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US4076783A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for producing polyester fibers

Assignee: Toyobo Co Ltd
•
Filing: 1974-12-13
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Granted: 1978-02-28
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Expires: 1994-12-13
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Abstract

Abstract A method for producing polyester fibers having excellent dyeability with basic dyes or disperse dyes, which comprises melt-spinning a polyester comprising predominantly (at least 80% by mol) repeating units of ethylene terephthalate and containing 0.5% by mol or more, preferably 1.5 to 5% by mol of an ester unit derived from a dicarboxylic acid or diol containing at least one metal sulfonate group under the condition of being highly oriented so as to give filaments having a birefringence (Δn) of 0.015 to 0.100 and drawing the resulting filaments at a fixed temperature and in a fixed draw ratio, and the polyester fibers which can be dyed with basic dyes or disperse dyes at a temperature of less than 100° C at a sufficiently high dye adsorption rate to give dyed fibers.

Inventors

  • 👤 Hiroshi Yasuda
  • 👤 Susumu Omori

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 02:02
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/688; C08G63/6884; C08G63/6886; D; D01; D01F; D01F6/00; D01F6/78; D01F6/84

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 215 words
A method for producing polyester fibers having excellent dyeability, and capable of being dyed with basic or disperse dyes at a temperature of less than 100° C. with no deterioration of said fibers, which comprises melt-spinning a polyester comprising predominantly repeating units of ethylene terephthalate and containing 0.5% by mol or more of an ester unit derived from a dicarboxylic acid or diol containing at least one metal sulfonate group under the condition of being highly oriented so as to give filaments having a birefringence (Δn) of 0.015 to 0.100 and drawing the resulting filaments at a temperature of less than the melting point of the polymer and satisfying the following equation (1): 100 ≦ T ≦ 4 × (Δn × 10.sup.3) + 70 (1) wherein T is the drawing temperature (° C) and Δn is the birefringence of the filaments obtained after the melt-spinning, and at a draw ratio of from 1.05 times up to the maximum draw ratio of the following equations (2) and (3): ##EQU2## wherein Δn is as defined above, DR max .sbsb.1 and DR max .sbsb.2 are each the maximum draw ratio, and IV f is the intrinsic viscosity of the filaments obtained after the melt-spinning which is measured at 30° C in a mixed solvent of phenol:tetrachloroethane = 3:2.
Claim 2
Independent Claim 215 words
A method for producing polyester fibers having excellent dyeability, and capable of being dyed with basic or disperse dyes at a temperature of less than 100° C. with no deterioration of said fibers, which comprises melt-spinning a polyester comprising predominantly repeating units of ethylene terephthalate and containing 0.5% by mol or more of an ester unit derived from a dicarboxylic acid or diol containing at least one metal sulfonate group under the condition of being highly oriented so as to give filaments having a birefringence (Δn) of 0.015 to 0.100 and drawing the resulting filaments at a temperature of less than the melting point of the polymer and satisfying the following equation (1): 100 ≦ T ≦ 4 × (Δn × 10.sup.3) + 70 (1) wherein T is the drawing temperature (° C) and Δn is the birefringence of the filaments obtained after the melt-spinning, and at a draw ratio of from 1.05 times up to the maximum draw ratio of the following equations (2) and (3): ##EQU2## wherein Δn is as defined above, DR max .sbsb.1 and DR max .sbsb.2 are each the maximum draw ratio, and IV f is the intrinsic viscosity of the filaments obtained after the melt-spinning which is measured at 30° C in a mixed solvent of phenol:tetrachloroethane = 3:2.
Claim 3
Dependent Claim 111 words
The method for producing polyester fibers according to claim 1, wherein the starting polyester contains at least 80% by mol of repeating units of ethylene terephthalate and is produced by copolymerizing ethylene glycol or oxide and terephthalic acid or a functional derivative thereof together with a dicarboxylic acid or diol containing a metal sulfonate group of the formula: ##STR4## wherein Z is a trivalent aromatic or aliphatic hydrocarbon group; R is a member selected from the group consisting of the following formulae: ##STR5## n and m are each an integer of 1 or more; and M is a metal; in the presence or absence of one or more other copolymerizable monomers.
Claim 4
Dependent Claim 42 words
The method for producing polyester fibers according to claim 1, wherein the starting polyester is a blend of the sulfonate group-containing polyester obtained as in claim 2 and a polyester containing at least 80% by mol of repeating units of ethylene terephthalate.
Claim 5
Dependent Claim 41 words
The method for producing polyester fibers according to claim 2, wherein the dicarboxylic acid or diol containing a metal sulfonate group is a member selected from the group consisting of sodium 3,5-di(carbomethoxy)benzenesulfonate, potassium 3,5-di(carbomethoxy)benzenesulfonate, sodium 1,8-di(carbomethoxy)naphthalene-3-sulfonate, potassium 2,5-di(carbomethoxy)benzenesulfonate and potassium 2,5-di(hydroxyethoxy)benzenesulfonate.
Claim 6
Dependent Claim 39 words
The method for producing polyester fibers according to claim 1, wherein the starting polyester contains the sulfonate group-containing ester unit in an amount of 1.5 to 5% by mol and has an intrinsic viscosity [η] of 0.35 to 0.55.
Claim 7
Dependent Claim 29 words
The method for producing polyester fibers according to claim 1, wherein the melt-spinning is carried out so as to give filaments having a birefringence (Δn) of 0.020 to 0.050.
Claim 8
Dependent Claim 52 words
The method for producing polyester fibers according to claim 1, wherein the drawing of the spun filaments is carried out at a temperature of 120° C or higher and lower than the melting point of the polymer and further not higher than 4 × (Δn × 10 3 ) + 60° C.
Claim 9
Dependent Claim 137 words
The method for producing polyester fibers as recited in claim 1, in which the polyester fibers produced cause dye exhaustion in a dye bath of a basic or disperse dye at a temperature of less than 100° C. of at least 81%, said dye exhaustion being measured by colorimetry, wherein the original dye solution is prepared so that the content of the dye is 5% by weight on the basis of the weight of the fibers to be dyed, and when the remaining solution becomes completely colorless the dye exhaustion is 100%, when the color concentration of the remaining solution is half that of the original dye solution the dye exhaustion is 50%, and when the color concentration of the remaining solution is the same as that of the original dye solution the dye exhaustion is 0%.

References Cited (Backward Citations)

US2952879A Cited
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US3527862A Cited
US3539680A Cited
US3448573A Cited
US3936999A Cited
US3771307A Cited
US3832436A Cited
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US3816994A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-27 1981-08-29 1982-02-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-27 1985-08-29 1986-02-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-27 1989-08-29 1990-02-28 $7700.00 Window Closed / Lapsed

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