Patent US2928544A successfully refreshed from Google Patents.
Patent US4069209A successfully refreshed from Google Patents.
US4069209A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Imino acids and resins derived therefrom
Assignee: Elantas PDG Inc
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Filing: 1976-04-12
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Granted: 1978-01-17
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Expires: 1996-04-12
Abstract
Abstract This invention relates to imino dicarboxylic acids (IDA) of the general formulae ##STR1## and ##STR2## where IS A MOIETY, PREFERABLY AROMATIC, R is a moiety, preferably aliphatic, and to resins derived from such acids. Such resins, which may vary widely, are illustrated by polyesters, poly(ester-amides), poly (ester-imides), poly(ester-imide-amides), etc. In the preferred embodiment such resins contain tris (hydroxyethyl) isocyanurate. The preferred IDA, which is derived from trimellitic anhydride (TMA) and glycine, has the following idealized formula ##STR3## and IS THE PREDOMINANT DICARBOXYLIC ACID EMPLOYED IN SUCH RESINS.
Inventors
- 👤 Daniel J. Lange
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 14:35
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/303; H01B3/305; C; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G69/00; C08G69/44; C08G73/00; C08G73/06; C08G73/10; C08G73/16; H01B3/306; H01B3/42; H01B3/421; H01B3/422; H01B3/423
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
257 words
A resin which is a polyester of A. a dicarboxylic acid component which is a preformed iminodicarboxylic acid of the formula ##STR37## or ##STR38## where Z and Z' are aromatic moieties, the indicated ##STR39## group attached to Z being attached to an aromatic ring of Z, the ##STR40## groups linking an N to Z or Z' each being attached to an aromatic ring in Z or Z' and being present in a 5 membered imide ring and the moiety R being divalent aliphatic, the N and COOH moieties attached to R being attached to carbons of R, and of a polyhydric alcohol component which is at least one of B. a glycol component, and C. a polyol component containing at least three esterifiable hydroxyl groups, and any further components of said resin being D. the imide or imide-amide of D 1 . an aromatic diamine and D 2 . an aromatic tricarboxylic or aromatic tetracarboxylic acid, of the formulae, respectively, ##STR41## , and ##STR42## two of the COOH groups of the acid (a) and each of the COOH groups of each of the two pairs of such groups of the acid (b) being attached to adjacent carbons of a benzene ring of the Z" and Z'" moieties, respectively, Z" and Z'" being aromatic moieties, where (A) and at least one of (B) and (C) and (D) are the sole polymer forming components of said resin and only the components (A) and at least one of (B) and (C) are required to be present as polymer forming components.
Claim 2
Dependent Claim
257 words
A resin which is a polyester of A. a dicarboxylic acid component which is a preformed iminodicarboxylic acid of the formula ##STR37## or ##STR38## where Z and Z' are aromatic moieties, the indicated ##STR39## group attached to Z being attached to an aromatic ring of Z, the ##STR40## groups linking an N to Z or Z' each being attached to an aromatic ring in Z or Z' and being present in a 5 membered imide ring and the moiety R being divalent aliphatic, the N and COOH moieties attached to R being attached to carbons of R, and of a polyhydric alcohol component which is at least one of B. a glycol component, and C. a polyol component containing at least three esterifiable hydroxyl groups, and any further components of said resin being D. the imide or imide-amide of D 1 . an aromatic diamine and D 2 . an aromatic tricarboxylic or aromatic tetracarboxylic acid, of the formulae, respectively, ##STR41## , and ##STR42## two of the COOH groups of the acid (a) and each of the COOH groups of each of the two pairs of such groups of the acid (b) being attached to adjacent carbons of a benzene ring of the Z" and Z'" moieties, respectively, Z" and Z'" being aromatic moieties, where (A) and at least one of (B) and (C) and (D) are the sole polymer forming components of said resin and only the components (A) and at least one of (B) and (C) are required to be present as polymer forming components.
Claim 3
Dependent Claim
24 words
The resin of claim 1 where the iminodicarboxylic acid component has at least one of the formulae ##STR43## and ##STR44## where n = 1-5.
Claim 4
Dependent Claim
21 words
The resin of claim 2 where the resin is a polyester of (A), (B) and (C), the components (D) being absent.
Claim 5
Dependent Claim
18 words
The resin of claim 2 where the resin is a poly(esterimide) of components (A), (B), (C) and (D).
Claim 6
Dependent Claim
18 words
The resin of claim 2 where the resin is a poly(esterimide-amide) of components (A), (B), (C) and (D).
Claim 7
Dependent Claim
14 words
The resin of claim 3 in which the polyol component (C) is tris(hydroxyethyl) isocyanurate.
Claim 8
Dependent Claim
14 words
The resin of claim 4 in which the polyol component (C) is tris(hydroxyethyl) isocyanurate.
Claim 9
Dependent Claim
14 words
The resin of claim 5 in which the polyol component (C) is tris(hydroxyethyl) isocyanurate.
Claim 10
Dependent Claim
14 words
The resin of claim 6 where the component A is the iminodicarboxylic acid ##STR45##
Claim 11
Dependent Claim
14 words
The resin of claim 7 where the component A is the iminodicarboxylic acid ##STR46##
Claim 12
Dependent Claim
15 words
The resin of claim 8 where the component A is the iminodicarboxylic acid is ##STR47##
Claim 13
Dependent Claim
36 words
The resin of claim 9 which is a polyester of 20 equivalents of ethylene glycol, 40 equivalents of tris(hydroxyethyl) isocyanurate and the iminodicarboxylic acid from 40 equivalents of trimellitic acid anhydride and 40 equivalents of glycine.
Claim 14
Dependent Claim
46 words
The resin of claim 10 which is a poly(ester-imide) of 18 equivalents of ethylene glycol, 25 equivalents of tris(hydroxyethyl) isocyanurate, 32 equivalents of trimellitic acid anhydride, 16 equivalents of methylene dianiline and the iminodicarboxylic acid from 9 equivalents of trimellitic acid and 9 equivalents of glycine.
Claim 15
Dependent Claim
47 words
The resin of claim 11 which is a poly(ester-imide-amide) of 18 equivalents of ethylene glycol, 25 equivalents of tris (hydroxyethyl) isocyanurate, 30 equivalents of trimellitic acid anhydride, 18 equivalents of methylene dianiline and the iminodicarboxylic from 9 equivalents of trimellitic acid anhydride and 9 equivalents of glycine.
Claim 16
Dependent Claim
42 words
The resin of claim 2 which is a poly(ester-imide) of 51 equivalents of ethylene glycol, 26 equivalents of trimellitic acid anhydride, 13 equivalents of methylene dianiline and the iminodicarboxylic acid from 10 equivalents of trimellitic acid anhydride and 10 equivalents of glycine.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-01-16 | 1981-07-18 | 1982-01-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-01-16 | 1985-07-18 | 1986-01-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-01-16 | 1989-07-18 | 1990-01-17 | $7700.00 | Window Closed / Lapsed |