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US4066895A Expired / Lapsed US ⏱️ 0.0 years remaining

Scanning mass spectrometer having constant magnetic field

Assignee: Shimadzu Seisakusho Ltd
•
Filing: 1976-09-08
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Granted: 1978-01-03
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Expires: 1996-09-08
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Abstract

Abstract A mass spectrometer wherein the ion beam is deflected for scanning of a mass spectrum or selection of mass numbers, without changing the magnetic field strength and the ion-accelerating voltage. The means for deflecting the ion beam may be arranged between the ion source and the magnetic field or within the magnetic field or between the magnetic field and the ion detector.

Inventors

  • 👤 Masaya Iwanaga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 20:20
CPC Classifications
H; H01; H01J; H01J49/00; H01J49/02; H01J49/06; H01J49/061; H01J49/26; H01J49/28; H01J49/30

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 145 words
A mass spectrometer comprising an ion source for producing and ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means being provided between said ion source of said magnetic field so that as said ion beam is deflected, the point or angle of incidence on said first end face at which said ion beam enters said magnetic field is changed so as to change the radius of curvature of the trajectory of the ion that enters said ion detecting means.
Claim 2
Dependent Claim 145 words
A mass spectrometer comprising an ion source for producing and ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means being provided between said ion source of said magnetic field so that as said ion beam is deflected, the point or angle of incidence on said first end face at which said ion beam enters said magnetic field is changed so as to change the radius of curvature of the trajectory of the ion that enters said ion detecting means.
Claim 3
Dependent Claim 41 words
The mass spectrometer of claim 1, wherein said ion beam deflecting means comprises a pair of electrostatic deflectors arranged in the direction of said ion beam and designed to deflect said ion beam to the same angle but in opposite directions.
Claim 4
Dependent Claim 41 words
The mass spectrometer of claim 1, wherein said ion beam deflecting means comprises a pair of coreless coils arranged in the direction of said ion beam and designed to deflect said ion beam to the same angle but in opposite directions.
Claim 5
Dependent Claim 38 words
The mass spectrometer of claim 1, further including between said magnetic field and said ion detecting means an electrostatic field which cooperates with said magnetic field to satisfy the energy and direction focusing condition for improvement of resolution.
Claim 6
Dependent Claim 124 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means comprising an electrostatic deflector disposed within said magnetic field so that as the electrostatic field strength of said deflector is changed, the radius of curvature of the trajectory of the ion that enters said ion detecting means is changed.
Claim 7
Dependent Claim 124 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means comprising an electrostatic deflector disposed within said magnetic field so that as the electrostatic field strength of said deflector is changed, the radius of curvature of the trajectory of the ion that enters said ion detecting means is changed.
Claim 8
Dependent Claim 54 words
The mass spectrometer of claim 5, wherein said electrostatic deflector comprises an opposed pair of electrode plates composed of parts of concentric hollow cylinders the center of which coincides with that of the circle of the ion trajectory in said magnetic field and means for impressing a variable voltage across said pair of electrodes.
Claim 9
Dependent Claim 119 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means being arranged between said magnetic field and said ion detecting means so that as said ion beam is deflected, the radius of curvature of the trajectory of the ion that enters said ion detecting means changes.
Claim 10
Dependent Claim 119 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means being arranged between said magnetic field and said ion detecting means so that as said ion beam is deflected, the radius of curvature of the trajectory of the ion that enters said ion detecting means changes.
Claim 11
Dependent Claim 40 words
The mass spectrometer of claim 7, wherein said ion beam deflecting means comprises a pair of electrostatic deflectors arranged in the direction of said ion beam designed to deflect said ion beam to the same angle but in opposite directions.
Claim 12
Dependent Claim 41 words
The mass spectrometer of claim 7, wherein said ion beam deflecting means comprises a pair of coreless coils arranged in the direction of said ion beam and designed to deflect said ion beam to the same angle but in opposite directions.
Claim 13
Dependent Claim 37 words
The mass spectrometer of claim 7, further including between said ion source and said magnetic field an electrostatic field which cooperates with said magnetic field to satisfy the energy and direction focusing condition for improvement of resolution.
