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High molecular weight polytriazines of soluble polymeric n-cyano-isourea ethers

Assignee: Bayer AG
•
Filing: 1976-07-22
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Granted: 1978-01-03
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Expires: 1996-07-22
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Abstract

Abstract High molecular weight temperature-resistant polymers of polytriazine structure obtained by heating cyanamides of the formula I r -- (nh-cn).sub.n in which R represents an aliphatic, cycloaliphatic, heterocyclic or aromatic radical, optionally interrupted by oxygen and n is a number from 2 to 5, with polyfunctional, aromatic cyanic acid esters into a fusible or in organic solvents soluble polymeric N-cyano-isourea ether and completing the reaction at elevated temperatures and optionally in the presence of a catalyst to form said polymer of polytriazine structure.

Inventors

  • 👤 Rudolf Sundermann
  • 👤 Gunther Rottloff
  • 👤 Ernst Grigat

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 14:32
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/0622; C08G73/0638; C08G73/065; C08G73/0655

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 65 words
A mixture which can be converted into a high molecular weight polymer of polytriazine structure which is substantially insoluble in solvents, the mixture comprising: A. a cyanamide corresponding to the general formula (I): r (nh-cn).sub.n (I) in which R represents an aliphatic, cycloaliphatic, heterocyclic or aromatic radical optionally interrupted by at least one oxygen atom, and n is a number from 2 to 5, and
Claim 2
Dependent Claim 65 words
A mixture which can be converted into a high molecular weight polymer of polytriazine structure which is substantially insoluble in solvents, the mixture comprising: A. a cyanamide corresponding to the general formula (I): r (nh-cn).sub.n (I) in which R represents an aliphatic, cycloaliphatic, heterocyclic or aromatic radical optionally interrupted by at least one oxygen atom, and n is a number from 2 to 5, and
Claim 3
Dependent Claim 40 words
B. an aromatic cyanic acid ester corresponding to the general formula (II): ar (OCN).sub.p (II) in which Ar represents an aromatic radical or an aromatic radical interrupted by a bridge member and p is a number from 2 to 5.
Claim 4
Dependent Claim 40 words
B. an aromatic cyanic acid ester corresponding to the general formula (II): ar (OCN).sub.p (II) in which Ar represents an aromatic radical or an aromatic radical interrupted by a bridge member and p is a number from 2 to 5.
Claim 5
Dependent Claim 28 words
A mixture as claimed in claim 1, which comprises from 30 to 70 mol % of component A and from 70 to 30 mol % of component B.
Claim 6
Dependent Claim 87 words
A process for the production of a high molecular weight polymer of polytriazine structure, which comprises reacting a mixture as claimed in claim 1, at an elevated temperature, optionally in the presence of a catalyst to form a prepolymer soluble in organic solvents or a fusible prepolymer (polymeric N-cyano-isourea ether), and allowing the prepolymer to react to completion at an elevated temperature and optionally in the presence of a catalyst to form the desired high molecular weight polymer of polytriazine structure which is substantially insoluble in solvents.
Claim 7
Dependent Claim 26 words
A process as claimed in claim 3, wherein the reaction to form the prepolymer is carried out at a temperature of from 30° tp 150° C.
Claim 8
Dependent Claim 19 words
A process as claimed in claim 3, wherein the prepolymer at a temperature of from 150° to 350° C.

References Cited (Backward Citations)

US3130224A Cited
US3308101A Cited
US3694408A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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