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US4075176A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalysis of amino resin cross-linking reactions with high molecular weight sulfonic acids

Assignee: King Industries Inc
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Filing: 1976-05-06
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Granted: 1978-02-21
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Expires: 1996-05-06
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Abstract

Abstract Amino resins, e.g., ureaformaldehyde and melamine-formaldehyde thermosetting resin systems, are catalyzed with high molecular weight polyalkylaromatic polysulfonic acids, e.g., dinonylnaphthalene disulfonic acid and didodecylnaphthalene disulfonic acid. Resins cured with such catalysts provide surface coatings having superior properties. The catalyzed compositions can include other conventional ingredients, capable of co-reacting with the amino resins, such as polyols, polyacids, alkyd resins, polyester resins, and the like, to provide compositions curable to products having a wide range of properties.

Inventors

  • 👤 Lawrence V. Gallacher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 05:33
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/36; C08K5/41; C08K5/42; C08K5/04; C08K5/05; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31616; Y10T428/31623; Y10T428/31627; Y10T428/31678; Y10T428/31681; Y10T428/31688; Y10T428/31725; Y10T428/31942; Y10T428/31949; Y10T428/31964

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 30 words
A composition comprising a convertible amino resin and a catalytically effective amount of a thermally-decomposable adduct of a polyalkylaromatic polysulfonic acid, having a molecular weight of at least about 500.
Claim 2
Dependent Claim 30 words
A composition comprising a convertible amino resin and a catalytically effective amount of a thermally-decomposable adduct of a polyalkylaromatic polysulfonic acid, having a molecular weight of at least about 500.
Claim 3
Dependent Claim 18 words
A composition as defined in claim 1 wherein said adduct comprises a N,N-dimethylhydroxyethylammonium salt of dinonylnaphthalene disulfonic acid.
Claim 4
Dependent Claim 24 words
A composition as defined in claim 1 wherein said polyalkylaromatic polysulfonic acid is dinonylnaphthalene disulfonic acid, the nonyl radicals of which are highly branched.
Claim 5
Dependent Claim 30 words
A composition as defined in claim 1 wherein in said adduct said polyalkylaromatic polysulfonic acid comprises from about 0.1 to 12% by weight based upon the weight of resin solids.
Claim 6
Dependent Claim 32 words
A composition as defined in claim 4 wherein the concentration of polyalkylaromatic polysulfonic acid in said adduct is from about 0.2 to 6% by weight based on the weight of resin solids.
Claim 7
Dependent Claim 16 words
A composition as defined in claim 1 wherein said convertible amino resin is a urea condensate.
Claim 8
Dependent Claim 16 words
A composition as defined in claim 6 wherein said urea condensate is dissolved in a solvent.
Claim 9
Dependent Claim 16 words
A composition as defined in claim 1 wherein said convertible amino resin is a melamine condensate.
Claim 10
Dependent Claim 16 words
A composition as defined in claim 8 wherein said melamine condensate is dissolved in a solvent.
Claim 11
Dependent Claim 17 words
A composition as defined in claim 1 wherein said convertible amino resin is modified with an alcohol.
Claim 12
Dependent Claim 24 words
A composition as defined in claim 1 wherein said convertible amino resin is selected from the group consisting of urea condensates and melamine condensates.
Claim 13
Dependent Claim 19 words
A composition as defined in claim 1 wherein said adduct is an ammonium salt of said polyalkylaromatic polysulfonic acid.
Claim 14
Dependent Claim 19 words
A composition as defined in claim 1 wherein said adduct is an aniline salt of said polyalkylaromatic polysulfonic acid.
Claim 15
Dependent Claim 19 words
A composition as defined in claim 1 wherein said adduct is a triethanolammonium salt of said polyalkylaromatic polysulfonic acid.
Claim 16
Dependent Claim 38 words
A coating composition, the constituents of which comprise (i) an alkoxylated melamine formaldehyde resin; and (ii) an adduct of dinonylnaphthalene disulfonic acid wherein said acid comprises 0.1 - 6% by weight, based on the weight of resin solids.
Claim 17
Dependent Claim 38 words
A coating composition, the constituents of which comprise (i) an alkoxylated melamine formaldehyde resin; and (ii) an adduct of dinonylnaphthalene disulfonic acid wherein said acid comprises 0.1 - 6% by weight, based on the weight of resin solids.
Claim 18
Dependent Claim 16 words
A composition as defined in claim 15 wherein said resin is a methylolated melamine formaldehyde resin.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-20 1981-08-22 1982-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-20 1985-08-22 1986-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-20 1989-08-22 1990-02-21 $7700.00 Window Closed / Lapsed

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