US4065368A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Printed circuit cover coating comprising an ultraviolet radiation sensitive acrylic resin
Assignee: AT&T Inc
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Filing: 1976-02-23
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Granted: 1977-12-27
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Expires: 1996-02-23
Abstract
Abstract A flexible photopolymerizable resin is prepared in a two-stage process by the esterification of castor oil which chlorendic anhydride to yield a chlorendic anhydride half ester and the subsequent reaction of the half ester with a reagent having acrylic functionality, a cure retardant and an acrylic functional monomer. The resultant acrylic ester evidences superior insulation resistance during aging.
Inventors
- 👤 Kenneth Allan Holtzman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 17:22
CPC Classifications
C; C09; C09D; C09D151/00; C09D151/08; C08; C08G; C08G63/00; C08G63/68; C08G63/682; H; H05; H05K; H05K3/00; H05K3/22; H05K3/28; H05K3/285; H05K3/287
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
183 words
Method for the preparation of photopolymerizable acrylic resin which comprises the steps of: a. esterifying castor oil with chlorendic anhydride in the presence of an amine catalyst at a temperature within the range of 120°-150° C for a time period ranging from 16-2 hours, the lower temperatures corresponding with the longer reaction times and the converse, so yielding a chlorendic anhydride half ester, b. admixing the resultant ester with a cure retardant, from 5 to 20 parts per 100 parts of resin of an acrylic functional monomer selected from the group consisting of methyl acrylate, butyl acrylate, ethyl hexyl methacrylate, alkyl acrylate, and methyl methacrylate, and a reagent having acrylic functionality, selected from the group consisting of glycidyl acrylate, glycidyl methacrylate and a mixture of glycidyl methacrylate and butyl glycidyl ether, said reagent being employed in an amount sufficient to assure that at least 50% of the carboxyl groups present in the ester system are reacted therewith, so yielding an acrylic ester, and c. exposing the acrylic ester to a source of ultraviolet radiation for a time peroid sufficient to effect curing thereof.
Claim 2
Dependent Claim
183 words
Method for the preparation of photopolymerizable acrylic resin which comprises the steps of: a. esterifying castor oil with chlorendic anhydride in the presence of an amine catalyst at a temperature within the range of 120°-150° C for a time period ranging from 16-2 hours, the lower temperatures corresponding with the longer reaction times and the converse, so yielding a chlorendic anhydride half ester, b. admixing the resultant ester with a cure retardant, from 5 to 20 parts per 100 parts of resin of an acrylic functional monomer selected from the group consisting of methyl acrylate, butyl acrylate, ethyl hexyl methacrylate, alkyl acrylate, and methyl methacrylate, and a reagent having acrylic functionality, selected from the group consisting of glycidyl acrylate, glycidyl methacrylate and a mixture of glycidyl methacrylate and butyl glycidyl ether, said reagent being employed in an amount sufficient to assure that at least 50% of the carboxyl groups present in the ester system are reacted therewith, so yielding an acrylic ester, and c. exposing the acrylic ester to a source of ultraviolet radiation for a time peroid sufficient to effect curing thereof.
Claim 3
Dependent Claim
12 words
Method in accordance with claim 1 wherein said amine catalyst is benzyldimethylamine.
Claim 4
Dependent Claim
19 words
Method in accordance with claim 1 where the reagent is a mixture of glycidyl methacrylate and butyl glycidyl ether.
Claim 5
Dependent Claim
13 words
Method in accordance with claim 1 wherein the monomer is 2-ethyl hexyl methacrylate.
Claim 6
Dependent Claim
15 words
Method in accordance with claim 4 wherein a photosensitizer is added to the acrylic ester.
Claim 7
Dependent Claim
16 words
Method in accordance with claim 4 wherein a flame retardant is added to the acrylic ester.
Claim 8
Dependent Claim
13 words
Method in accordance with claim 5 wherein the photosensitizer is a benzoin ether.
Claim 9
Dependent Claim
10 words
Product prepared in accordance with the method of claim 1.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-12-26 | 1981-06-27 | 1981-12-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-12-26 | 1985-06-27 | 1985-12-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-12-26 | 1989-06-27 | 1989-12-27 | $7700.00 | Window Closed / Lapsed |