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Process for the manufacture of maleic anhydride

Assignee: Norsolor SA
•
Filing: 1976-10-21
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Granted: 1978-01-24
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Expires: 1996-10-21
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Abstract

Abstract A process for the manufacture of maleic anhydride by the oxidation of benzene with oxygen in the presence of a catalyst which has been previously activated and which comprises an inert support coated with a catalytically active mass containing by weight 10% to 20% of antimony trioxide, 40% to 70% of vanadium pentoxide, 20% to 50% of molybdenum trioxide, 0.7% to 1.5% of phosphorus pentoxide, 0.9% to 2.0% of sodium oxide and possibly another mineral oxide.

Inventors

  • 👤 Jean Henri Camille Ciquier
  • 👤 Michel Hyppolite Carfantan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 13:38
CPC Classifications
C; C07; C07C; C07C51/00; C07C51/16; C07C51/31; C07C51/313; B; B01; B01J; B01J23/00; B01J23/002; B01J23/16; B01J23/24; B01J23/28; B01J27/00; B01J27/14; B01J27/186; B01J27/195; B01J27/198; B01J27/199; B01J2523/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 93 words
A process for the manufacture of maleic anhydride by the oxidation of benzene with oxygen in the presence of a catalyst which has been previously activated and which comprises an inert support coated with a catalytically active mass containing, by weight, 10% to 20% of antimony trioxide, 40% to 70% of vanadium pentoxide, 20% to 50% of molybdenum trioxide, 0.7% to 1.5% of phosphorus pentoxide, 0.9% to 2.0% of sodium oxide and optionally another mineral oxide selected from the group consisting of, nickel, calcium, iron, silver, strontium, uranium, tungsten, cobalt, and boron oxides.
Claim 2
Dependent Claim 93 words
A process for the manufacture of maleic anhydride by the oxidation of benzene with oxygen in the presence of a catalyst which has been previously activated and which comprises an inert support coated with a catalytically active mass containing, by weight, 10% to 20% of antimony trioxide, 40% to 70% of vanadium pentoxide, 20% to 50% of molybdenum trioxide, 0.7% to 1.5% of phosphorus pentoxide, 0.9% to 2.0% of sodium oxide and optionally another mineral oxide selected from the group consisting of, nickel, calcium, iron, silver, strontium, uranium, tungsten, cobalt, and boron oxides.
Claim 3
Dependent Claim 23 words
A process according to claim 1 in which the catalytically active mass represents 10% to 20% of the total weight of the catalyst.
Claim 4
Dependent Claim 30 words
A process according to claim 1 in which the catalyst is present in the form of spherically or irregularly-shaped grains having an average particle size of 3 to 8 mm.
Claim 5
Dependent Claim 24 words
A process according to claim 1 in which the inert support comprises alumina, silica, silicon carbide, aluminium silicate or a mixture of these compounds.
Claim 6
Dependent Claim 26 words
A process according to claim 1 in which the hot point of the catalyst is maintained at a temperature of from 400° C. to 450° C.
Claim 7
Dependent Claim 23 words
A process according to claim 1 in which the hot point of the catalyst is maintained at a temperature of about 430° C.
Claim 8
Dependent Claim 20 words
A process according to claim 1 in which 10 to 16 moles of oxygen are used per mole of benzene.
Claim 9
Dependent Claim 17 words
A process according to claim 1 in which the oxygen is used in the form of air.
Claim 10
Dependent Claim 25 words
A process according to claim 1 in which the oxygen is used in the form of air at a pressure of up to two atmospheres.

References Cited (Backward Citations)

US3086026A Cited
US3094539A Cited
US3115477A Cited
US3849448A Cited
US3725472A Cited
US3702868A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-23 1981-07-25 1982-01-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-23 1985-07-25 1986-01-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-23 1989-07-25 1990-01-24 $7700.00 Window Closed / Lapsed

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