Patent US4076849A successfully refreshed from Google Patents.
US4076849A
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Control of nitrosamine formation in nitrite cured meat
Assignee: Maple Leaf Foods Inc
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Filing: 1975-10-02
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Granted: 1978-02-28
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Expires: 1995-10-02
Abstract
Abstract The formation of nitrosamines in cooked, cured meat products is reduced or eliminated by using certain aromatic secondary amines, such as p-alkoxy-N-alkylaminobenzenes, in the curing mixtures or to treat the cured meat.
Inventors
- 👤 Kekhusroo R. Bharucha
- 👤 Leon J. Rubin
- 👤 Charles K. Cross
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 07:58
CPC Classifications
A; A23; A23B; A23B4/00; A23B4/14; A23B4/18; A23B4/20; A23B4/02
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
187 words
a meat treating composition comprising a solution or dispersion of an aromatic secondary amine in a nitrite-containing meat curing solution, the amount of said aromatic secondary amine being effective to reduce the nitrosamine content of nitrite cured meat treated by said composition and cooked at frying temperature, said aromatic secondary amine having the formula: ##STR2## wherein: R 1 is a hydrocarbon radical of one to eighteen carbon atoms; and R 2 , R 3 , R 4 , R 5 and R 6 are each selected from: (a) hydrogen, (b) a hydrocarbon radical as defined for R 1 above, (c) --OR 7 where R 7 is hydrogen or a hydrocarbon radical as defined for R 1 above; or two adjacent members R 2 , R 3 , R 4 , R 5 and R 6 are cyclized to form the group --CH 2 -- n where n is 3 to 5, with the remaining substituents being as defined above; with the proviso that at least one of R 2 , R 3 , R 4 , R 5 and R 6 is --OR 7 as defined above.
Claim 2
Dependent Claim
187 words
a meat treating composition comprising a solution or dispersion of an aromatic secondary amine in a nitrite-containing meat curing solution, the amount of said aromatic secondary amine being effective to reduce the nitrosamine content of nitrite cured meat treated by said composition and cooked at frying temperature, said aromatic secondary amine having the formula: ##STR2## wherein: R 1 is a hydrocarbon radical of one to eighteen carbon atoms; and R 2 , R 3 , R 4 , R 5 and R 6 are each selected from: (a) hydrogen, (b) a hydrocarbon radical as defined for R 1 above, (c) --OR 7 where R 7 is hydrogen or a hydrocarbon radical as defined for R 1 above; or two adjacent members R 2 , R 3 , R 4 , R 5 and R 6 are cyclized to form the group --CH 2 -- n where n is 3 to 5, with the remaining substituents being as defined above; with the proviso that at least one of R 2 , R 3 , R 4 , R 5 and R 6 is --OR 7 as defined above.
Claim 3
Dependent Claim
12 words
The meat treating composition of claim 1 wherein R 4 is alkoxy.
Claim 4
Dependent Claim
26 words
The meat treating composition of claim 1 wherein R 4 is alkoxy and R 2 , R 3 , R 5 and R 6 are hydrogen.
Claim 5
Dependent Claim
34 words
The meat treating composition of claim 1 wherein the meat curing solution is an aqueous solution and the aromatic secondary amine is dispersed in said solution with the aid of an edible emulsifying agent.
Claim 6
Dependent Claim
32 words
The meat curing composition of claim 4 wherein the aromatic secondary amine is present in the solution in an amount of about 0.001 to 0.5% based on the weight of the solution.
Claim 7
Dependent Claim
47 words
A composition for the curing of meats comprising an aqueous curing solution containing sodium chloride, a sugar, an alkali metal nitrite curing salt and from about 0.001 to 0.5% of a p-alkoxy-N-alkylaminobenzene compound wherein the alkoxy and alkyl groups each contain from 1 to 18 carbon atoms.
Claim 8
Dependent Claim
47 words
A composition for the curing of meats comprising an aqueous curing solution containing sodium chloride, a sugar, an alkali metal nitrite curing salt and from about 0.001 to 0.5% of a p-alkoxy-N-alkylaminobenzene compound wherein the alkoxy and alkyl groups each contain from 1 to 18 carbon atoms.
Claim 9
Dependent Claim
184 words
A process for nitrosamine control in nitrite cured meats comprising treating the meat during or after the nitrite cure with an amount of an aromatic secondary amine effective to reduce the quantity of nitrosamines formed when the cured meat is cooked at frying temperature, said aromatic secondary amine having the formula: ##STR3## wherein: R 1 is a hydrocarbon radical of one to eighteen carbon atoms; and R 2 , R 3 , R 4 , R 5 and R 6 are each selected from: (a) hydrogen (b) a hydrocarbon radical as defined for R 1 above, (c) --OR 7 where R 7 is hydrogen or a hydrocarbon radical as defined for R 1 above; or two adjacent members R 2 , R 3 , R 4 , R 5 and R 6 are cyclized to form the group --CH 2 -- n where n is 3 to 5, with the remaining substituents being as defined above; with the proviso that at least one of R 2 , R 3 , R 4 , R 5 and R 6 is --OR 7 as defined above.
