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US4066582A Expired / Lapsed US ⏱️ 0.0 years remaining

Improved acrylate based radiation curable coating compositions containing nitrocellulose

Assignee: Union Carbide Corp
•
Filing: 1976-09-27
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Granted: 1978-01-03
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Expires: 1996-09-27
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Abstract

Abstract Addition of a small amount by weight of nitrocellulose to certain acrylate or methacrylate containing radiation curable coating compositions greatly inhibits penetration of the uncured compositions into porous substrates such as paper or paperboard.

Inventors

  • 👤 Gunther William Babian
  • 👤 Edward Bruce Harris

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 17:24
CPC Classifications
C; C09; C09D; C09D4/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 95 words
In an acrylate or methacrylate-based radiation curable coating composition containing at least 10 weight percent of an oligomeric polyacrylate or polymethacrylate having a molecular weight from 800 to 5,000 and an average of 1 to 8 acrylyl groups per 1,000 molecular weight units, the improvement of having present in said radiation curable coating composition from 0.25 to 9 weight percent of nitrocellulose having a viscosity of 1/4 second to 1/2 second, measured by the falling ball method described in ASTM D301-56(65) and ASTM D1343-56(65), and an average nitrogen content from 10.9 to 12.2 weight percent.
Claim 2
Dependent Claim 95 words
In an acrylate or methacrylate-based radiation curable coating composition containing at least 10 weight percent of an oligomeric polyacrylate or polymethacrylate having a molecular weight from 800 to 5,000 and an average of 1 to 8 acrylyl groups per 1,000 molecular weight units, the improvement of having present in said radiation curable coating composition from 0.25 to 9 weight percent of nitrocellulose having a viscosity of 1/4 second to 1/2 second, measured by the falling ball method described in ASTM D301-56(65) and ASTM D1343-56(65), and an average nitrogen content from 10.9 to 12.2 weight percent.
Claim 3
Dependent Claim 24 words
A radiation curable coating composition as claimed in claim 1, wherein said oligomeric polyacrylate or polymethacrylate has a molecular weight from 1,500 to 2,500.
Claim 4
Dependent Claim 23 words
A radiation curable coating composition as claimed in claim 1, wherein there is present from 1 to 3 weight percent of said nitrocellulose.
Claim 5
Dependent Claim 58 words
A radiation curable coating composition as claimed in claim 1, wherein there is additionally present in the radiation curable coating composition a sufficient amount of phosphoric acid to adjust the pH to between 4.2 and 5.2, measured at a concentration of 10 volume percent of radiation curable coating composition in a 50/50 weight mixture of isopropanol and water.
Claim 6
Dependent Claim 58 words
A radiation curable coating composition as claimed in claim 1, wherein there is additionally present in the radiation curable coating composition a sufficient amount of phosphoric acid to adjust the pH to between 4.9 and 5.2, measured at a concentration of 10 volume percent of radiation curable coating composition in a 50/50 weight mixture of isopropanol and water.
Claim 7
Dependent Claim 47 words
A radiation curable coating composition as claimed in claim 4, wherein there is additionally present in the radiation curable coating composition an alkyl alcohol having from 1 to 4 carbon atoms in an amount from 2.5 to 5 times by weight the amount of phosphoric acid present.
Claim 8
Dependent Claim 47 words
A radiation curable coating composition as claimed in claim 4, wherein there is additionally present in the radiation curable coating composition an alkyl alcohol having from 1 to 4 carbon atoms in an amount from 3 to 4 times by weight the amount of phosphoric acid present.
Claim 9
Dependent Claim 47 words
A radiation curable coating composition as claimed in claim 5, wherein there is additionally present in the radiation curable coating composition an alkyl alcohol having from 1 to 4 carbon atoms in an amount from 2.5 to 5 times by weight the amount of phosphoric acid present.
Claim 10
Dependent Claim 47 words
A radiation curable coating composition as claimed in claim 5, wherein there is additionally present in the radiation curable coating composition an alkyl alcohol having from 1 to 4 carbon atoms in an amount from 3 to 4 times by weight the amount of phosphoric acid present.

References Cited (Backward Citations)

US3770602A Cited
US3749592A Cited
US3840448A Cited
US3912670A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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