Patent US4073738A successfully refreshed from Google Patents.
US4073738A
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Lubricating oil compositions containing alkyl acrylate or methacrylate polymers and copolymers of styrene and conjugated diene
Assignee: BASF SE
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Filing: 1977-01-11
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Granted: 1978-02-14
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Expires: 1997-01-11
Abstract
Abstract Mineral lubricating oil compositions which contain a predominant proportion of a mineral lubricating oil together with a pour point depressant based on alkyl acrylate or alkyl methacrylate polymers and a viscosity index (VI) improver comprising a special selectively hydrogenated copolymer of styrene and a conjugated diene. The VI improver employed is a selectively hydrogenated, random butadiene-styrene copolymer containing from 35 to 45% by weight of styrene and possessing a particular structure and distribution of the monomers. The compositions exhibit high stability to shear and may therefore in particular be used for lubricating I.C. engines or gearboxes.
Inventors
- 👤 Volker Ladenberger
- 👤 Klaus Bronstert
- 👤 Friedrich Hovemann
- 👤 Petr Simak
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 23:30
CPC Classifications
C; C10; C10M; C10M157/00; C10M2205/00; C10M2205/06; C10M2207/00; C10M2207/02; C10M2207/023; C10M2207/026; C10M2207/10; C10M2207/14; C10M2207/144; C10M2207/146; C10M2209/00; C10M2209/02; C10M2209/08; C10M2209/084; C10M2215/00; C10M2215/086; C10M2215/24; C10M2215/28; C10M2217/00; C10M2217/02; C10M2217/028; C10M2217/06; C10M2219/00; C10M2219/04; C10M2219/044; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/045; C10M2229/00; C10M2229/02; C10M2229/04; C10M2229/05; C10N; C10N2010/00; C10N2010/04
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
279 words
A mineral lubricating oil composition containing (a) a predominant proportion by weight of mineral lubricating oil, (b) from 0.05 to 2.5% by weight, based on the mineral lubricating oil, of a pour point depressant based on an alkyl acrylate or alkyl methacrylate polymer and (c) from 0.5 to 6% by weight, based on the mineral lubricating oil, of a selectively hydrogenated, random butadiene-styrene copolymer comprising from 35 to 45% by weight of styrene units and from 65 to 55% by weight of hydrogenated butadiene units, which copolymer, prior to hydrogenation, has a 1,2-vinyl content of the polymerized butadiene units of from 23 to 40% by weight, based on copolymerized butadiene units, and which has a 13 C-NMR spectrum in which the ratio of the sum of the intensities of the signals of the CH 2 groups in the β-position and the CH 2 groups of the ethyl branches, ΣCH 2 (β + ethyl), to the sum of the intensities of the signals of the γ-CH 2 and δ-CH 2 carbon atoms and CH 2 carbon atoms more remote from the branch points, ΣCH 2 (γ, δ and more remote), is from 1:1 to 1:1.4, and has an IR spectrum in which the ratio of the extinctions, E, of the styrene bands at 1,180 cm -1 and 1,150 cm -1 , E(1,180)/E(1,150), is from 0.6 to 0.73 and the ratio of the extinctions, E, of the styrene bands at 1,190 cm -1 and 1,180 cm -1 , E(1,190)/E(1,180), is from 0.15 to 0.22, and in which the content of olefinic double bonds has been reduced to a residual proportion of less than 5% as a result of the selective hydrogenation.
Claim 2
Dependent Claim
279 words
A mineral lubricating oil composition containing (a) a predominant proportion by weight of mineral lubricating oil, (b) from 0.05 to 2.5% by weight, based on the mineral lubricating oil, of a pour point depressant based on an alkyl acrylate or alkyl methacrylate polymer and (c) from 0.5 to 6% by weight, based on the mineral lubricating oil, of a selectively hydrogenated, random butadiene-styrene copolymer comprising from 35 to 45% by weight of styrene units and from 65 to 55% by weight of hydrogenated butadiene units, which copolymer, prior to hydrogenation, has a 1,2-vinyl content of the polymerized butadiene units of from 23 to 40% by weight, based on copolymerized butadiene units, and which has a 13 C-NMR spectrum in which the ratio of the sum of the intensities of the signals of the CH 2 groups in the β-position and the CH 2 groups of the ethyl branches, ΣCH 2 (β + ethyl), to the sum of the intensities of the signals of the γ-CH 2 and δ-CH 2 carbon atoms and CH 2 carbon atoms more remote from the branch points, ΣCH 2 (γ, δ and more remote), is from 1:1 to 1:1.4, and has an IR spectrum in which the ratio of the extinctions, E, of the styrene bands at 1,180 cm -1 and 1,150 cm -1 , E(1,180)/E(1,150), is from 0.6 to 0.73 and the ratio of the extinctions, E, of the styrene bands at 1,190 cm -1 and 1,180 cm -1 , E(1,190)/E(1,180), is from 0.15 to 0.22, and in which the content of olefinic double bonds has been reduced to a residual proportion of less than 5% as a result of the selective hydrogenation.
Claim 3
Dependent Claim
27 words
A mineral lubricating oil composition as claimed in claim 1, wherein the selectively hydrogenated random butadiene-styrene copolymer has a number-average molecular weight of from 30,000 to 150,000.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-02-13 | 1981-08-15 | 1982-02-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-02-13 | 1985-08-15 | 1986-02-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-02-13 | 1989-08-15 | 1990-02-14 | $7700.00 | Window Closed / Lapsed |