Cured or uncured compositions of homopolymers and copolymers of epihalohydrins

Claim 2

In a cured or uncured composition consisting essentially of: I. a polymer which is A. an epihalohydrin homopolymer, or B. an epihalohydrin copolymer consisting essentially of: 1. at least 5 mol% of an epihalohydrin monomer; and 2.

Claim 3

the remainder being at least one monomer selected from the group consisting of an epihalohydrin other than (1), copolymerizable epoxides other than epihalohydrin, and 5-membered dicarboxylic acid anhydrides; Ii. a second polymer blended with polymer I present in 0% to 50% by weight, based on the weight of polymer I, and being selected from at least one member of the group consisting of polychloroprene, polyvinyl chloride, chlorinated polyethylene and acrylic ester-chloroethylvinyl ether copolymer; and Iii. a curing amount of a 1,8-diazabicyclo(5,4,0(undecene-7 containing curing agent and a metal compound acid acceptor; the improvement wherein component III comprises, on a basis of 100 parts by weight, of polymer I: A. a curing agent consisting of a curing agent which is free from cyclic carboxylic acid anhydride and which is a member selected from the group consisting of 1. from about 1 to 200 parts by weight of an acid salt of (i) 1 mole of polycarboxylic acid with (ii) 1 mole of 1,8-diazabicyclo(5,4,0)undecene-7; 2. 1 to 10 parts by weight of a cyanuric acid salt of 1,8-diazabicyclo(5,4,0)undecene-7; and 3. a mixture of (i) 1 to 200 parts by weight of a polybasic carboxylic acid and (ii) 1 to 10 parts by weight of a neutral salt of 1,8-diazabicyclo(5,4,0)undecene-7; and B. an acid acceptor comprising from about 1 to 20 parts by weight of at least one metal compound selected from the group consisting of: the oxide, hydroxide, carbonate, silicate, phosphate and carboxylic acid salt of a metal of Group II of the Periodic Table of elements; or the oxide, basic carbonate, basic carboxylic acid salt and basic phosphite of a metal of

Claim 4

the remainder being at least one monomer selected from the group consisting of an epihalohydrin other than (1), copolymerizable epoxides other than epihalohydrin, and 5-membered dicarboxylic acid anhydrides; Ii. a second polymer blended with polymer I present in 0% to 50% by weight, based on the weight of polymer I, and being selected from at least one member of the group consisting of polychloroprene, polyvinyl chloride, chlorinated polyethylene and acrylic ester-chloroethylvinyl ether copolymer; and Iii. a curing amount of a 1,8-diazabicyclo(5,4,0(undecene-7 containing curing agent and a metal compound acid acceptor; the improvement wherein component III comprises, on a basis of 100 parts by weight, of polymer I: A. a curing agent consisting of a curing agent which is free from cyclic carboxylic acid anhydride and which is a member selected from the group consisting of 1. from about 1 to 200 parts by weight of an acid salt of (i) 1 mole of polycarboxylic acid with (ii) 1 mole of 1,8-diazabicyclo(5,4,0)undecene-7; 2. 1 to 10 parts by weight of a cyanuric acid salt of 1,8-diazabicyclo(5,4,0)undecene-7; and 3. a mixture of (i) 1 to 200 parts by weight of a polybasic carboxylic acid and (ii) 1 to 10 parts by weight of a neutral salt of 1,8-diazabicyclo(5,4,0)undecene-7; and B. an acid acceptor comprising from about 1 to 20 parts by weight of at least one metal compound selected from the group consisting of: the oxide, hydroxide, carbonate, silicate, phosphate and carboxylic acid salt of a metal of Group II of the Periodic Table of elements; or the oxide, basic carbonate, basic carboxylic acid salt and basic phosphite of a metal of

Claim 5

Group IV-A of the Periodic Table of elements. 2. The composition of claim 1 in which the curing agent is component III(A)(3) wherein the neutral salt of 1,8-diazabicyclo(5,4,0)undecene-7 III(A)(3)(ii) is a salt of the 1,8-diazabicyclo(5,4,0(undecene-7 and a compound selected from the group consisting of phenol, salt-forming derivatives of phenol, carboxylic acids, carbonic acid and weakly acidic inorganic solid acids.

Claim 6

The composition of claim 1 wherein the metals of Group II of metal compound III(B) are metals selected from the group consisting of Mg, Ca, Zn and Ba, and the metals of Group IVb of metal compound III(B) are metals selected from the group consisting of Sn and Pb.

Claim 7

The composition of claim 1 in which the curing agent is component III(A)(1).

Claim 8

The composition of claim 4 in which component III(A)(1) consists of about 1 to about 100 parts by weight of said acid salt per 100 parts by weight of polymer I.

Claim 9

The composition of claim 5 in which the polybasic carboxylic acid III(A)(1)(i) is free from sulfur and is selected from the group consisting of a. aliphatic saturated acids containing 2 to 10 carbon atoms; b. unsaturated dicarboxylic acids containing 4 to 6 carbon atoms; c. unsaturated tribasic carboxylic acids containing 6 carbon atoms; d. hydroxypolycarboxylic acids; e. polycarboxylic acids containing an ether linkage; f. carboxyl-terminated polycondensates formed between polyhydric alcohols and polycarboxylic acids; g. succinic acid derivatives resulting from the addition of maleic acid to an an unsaturated compound selected from the group consisting of rosin; olefin, cyclopentadiene, furan and anthracene; h. alicyclic polycarboxylic acids; and i. aromatic polycarboxylic acid; or j. halogen-substituted, amino-substituted or hydroxy-substituted products of any of the polybasic carboxylic acids (a)-(i).

