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US4069233A
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Fluoroaliphaticsulfonyl substituted ethylenes substituted by furyl, thenyl, or 1H-pyrrolyl groups
Assignee: 3M Co
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Filing: 1976-05-07
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Granted: 1978-01-17
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Expires: 1996-05-07
Abstract
Abstract Fluoroaliphaticsulfonyl substituted ethylenes, useful as catalysts in polymerization of monomers, e.g., epoxide, vinyl ether, and N-vinyl monomers, are prepared by condensation of precursor fluoroaliphaticsulfonyl methanes with aldehydes or N-formyl compounds.
Inventors
- 👤 Robert J. Koshar
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 10:05
CPC Classifications
C; C07; C07D; C07D207/00; C07D207/02; C07D207/30; C07D207/32; C07D207/33; C07D207/333; C07C; C07C317/00; C07C317/02; C07C317/08; C07D295/00; C07D295/04; C07D295/08; C07D295/084; C07D307/00; C07D307/02; C07D307/34; C07D307/38; C08; C08F; C08F4/00; C08G; C08G59/00; C08G59/18; C08G59/68; C08G59/687; C08G65/00; C08G65/02; C08G65/26; C08G65/2642; C08G65/2669; C08G65/2678; C08G65/2684
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
146 words
A fluoroaliphaticsulfonyl ethylene compound especially suited as a catalyst in epoxide, vinyl ether, and N-vinyl monomer polymerization and having the formula wherein R f is monovalent, saturated fluoroalkyl radical having from 1 to 18 carbon atoms; X is a monovalent, nonionic, electron withdrawing radical at least as electron withdrawing as a benzoyl radical selected from the group consisting of a cyano, phenylcarbonyl, alkylcarbonyl, perfluoroalkylcarbonyl of 2 to 18 carbon atoms, phenylsulfonyl, perfluoroalkylsulfonyl of 1-18 carbon atoms, nitro, fluorosulfonyl, or chlorosulfonyl group; R is hydrogen, an alkyl group, or a phenyl group; R' is the same as R with at least one being hydrogen; n is an integer from 0 to 7 depending on Z; n is 1 to 7 when Z is 2-furyl; n is zero when Z is a monovalent unsaturated, conjugated heterocyclic organic radical selected from the group consisting of furyl, thenyl and 1H-pyrrolyl.
Claim 2
Dependent Claim
146 words
A fluoroaliphaticsulfonyl ethylene compound especially suited as a catalyst in epoxide, vinyl ether, and N-vinyl monomer polymerization and having the formula wherein R f is monovalent, saturated fluoroalkyl radical having from 1 to 18 carbon atoms; X is a monovalent, nonionic, electron withdrawing radical at least as electron withdrawing as a benzoyl radical selected from the group consisting of a cyano, phenylcarbonyl, alkylcarbonyl, perfluoroalkylcarbonyl of 2 to 18 carbon atoms, phenylsulfonyl, perfluoroalkylsulfonyl of 1-18 carbon atoms, nitro, fluorosulfonyl, or chlorosulfonyl group; R is hydrogen, an alkyl group, or a phenyl group; R' is the same as R with at least one being hydrogen; n is an integer from 0 to 7 depending on Z; n is 1 to 7 when Z is 2-furyl; n is zero when Z is a monovalent unsaturated, conjugated heterocyclic organic radical selected from the group consisting of furyl, thenyl and 1H-pyrrolyl.
Claim 3
Dependent Claim
20 words
The compound of claim 1 wherein X is SO 2 R' f wherein R' f is perfluoroalkyl of 1-18 carbons.
Claim 4
Dependent Claim
14 words
The compound of claim 2 wherein R' f and R f are perfluoromethyl groups.
Claim 5
Dependent Claim
1 words
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Claim 6
Dependent Claim
1 words
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Claim 7
Dependent Claim
1 words
##STR17##
Claim 8
Dependent Claim
1 words
##STR17##
References Cited (Backward Citations)
US3632843A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-01-16 | 1981-07-18 | 1982-01-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-01-16 | 1985-07-18 | 1986-01-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-01-16 | 1989-07-18 | 1990-01-17 | $7700.00 | Window Closed / Lapsed |