Claim 14
Dependent Claim 144 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means comprising a first electrostatic deflector arranged between said ion source and said first end face of said magnetic field to deflect said ion beam, a second electrostatic deflector arranged between said second end face of said magnetic field and said ion detecting means and means for operating said first and second electrostatic deflectors in ganged relation to each other.
Claim 15
Dependent Claim 144 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said ion beam deflecting means comprising a first electrostatic deflector arranged between said ion source and said first end face of said magnetic field to deflect said ion beam, a second electrostatic deflector arranged between said second end face of said magnetic field and said ion detecting means and means for operating said first and second electrostatic deflectors in ganged relation to each other.
Claim 16
Dependent Claim 107 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample; and an electrostatic lens arranged between said ion source and said first end face of said magnetic field to converge said ion beam from said ion source.
Claim 17
Dependent Claim 107 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample; and an electrostatic lens arranged between said ion source and said first end face of said magnetic field to converge said ion beam from said ion source.
Claim 18
Dependent Claim 39 words
The mass spectrometer of claim 12, further including another electrostatic lens arranged between said second end face of said magnetic field and said ion detecting means to converge said ion beam to be detected by said ion detecting means.
Claim 19
Dependent Claim 111 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; and analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample; and an electrostatic lens arranged between said second end face of said magnetic field and said ion detecting means to converge said ion beam to be detected by said ion detecting means.
Claim 20
Dependent Claim 111 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; and analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample; and an electrostatic lens arranged between said second end face of said magnetic field and said ion detecting means to converge said ion beam to be detected by said ion detecting means.
Claim 21
Dependent Claim 157 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said magnetic field being so arranged that an ion of a predetermined mass number included in said ion beam emerges from said second end face of said magnetic field to advance at a small angle with said second end face while the ions of smaller mass numbers included in said ion beam do not emerge from said second end face, and said detecting means is so arranged as to detect said ion of said predetermined mass number.
Claim 22
Dependent Claim 157 words
A mass spectrometer comprising an ion source for producing an ion beam of a sample; an analyzer including a constant magnetic field having at least a first end face at which said ion beam enters said magnetic field and a second end face at which said ion beam emerges out of said magnetic field; means for detecting ions; and means for deflecting said ion beam for scanning of the mass spectrum or selection of predetermined mass numbers of said sample, said magnetic field being so arranged that an ion of a predetermined mass number included in said ion beam emerges from said second end face of said magnetic field to advance at a small angle with said second end face while the ions of smaller mass numbers included in said ion beam do not emerge from said second end face, and said detecting means is so arranged as to detect said ion of said predetermined mass number.
Claim 23
Dependent Claim 43 words
The mass spectrometer of claim 15, wherein said ion beam deflecting means comprises a pair of electrostatic deflectors arranged in the direction of said ion beam and so designed as to deflect said ion beam to the same angle but in opposite directions.
Claim 24
Dependent Claim 43 words
The mass spectrometer of claim 15, wherein said ion beam deflecting means comprises a pair of coreless coils arranged in the direction of said ion beam and so designed as to deflect said ion beam to the same angle but in opposite directions.
Claim 25
Dependent Claim 34 words
The mass spectrometer of claim 15, further including an electrostatic lens arranged between said ion source and said first end face of said magnetic field to converge said ion beam from said ion source.
Claim 26
Dependent Claim 39 words
The mass spectrometer of claim 18, further including another electrostatic lens arranged between said second end face of said magnetic field and said ion detecting means to converge said ion beam to be detected by said ion detecting means.

References Cited (Backward Citations)

FR1115501A Cited
GB957084A Cited
US3641339A Cited
US3840743A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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