Claim 10
Dependent Claim
184 words
A process for nitrosamine control in nitrite cured meats comprising treating the meat during or after the nitrite cure with an amount of an aromatic secondary amine effective to reduce the quantity of nitrosamines formed when the cured meat is cooked at frying temperature, said aromatic secondary amine having the formula: ##STR3## wherein: R 1 is a hydrocarbon radical of one to eighteen carbon atoms; and R 2 , R 3 , R 4 , R 5 and R 6 are each selected from: (a) hydrogen (b) a hydrocarbon radical as defined for R 1 above, (c) --OR 7 where R 7 is hydrogen or a hydrocarbon radical as defined for R 1 above; or two adjacent members R 2 , R 3 , R 4 , R 5 and R 6 are cyclized to form the group --CH 2 -- n where n is 3 to 5, with the remaining substituents being as defined above; with the proviso that at least one of R 2 , R 3 , R 4 , R 5 and R 6 is --OR 7 as defined above.
Claim 11
Dependent Claim
34 words
The process of claim 7 wherein the aromatic secondary amine is applied to the meat in an amount such that the cured meat contains from about 0.002 to 4.0 millimoles per kilogram of meat.
Claim 12
Dependent Claim
34 words
The process of claim 7 wherein the aromatic secondary amine is applied to the meat in an amount such that the cured meat contains from about 0.04 to 1.5 millimoles per kilogram of meat.
Claim 13
Dependent Claim
25 words
The process of claim 7 wherein the aromatic secondary amine is dispersed in the nitrite curing solution and the solution is injected into the meat.
Claim 14
Dependent Claim
27 words
The process of claim 7 wherein the aromatic secondary amine is dissolved in liquid solvent medium and the solution is applied to surfaces of sliced cured meat.
Claim 15
Dependent Claim
16 words
The process of claim 7 wherein the meat is a pork cut for production of bacon.
Claim 16
Dependent Claim
11 words
The process of claim 11 wherein the meat is sliced bacon.
Claim 17
Dependent Claim
68 words
A process for the curing of bacon so as to reduce the quantity of nitrosamines formed when the cured bacon is subjected to frying temperatures, comprising curing said bacon with a nitrite curing solution containing an amount of a p-alkoxy-N-alkyaminobenzene compound sufficient to provide from about 0.04 to 1.5 millimoles per kilogram of meat, the alkoxy and alkyl groups of said compound each containing from 1-18 carbon atoms.
Claim 18
Dependent Claim
68 words
A process for the curing of bacon so as to reduce the quantity of nitrosamines formed when the cured bacon is subjected to frying temperatures, comprising curing said bacon with a nitrite curing solution containing an amount of a p-alkoxy-N-alkyaminobenzene compound sufficient to provide from about 0.04 to 1.5 millimoles per kilogram of meat, the alkoxy and alkyl groups of said compound each containing from 1-18 carbon atoms.
Claim 19
Dependent Claim
32 words
The process of claim 14 wherein the curing solution contains alkali metal nitrite, sodium chloride and a sugar dissolved therein and the p-alkoxy-N-alkylaminobenzene is dispersed in said solution with an edible emulsifier.
Claim 20
Dependent Claim
14 words
The process of claim 14 wherein the curing solution is injected into the meat.
Claim 21
Dependent Claim
58 words
A process for the control of nitrosamine formation during cooking of nitrite cured bacon comprising applying to slices of the cured bacon an edible oil solution of a p-alkoxy-N-alkylaminobenzene compound, said solution being applied to the bacon slices in an amount sufficent to provide from about 0.04 to 1.5 millimoles of the said compound per kilogram of bacon.
Claim 22
Dependent Claim
58 words
A process for the control of nitrosamine formation during cooking of nitrite cured bacon comprising applying to slices of the cured bacon an edible oil solution of a p-alkoxy-N-alkylaminobenzene compound, said solution being applied to the bacon slices in an amount sufficent to provide from about 0.04 to 1.5 millimoles of the said compound per kilogram of bacon.
Claim 23
Dependent Claim
115 words
A nitrite cured meat product containing from about 0.04 to 1.5 millimoles per kilogram of a compound of the formula: ##STR4## wherein: R 1 is a hydrocarbon radical of one to eighteen carbon atoms; R 2 , R 3 , R 4 , R 5 and R 6 are each selected from: (a) hydrogen, (b) A hydrocarbon radical as defined for R 1 above, (c) --OR 7 where R 7 is hydrogen, a hydrocarbon radical as defined for R 1 above, or two adjacent members R 2 , R 3 , R 4 , R 5 and R 6 are cyclized to form the group --CH 2 -- n where n is 3 to 5.
Claim 24
Dependent Claim
115 words
A nitrite cured meat product containing from about 0.04 to 1.5 millimoles per kilogram of a compound of the formula: ##STR4## wherein: R 1 is a hydrocarbon radical of one to eighteen carbon atoms; R 2 , R 3 , R 4 , R 5 and R 6 are each selected from: (a) hydrogen, (b) A hydrocarbon radical as defined for R 1 above, (c) --OR 7 where R 7 is hydrogen, a hydrocarbon radical as defined for R 1 above, or two adjacent members R 2 , R 3 , R 4 , R 5 and R 6 are cyclized to form the group --CH 2 -- n where n is 3 to 5.
Claim 25
Dependent Claim
12 words
The product of claim 18 wherein the nitrite cured meat is bacon.
Claim 26
Dependent Claim
11 words
The product of claim 19 wherein the compound is a p-alkoxy-N-alkylaminobenzene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-02-27 | 1981-08-29 | 1982-02-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-02-27 | 1985-08-29 | 1986-02-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-02-27 | 1989-08-29 | 1990-02-28 | $7700.00 | Window Closed / Lapsed |