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N-cyanosulfonamide resins and intermediates therefor and products thereof

Assignee: Novartis Corp
•
Filing: 1976-10-12
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Granted: 1978-02-21
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Expires: 1996-10-12
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Abstract

Abstract This invention provides compositions containing polysulfonamides which are prepared by the addition polymerization of poly-N-cyanosulfonamides. The resins are useful in coating, molding, laminating and casting applications.

Inventors

  • 👤 Raymond J. Kray

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 14:04
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/0622; C08G73/0638; C08G73/065; H; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0313; H05K1/032; H05K1/0346; Y; Y10; Y10S; Y10S428/00; Y10S428/901; Y10S428/902; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31725; Y10T442/00; Y10T442/20; Y10T442/2549; Y10T442/2566

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 104 words
An addition polymerization product of (a) an N-cyanosulfonamide compound of the formula ##STR27## wherein each R' is independently a monovalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical; and x is 1 to 5 (b) with 0 to 20 moles per mole of (a) of a bis-N-cyanosulfonamide compound of the formula ##STR28## wherein R is a divalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical; and each R' is independently a monovalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical; and (c) with 0 to 10 moles per mole of (a) of a bis cyanamide having the formula ##STR29## wherein R is a divalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical.
Claim 2
Dependent Claim 104 words
An addition polymerization product of (a) an N-cyanosulfonamide compound of the formula ##STR27## wherein each R' is independently a monovalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical; and x is 1 to 5 (b) with 0 to 20 moles per mole of (a) of a bis-N-cyanosulfonamide compound of the formula ##STR28## wherein R is a divalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical; and each R' is independently a monovalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical; and (c) with 0 to 10 moles per mole of (a) of a bis cyanamide having the formula ##STR29## wherein R is a divalent aromatic, aliphatic, cycloaliphatic or heterocyclic radical.
Claim 3
Dependent Claim 31 words
The polymerization product of claim 1 which contains up to 25 percent by weight of the total composition of a cyanamide of the formula ##STR30## wherein x is 1 to 5.
Claim 4
Dependent Claim 27 words
The polymerization product of claim 1 wherein 1 to 20 moles of the component (b) is used and 1 to 10 moles of component (c) is used.
Claim 5
Dependent Claim 61 words
The polymerization product of claim 1 wherein x is 1 or 2 or mixtures thereof, and R is a divalent aromatic radical selected from the group consisting of phenylene, bisphenylene, naphthylene and the foregoing radicals linked by divalent groups selected from the group consisting of oxa, carbonyl, lower alkylene, lower alkylidene, sulfonyl, thia, arylimino, amido, and imido; and R' is phenyl.
Claim 6
Dependent Claim 15 words
The polymerization product of claim 2 wherein x is 1 or 2 or mixture thereof.
Claim 7
Dependent Claim 34 words
The polymerization product of claim 1 wherein component (a) has the formula ##STR31## wherein x is 1 or 2 or mixtures thereof; component (b) has the formula ##STR32## component (c) has the formula ##STR33##
Claim 8
Dependent Claim 34 words
The polymerization product of claim 6 which contains up to 25 percent by weight of the total composition of a cyanamide of the formula ##STR34## wherein x is 1 or 2 or mixtures thereof.
Claim 9
Dependent Claim 18 words
The polymerization product of claim 1 formed by the polymerization of an N-cyanosulfonide compound of the formula ##STR35##
Claim 10
Dependent Claim 56 words
The polymerization product formed by the polymerization of (1) from about 5% to 80% by weight of an N-cyanosulfonamide compound of the formula ##STR36## (2) from about 10% to 30% by weight of an N-cyanosulfonamide compound of the formula ##STR37## (3) from about 3% to 84% by weight of a bis-N-cyanosulfonamide compound of the formula ##STR38##
Claim 11
Dependent Claim 56 words
The polymerization product formed by the polymerization of (1) from about 5% to 80% by weight of an N-cyanosulfonamide compound of the formula ##STR36## (2) from about 10% to 30% by weight of an N-cyanosulfonamide compound of the formula ##STR37## (3) from about 3% to 84% by weight of a bis-N-cyanosulfonamide compound of the formula ##STR38##
Claim 12
Dependent Claim 40 words
The composition of claim 9 wherein component (1) is present in an amount of 5% by weight; component (2) is present in an amount of 11% by weight; and component (3) is present in am amount of 84% by weight.
Claim 13
Dependent Claim 40 words
The composition of claim 9 wherein component (1) is present in an amount of 75% by weight; component (2) is present in an amount of 20% by weight; and component (3) is present in an amount of 5% by weight.
Claim 14
Dependent Claim 19 words
A laminate of a polymer of claim 1 which consists essentially of a fibrous substrate impregnated with said polymer.
Claim 15
Dependent Claim 17 words
A laminate according to claim 12 wherein the fibrous substrate in glass, graphite, boron, or aromatic polyamide.
Claim 16
Dependent Claim 9 words
A molded part of a polymer of claim 1.
Claim 17
Dependent Claim 11 words
A cast film or coating of a polymer of claim 1.

References Cited (Backward Citations)

US2531468A Cited
US2853475A Cited
US2813775A Cited
US3308101A Cited
US3497476A Cited
US3654192A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-20 1981-08-22 1982-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-20 1985-08-22 1986-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-20 1989-08-22 1990-02-21 $7700.00 Window Closed / Lapsed

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