R is selected from the group consisting of carboxyalkyl and carboxyhaloalkyl having from 2 to about 6 carbons.
Claim 9
Dependent Claim
15 words
The copolymer of claim 6 wherein n is a value between 2 and about 15.
Claim 10
Dependent Claim
18 words
The copolymer of claim 6 wherein said R is selected from the group consisting of carboxymethyl and carboxyhalomethyl.
Claim 11
Dependent Claim
19 words
The thermoplastic copolymer of claim 6 wherein said X is selected from the group consisting of chloro and fluoro.
Claim 12
Dependent Claim
61 words
The composition comprising a telomer of ethylene and carbon monoxide having a melting point within the range of about 200° to about 450° C. and the empirical formula ##STR4## wherein X is halo, n is a value between 2 and about 30 and R is selected from the group consisting of carboxyalkyl and carboxyhaloalkyl having from 2 to about 6 carbons.
Claim 13
Dependent Claim
61 words
The composition comprising a telomer of ethylene and carbon monoxide having a melting point within the range of about 200° to about 450° C. and the empirical formula ##STR4## wherein X is halo, n is a value between 2 and about 30 and R is selected from the group consisting of carboxyalkyl and carboxyhaloalkyl having from 2 to about 6 carbons.
Claim 14
Dependent Claim
43 words
The telomer produced by the method of claim 1 characterized by repeating ethylene and carbon monoxide monomer units and having terminal halo groups at one end and terminal groups at the other end selected from the group consisting of carboxyalkyl and carboxyhaloalkyl radicals.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-02-27 | 1981-08-29 | 1982-02-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-02-27 | 1985-08-29 | 1986-02-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-02-27 | 1989-08-29 | 1990-02-28 | $7700.00 | Window Closed / Lapsed |