Patent US4066809A successfully refreshed from Google Patents.
US4066809A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for preparing substrate surfaces for electroless deposition
Assignee: International Business Machines Corp
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Filing: 1976-06-28
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Granted: 1978-01-03
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Expires: 1996-06-28
Abstract
Abstract A three step seeding process with a hot water rinse and bake includes first contacting the surface of a substrate with a stannous chloride sensitizing solution, followed by a hot water rinse to remove any excess stannous chloride. Next, a palladium chloride activator is used to interact with the stannous compounds to form an adherent layer of metallic palladium particles. Thereafter, the surface is subjected to a palladium chloride/stannous chloride/HCL seeder bath which deposits a final catalytic layer on the surface and drilled through holes to facilitate the electroless plating of a metal of the substrate. A subsequent baking at a temperature between 105° C and 120° C sets the seeder on the substrate surface and in the through holes in the substrate.
Inventors
- 👤 Warren Alan Alpaugh
- 👤 George Joseph Macur
- 👤 Gary Paul Vlasak
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 13:49
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C23C18/28
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
206 words
A method for conditioning the surfaces of a dielectric base material for the electroless plating of a conductive metal thereon, comprising the steps of: contacting the surfaces of the dielectric base material with an aqueous stannous chloride sensitizing solution comprising between 53 and 57 grams per liter of SnCl 2 · 2H 2 O with 37% HCl at a ratio of 50 milliliters per liter; rinsing the excess stannous chloride solution from the surfaces with hot water; contacting the surfaces of the dielectric base material with an aqueous palladium chloride activator solution, said aqueous palladium chloride activator solution formed by mixing about 50 grams of palladium chloride having a concentration of 0.13 to 0.17 grams per liter with approximately 3780 milliliters of 37% hydrochloric acid having a concentration of 10 milliliters per liter; contacting the surfaces of the base material with an aqueous palladium chloride/stannous chloride/hydrochloric acid seeder bath, said palladium chloride/stannous chloride/hydrochloric acid seeder bath comprising from 1.2 to 2.5 grams per liter of PdCl 2 , from 80 to 150 grams per liter of SnCl 2 · 2H 2 O, and from 290 to 360 milliliters per liter of 37% HCl; and, baking the base material at a temperature of at least 105° C.
Claim 2
Independent Claim
206 words
A method for conditioning the surfaces of a dielectric base material for the electroless plating of a conductive metal thereon, comprising the steps of: contacting the surfaces of the dielectric base material with an aqueous stannous chloride sensitizing solution comprising between 53 and 57 grams per liter of SnCl 2 · 2H 2 O with 37% HCl at a ratio of 50 milliliters per liter; rinsing the excess stannous chloride solution from the surfaces with hot water; contacting the surfaces of the dielectric base material with an aqueous palladium chloride activator solution, said aqueous palladium chloride activator solution formed by mixing about 50 grams of palladium chloride having a concentration of 0.13 to 0.17 grams per liter with approximately 3780 milliliters of 37% hydrochloric acid having a concentration of 10 milliliters per liter; contacting the surfaces of the base material with an aqueous palladium chloride/stannous chloride/hydrochloric acid seeder bath, said palladium chloride/stannous chloride/hydrochloric acid seeder bath comprising from 1.2 to 2.5 grams per liter of PdCl 2 , from 80 to 150 grams per liter of SnCl 2 · 2H 2 O, and from 290 to 360 milliliters per liter of 37% HCl; and, baking the base material at a temperature of at least 105° C.
Claim 3
Dependent Claim
24 words
The invention according to claim 1 wherein the temperature of the hot water in the rinsing step is between 55° C and 80° C.
Claim 4
Dependent Claim
20 words
The invention according to claim 1 wherein the temperature for the baking step is between 105° C and 120° C.
Claim 5
Dependent Claim
24 words
The invention according to claim 1 wherein the pH of said stannous chloride sensitizing solution is adjusted to a range between 0.2 and 0.5.
Claim 6
Dependent Claim
18 words
The invention according to claim 4 wherein the pH of the stannous chloride sensitizing solution is about 0.4.
Claim 7
Dependent Claim
22 words
The invention according to claim 4 wherein the temperature of said stannous chloride sensitizing solution is maintained at 65° ± 10° F.
Claim 8
Dependent Claim
20 words
The invention according to claim 1 wherein the pH of said palladium chloride activator solution is between 0.75 and 1.00.
Claim 9
Dependent Claim
22 words
The invention according to claim 7 wherein the temperature of said palladium chloride activator solution is maintained at 65° ± 10° F.
Claim 10
Dependent Claim
48 words
The invention according to claim 1 wherein said seeder bath comprises about 1.5 grams per liter of PdCl 2 , 100 grams per liter of SnCl 2 , 280 milliliters per liter of 37% HCl and said bath is maintained at a temperature of 65° ± 10° F.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-01-02 | 1981-07-04 | 1982-01-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-01-02 | 1985-07-04 | 1986-01-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-01-02 | 1989-07-04 | 1990-01-03 | $7700.00 | Window Closed / Lapsed |