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US4075131A Expired / Lapsed US ⏱️ 0.0 years remaining

Conditioning shampoo

Assignee: 3M Co
•
Filing: 1976-09-17
•
Granted: 1978-02-21
•
Expires: 1996-09-17
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Abstract

Abstract A conditioning shampoo composition especially suited for use in cleansing and conditioning human hair is comprised of an aqueous mixture of detergent and zwitterionic polymer. The detergent may either be an anionic surfactant or an amphoteric surfactant or a mixture thereof.

Inventors

  • 👤 Craig A. Sterling

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 08:47
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/44; A61K8/442; A61K8/45; A61K8/46; A61K8/463; A61K8/72; A61K8/81; A61K8/8141; A61K8/8152; A61Q; A61Q5/00; A61Q5/02; A61Q5/12; C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5428; A61K2800/59; A61K2800/596

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 267 words
A conditioning shampoo composition which consists essentially of from about 1% to about 60% by weight anionic or amphoteric surfactant and at least about 0.5% by weight zwitterionic polymer, said polymer containing at least 10% on a molar basis of zwitterionic moiety, having a viscosity of about 100 to 100,000 cps, when tested at 24.5 ± 0.25% non-volatiles in water (with a Brookfield viscometer, using the appropriate spindle and speed) and being selected from a group consisting of (A) polymers of carboxy betaines having the repeating formula ##STR2## wherein, R 1 represents a polymerizable unsaturated group, x and y represent integers from 1 to 3 inclusive, R 2 and R 3 represent hydrogen, methyl, ethyl or propyl radicals, R 4 and R 5 represent a hydrogen atom or an alkyl radical with the total carbon atoms in R 4 and R 5 not exceeding six, and (B) copolymers of monomers (1) and (2), shown below: (1) substituted acidic vinyl compounds having the general formula CR 7 H═CR 8 CO 2 H wherein R 7 represents a hydrogen atom or a carboxylic acid group and R 8 represents a hydrogen atom, a chlorine atom or a methyl group, and (2) substituted basic vinyl compounds having the general formula CH 2 ═CR 6 COQ wherein R 6 represents a hydrogen atom or a methyl group and Q is an organic radical containing a basic nitrogen-containing group, wherein the mole ratio of basic monomer to acidic monomer in said copolymer is from 0.6:1 to 1.5:1, except where R 7 is CO 2 H, the mole ratio is 1.2:1 to 3:1.
Claim 2
Dependent Claim 267 words
A conditioning shampoo composition which consists essentially of from about 1% to about 60% by weight anionic or amphoteric surfactant and at least about 0.5% by weight zwitterionic polymer, said polymer containing at least 10% on a molar basis of zwitterionic moiety, having a viscosity of about 100 to 100,000 cps, when tested at 24.5 ± 0.25% non-volatiles in water (with a Brookfield viscometer, using the appropriate spindle and speed) and being selected from a group consisting of (A) polymers of carboxy betaines having the repeating formula ##STR2## wherein, R 1 represents a polymerizable unsaturated group, x and y represent integers from 1 to 3 inclusive, R 2 and R 3 represent hydrogen, methyl, ethyl or propyl radicals, R 4 and R 5 represent a hydrogen atom or an alkyl radical with the total carbon atoms in R 4 and R 5 not exceeding six, and (B) copolymers of monomers (1) and (2), shown below: (1) substituted acidic vinyl compounds having the general formula CR 7 H═CR 8 CO 2 H wherein R 7 represents a hydrogen atom or a carboxylic acid group and R 8 represents a hydrogen atom, a chlorine atom or a methyl group, and (2) substituted basic vinyl compounds having the general formula CH 2 ═CR 6 COQ wherein R 6 represents a hydrogen atom or a methyl group and Q is an organic radical containing a basic nitrogen-containing group, wherein the mole ratio of basic monomer to acidic monomer in said copolymer is from 0.6:1 to 1.5:1, except where R 7 is CO 2 H, the mole ratio is 1.2:1 to 3:1.
Claim 3
Dependent Claim 12 words
The composition of claim 1 wherein said zwitterionic monomer is beta-methacryloxyethyl-beta-dimethylaminopropionate betaine.
Claim 4
Dependent Claim 27 words
The composition of claim 1 wherein said acidic vinyl compound monomer is selected from the group consisting of acrylic acid, methacrylic acid, maleic acid and alphachloroacrylic acid.
Claim 5
Dependent Claim 27 words
The composition of claim 1 wherein said basic vinyl compound monomer is selected from the group consisting of dialkylaminoalkyl methacrylates, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylamides and dialkylaminoalkyl acrylamides.
Claim 6
Dependent Claim 21 words
The composition of claim 1 wherein said zwitterionic copolymer is obtained by polymerizing acrylic acid with dimethylaminoethyl methacrylate or diethylaminoethyl acrylate.
Claim 7
Dependent Claim 21 words
The composition of claim 1 wherein said zwitterionic polymer comprises from about 0.5 to about 5% by weight of said composition.
Claim 8
Dependent Claim 28 words
The composition of claim 1 wherein said anionic or amphoteric surfactant is replaced up to one third of its weight with a cosmetically acceptable foam building nonionic surfactant.
Claim 9
Dependent Claim 25 words
The composition of claim 7 wherein said non-ionic surfactant is selected from the group consisting of alkyl phenoxy poly(ethyleneoxy) alkanol and fatty acid alkanol amides.
Claim 10
Dependent Claim 11 words
The composition of claim 1 wherein there is also contained protein.
Claim 11
Dependent Claim 32 words
A method of cleansing and conditioning the hair and scalp by applying an aqueous composition as defined in claim 1 to the hair and scalp, working it to a lather and rinsing.
Claim 12
Dependent Claim 35 words
A method of cleansing and conditioning the hair as set forth in claim 10 wherein said zwitterionic polymer is present in an amount of from about 0.5 to about 5% by weight in said composition.
Claim 13
Dependent Claim 46 words
The composition of claim 1 wherein said (A) carboxy betaine polymer also contains non-zwitterionic monomer selected from the group consisting of acrylic and methacrylic acid, vinyl pyrrolidone, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, quaternary ammonium acrylates, quaternary ammonium methacrylates, alkyl acrylates, alkyl methacrylates, acrylamides, methacrylamides, and vinyl acetate.
Claim 14
Dependent Claim 40 words
The composition of claim 1 wherein said (B) copolymer also contains non-zwitterionic monomer selected from the group consisting of vinyl pyrrolidone, dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, quaternary ammonium acrylates, quaternary ammonium methacrylates, alkyl acrylates, alkyl methacrylates, acrylamides, methacrylamides, and vinyl acetate.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-20 1981-08-22 1982-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-20 1985-08-22 1986-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-20 1989-08-22 1990-02-21 $7700.00 Window Closed / Lapsed

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