Claim 10

The composition of claim 5 in which the polybasic carboxylic acid III(A)(1)(i) is selected from the group consisting of aliphatic carboxylic acid containing 4 to 10 carbon atoms.

Claim 11

The composition of claim 7 in which the aliphatic carboxylic acid containing 4 to 10 carbon atoms is a saturated acid selected from the group consisting of succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid and sebacic acid or an unsaturated acid selected from the group consisting of maleic acid, fumaric acid, citraconic acid, isaconic acid, itaconic acid, glutaconic acid and muconic acid.

Claim 12

The composition of claim 1 in which the curing agent is component III(A)(2) cyanuric acid salt of 1,8-diazabicyclo(5,4,0)undecene-7.

Claim 13

The composition of claim 2 wherein said neutral salt of III(A)(3)(ii) is a salt of 1,8-diazabicyclo(5,4,0(undecene-7 and a phenolic substance selected from a group consisting of phenol, cresol, ethylphenol, allylphenol, guaiacol, chlorophenol, resorcinol, bisphenol, bis-(4-hydroxyphenyl)methane and bis-(4-hydroxyphenyl)-2-propane.

Claim 14

The composition of claim 2 wherein said neutral salt III(A)(3)(ii) is a salt of 1,8-diazabicyclo(5,4,0)undecene-7 and a carboxylic acid selected from the group consisting of acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthoic acid, caprylic acid, lauric acid, myristic acid, stearic acid, methylcaproic acid, methylcaprylic acid, ethylcaproic acid, ethylcaprylic acid, acrylic acid, methacrylic acid, crotonic acid, oleic acid, cyclohexane-carboxylic acid, glycolic acid, lactic acid, glycine, alanine, benzoic acid, toulene-carboxylic acid, cinnamic acid, aminobenzoic acid, hydroxybenzoic acid, chlorobenzoic acid, naphthalenecarboxylic acid, pyridinecarboxylic acid, succinic acid, fumaric acid, glutaric acid, adipic acid, sebacic acid, phthalic acid, trimellitic acid, tetrahydrophthalic acid, hexahydrophthalic acid, dodecenylsuccinic acid, tartaric acid and diglycolic acid.

Claim 15

The composition of claim 2 wherein said polybasic carboxylic acid III(A)(3)(i) is free from sulfur and is a member selected from the group consisting of a. aliphatic saturated acids containing 2 to 10 carbon atoms; b. unsaturated dicarboxylic acids containing 4 to 6 carbon atoms; c. unsaturated tribasic carboxylic acids containing 6 carbon atoms; d. hydroxypolycarboxylic acids; e. polycarboxylic acids containing an ether linkage; f. carboxyl-terminated polycondensates formed between polyhydric alcohols and polycarboxylic acids; g. succinic acid derivatives resulting from the addition of maleic acid to an unsaturated compound selected from the group consisting of rosin, olefin, cyclopentadiene, furan and anthracene; h. alicyclic polycarboxylic acid; and i. aromatic polycarboxylic acid; or j. halogen-substituted, amino-substituted or hydroxy-substituted products of any of the polybasic carboxylic acids (a)-(i).

Claim 16

The composition of claim 2 which polycarboxylic acid III(A)(3)(i) is from about 1 to about 100 parts by weight.

Claim 17

The composition of claim 3 wherein metal compound III(B) is at least one member selected from the group consisting of magnesium oxide (magnesia), calcium oxide (quicklime), calcium hydroxide (slaked lime), barium oxide, zinc oxide (zinc white), magnesium carbonate, barium carbonate, strontium carbonate, calcium carbonate, magnesium silicate, calcium silicate, magnesium phthalate, calciumphthalate, calcium stearate, magnesium benzoate, calcium oleate, calcium citrate, calcium phosphite, magnesium phosphite, triplubmic tetroxice (red lead), lead monoxide (litharge), stannic oxide, dibasic lead carbonate (white lead), dibasic lead phthalate, dibasic lead stearate and dibasic lead phosphite.

Claim 18

The composition of claim 1 which is cured.

Claim 19

The composition of claim 2 which is cured.

Claim 20

The composition of claim 2 in which the curing agent III(A)(3) is a mixture of itaconic acid, sebacic acid or adipic acid and 2-ethylhexane acid salt of 1,8-diazabicyclo(5,4,0)undecene-7.

Claim 21

The composition of claim 16 in which the curing agent III(A)(3) is a mixture of sebacic acid and 2-ethylhexane acid salt of 1,8-diazabicyclo(5,4,0)undecene-7.

Claim 22

The composition of claim 4 in which component III(A)(i) is succinic acid salt or sebacic salt of 1,8-diazabicyclo(5,4,0)undecene-7.

Claim 23

The composition of claim 19 in which the curing agent III(A)(1) is sebacic acid salt of 1,8-diazabicyclo(5,4,0)undecene-7.

Claim 24

The composition of claim 20 which is cured.