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US4073761A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyethylene emulsion containing resin binder compositions and processes

Assignee: Occidental Chemical Corp
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Filing: 1975-04-11
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Granted: 1978-02-14
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Expires: 1995-04-11
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Abstract

Abstract Compositions which are useful for binding solid, discrete particles are comprised of a liquid one-step phenol formaldehyde resin, a urea resin component such as urea formaldehyde, an accelerator selected from an acid and a salt of an acid, and an aqueous emulsion of polyethylene. The wet mixtures of the foregoing components exhibit improved flow characteristics in intricate molds. The wet mixtures are useful for molding foundry core compositions and consolidated wood compositions that have improved moisture resistance.

Inventors

  • 👤 Richard C. Bowman
  • 👤 Daniel J. Kay

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 15:50
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/36; C08K5/39; C08K5/405; B; B22; B22C; B22C1/00; B22C1/16; B22C1/20; B22C1/22; C08K5/16; C08K5/21; C08L; C08L61/00; C08L61/04; C08L61/06; C08L61/34; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2991

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 65 words
A composition consisting essentially of a mixture of (1) an aqueous emulsion of polyethylene, (2) an aqueous solution of a compound selected from the group consisting of a strong mineral acid, an organic acid, an ammonium salt of a strong mineral acid and an ammonium salt of an organic acid, and (3) a compound selected from the group consisting of urea, thiourea, and mixtures thereof.
Claim 2
Dependent Claim 65 words
A composition consisting essentially of a mixture of (1) an aqueous emulsion of polyethylene, (2) an aqueous solution of a compound selected from the group consisting of a strong mineral acid, an organic acid, an ammonium salt of a strong mineral acid and an ammonium salt of an organic acid, and (3) a compound selected from the group consisting of urea, thiourea, and mixtures thereof.
Claim 3
Dependent Claim 11 words
The composition of claim 1 wherein said compound comprises ammonium nitrate.
Claim 4
Dependent Claim 39 words
The composition of claim 1 wherein the emulsion of polyethylene contains about 10 to about 70 weight percent solids and is in a proportion of about 1 to about 10 weight percent based on the weight of said composition.
Claim 5
Dependent Claim 109 words
In a binder composition comprising (a) a resinous binder and (b) an accelerator, wherein the resinous binder comprises a one-step phenol-formaldehyde resin and a urea resin component selected from the group consisting of a urea-formaldehyde resin and a thiourea-formaldehyde resin, wherein the improvement comprises the accelerator consisting essentially of a mixture of (1) an aqueous emulsion of polyethylene, (2) an aqueous solution of a compound selected from the group consisting of a strong mineral acid, an organic acid, an ammonium salt of a strong mineral acid and an ammonium salt of an organic acid, and (3) a compound selected from the group consisting of urea, thiourea, and mixtures thereof.
Claim 6
Dependent Claim 109 words
In a binder composition comprising (a) a resinous binder and (b) an accelerator, wherein the resinous binder comprises a one-step phenol-formaldehyde resin and a urea resin component selected from the group consisting of a urea-formaldehyde resin and a thiourea-formaldehyde resin, wherein the improvement comprises the accelerator consisting essentially of a mixture of (1) an aqueous emulsion of polyethylene, (2) an aqueous solution of a compound selected from the group consisting of a strong mineral acid, an organic acid, an ammonium salt of a strong mineral acid and an ammonium salt of an organic acid, and (3) a compound selected from the group consisting of urea, thiourea, and mixtures thereof.
Claim 7
Dependent Claim 36 words
The composition of claim 4 wherein the polyethylene emulsion contains about 10 to about 70 weight percent solids and is in a proportion of about 0.3 to about 5 weight percent based on the resinous components.
Claim 8
Dependent Claim 12 words
The binder composition of claim 4 wherein the compound is ammonium nitrate.
Claim 9
Dependent Claim 133 words
In a process of bonding discrete, solid inert particles with a binder composition comprising (a) a resinous binder and (b) an accelerator to produce a wet mixture and heating the wet mixture to effect setting of the components, said resinous binder comprising a one-step phenol-formaldehyde resin and a urea resin component selected from the group consisting of a urea-formaldehyde resin and a thiourea-formaldehyde resin, wherein the improvement comprises the accelerator consisting essentially of a mixture of (1) an aqueous emulsion of polyethylene, (2) an aqueous solution of a compound selected from the group consisting of a strong mineral acid, an organic acid, an ammonium salt of a strong mineral acid, and an ammonium salt of an organic acid, and (3) a compound selected from the group consisting of urea, thiourea, and mixtures thereof.
Claim 10
Dependent Claim 133 words
In a process of bonding discrete, solid inert particles with a binder composition comprising (a) a resinous binder and (b) an accelerator to produce a wet mixture and heating the wet mixture to effect setting of the components, said resinous binder comprising a one-step phenol-formaldehyde resin and a urea resin component selected from the group consisting of a urea-formaldehyde resin and a thiourea-formaldehyde resin, wherein the improvement comprises the accelerator consisting essentially of a mixture of (1) an aqueous emulsion of polyethylene, (2) an aqueous solution of a compound selected from the group consisting of a strong mineral acid, an organic acid, an ammonium salt of a strong mineral acid, and an ammonium salt of an organic acid, and (3) a compound selected from the group consisting of urea, thiourea, and mixtures thereof.
Claim 11
Dependent Claim 14 words
The process of claim 7 wherein the discrete, solid inert particles comprise foundry sand.
Claim 12
Dependent Claim 39 words
The process of claim 7 wherein the emulsion of polyethylene contains about 10 to about 70 weight percent solids and is in a proportion of about 1 to about 10 weight percent based on the weight of said composition.
Claim 13
Dependent Claim 11 words
The process of claim 7 wherein the compound comprises ammonium nitrate.

References Cited (Backward Citations)

CA575901A Cited
US2923989A Cited
US2943068A Cited
US3059297A Cited
US3306864A Cited
US3184814A Cited
US3666706A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-13 1981-08-15 1982-02-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-13 1985-08-15 1986-02-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-13 1989-08-15 1990-02-14 $7700.00 Window Closed / Lapsed

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