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US3907732A Expired / Lapsed US ⏱️ 0.0 years remaining

Paint compositions for indicating irradiation dose

Assignee: Kansai Paint Co Ltd
•
Filing: 1971-02-16
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Granted: 1975-09-23
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Expires: 1991-02-16
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Abstract

Abstract Paint compositions for indicating irradiation dose are prepared from chlorine-combined polyester, 5 to 30 percent by weight of a reductive discoloring substance or a mixture of said substances, and/or 0.005 to 2.0 percent by weight of a reducing dyestuff or a mixture of said dyestuffs, in which said chlorine-combined polyester is obtained by a chlorinated dibasic acid or its anhydride as an acid component or a part of an acid component selected from a group consisting of 3-chlorophthalic acid, 4chlorophthalic acid, dichlorinated phthalic acid, tetrachlorophthalic acid, 1,4,5,6,7,7-hexachlorobicyclo-(2,2,1)5-heptene-2,3-dicarboxylic acid, 4-chloro-4-cyclohexene-1,2dicarboxylic acid and the anhydrides corresponding to said acids.

Inventors

  • 👤 Tsutomu Maruyama
  • 👤 Koichiro Murata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 07:34
CPC Classifications
G; G01; G01N; G01N31/00; G01N31/22; C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/16; C09; C09D; C09D167/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 103 words
PAINT COMPOSITIONS FOR INDICATING IRRIDIATION DOSE COMPRISING: A. A CHLORINE-COMBINED POLYESTER RESIN HAVING AN ACID VALUE OF LESS THAN 40 OBTAINED BY CONDENSING A POLYBASIC ACID COMPONENT COMPRISING MORE THAN 25 MOL PERCENT OF A CHLORINATED DIBASIC ACID COMPONENT COMPRISING MORE THAN 25 MOLE PERCENT BY DIBASIC ACID OR ITS ANHYDRIDE SELECTED FROM THE GROUP CONSISTING OF 3-CHLOROPHTHALIC ACID, 4-CHLOROPHTHALIC ACID, DICHLORINATED PHTHALIC ACID, TETRACHLOROPHTHARIC ACID, 1,4,5,6,7,7-HEXACHLOROBICYCLO(2,2,1)-5-HEPTENE-2,3-DICRBOXYLIC ACID, 4-CHLORO-4CYCLOHEXENE-1,2-DICARBOXYLIC ACID AND ANHYDRIDES CORRESPONDING TO SAID ACIDS WITH GLYCOLS, AND B. 5 TO 30 PERCENT BY WEIGHT OF A REDUCTIVE DISCOLORING SUBSTANCE AND C. 0.005 TO 2.0 PERCENT BY WEIGHT OF A REDUCING DYESTUFF.
Claim 2
Dependent Claim 103 words
PAINT COMPOSITIONS FOR INDICATING IRRIDIATION DOSE COMPRISING: A. A CHLORINE-COMBINED POLYESTER RESIN HAVING AN ACID VALUE OF LESS THAN 40 OBTAINED BY CONDENSING A POLYBASIC ACID COMPONENT COMPRISING MORE THAN 25 MOL PERCENT OF A CHLORINATED DIBASIC ACID COMPONENT COMPRISING MORE THAN 25 MOLE PERCENT BY DIBASIC ACID OR ITS ANHYDRIDE SELECTED FROM THE GROUP CONSISTING OF 3-CHLOROPHTHALIC ACID, 4-CHLOROPHTHALIC ACID, DICHLORINATED PHTHALIC ACID, TETRACHLOROPHTHARIC ACID, 1,4,5,6,7,7-HEXACHLOROBICYCLO(2,2,1)-5-HEPTENE-2,3-DICRBOXYLIC ACID, 4-CHLORO-4CYCLOHEXENE-1,2-DICARBOXYLIC ACID AND ANHYDRIDES CORRESPONDING TO SAID ACIDS WITH GLYCOLS, AND B. 5 TO 30 PERCENT BY WEIGHT OF A REDUCTIVE DISCOLORING SUBSTANCE AND C. 0.005 TO 2.0 PERCENT BY WEIGHT OF A REDUCING DYESTUFF.
Claim 3
Dependent Claim 61 words
Paint compositions for indicating irradiation dose according to claim 1, in which said polyester resin is further modified by less than 15 percent by weight of monobasic acid selected from the group consisting of coconut oil, cotton seed oil, soyabean oil, rice oil, safflower oil and their fatty acids, aliphatic monobasic acids having 8 to 18 carbon atoms, and mixture thereof.
Claim 4
Dependent Claim 68 words
Paint compositions for indicating irradiation dose according to claim 2, in which said aliphatic monobasic acids are at least one member selected from the group consisting of caprylic acid, pelargonic acid, capric acid, undecylic acid, lauric acid, tridecyclic acid, myristic acid, pentadecylic acid, palmitic acid, heptadecylic acid, stearic acid, lauroleic acid, myristoleic acid, palmitoleic acid, oleic acid, recinoleic acid, linoleic acid, linolenic acid, eleostearic acid and licanic acid.
Claim 5
Dependent Claim 49 words
Paint compositions for indicating irradiation dose according to claim 1, in which said polybasic acid component comprises at least one member selected from the group consisting of phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, succinic acid, maleic acid, adipic acid, azeraic acid, sebacic acid, and acid anhydrides thereof.
Claim 6
Dependent Claim 57 words
Paint compositions for indicating irradiation dose according to claim 1, in which said glycols include at least one member selected from the group consisting of ethylene glycol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 2,3-pentanediol, threo-2,3-pentanediol, erythro-2,3-pentanediol, 3-methyl-1,2-butanediol, trimethylene glycol, Beta -butylene glycol, 2,4-pentanediol, 2,2-dimethyltrimethylene glycol, 2,2-dimethyl-1,3-butanediol, 2,2-dimethyl-1,3-pentanediol, tetramethylene glycol, 1,4-pentanediol, 3-methyl-2,5-pentanediol, 1,4-hexanediol, 2,5-hexanediol, pentamethylene glycol, 1,5-hexanediol and hexamethylene glycol.
Claim 7
Dependent Claim 41 words
Paint compositions for indicating the irradiation dose according to claim 1, in which said chlorine-combined polyester resin is obtained by condensing a mixture comprising 1.0 mol of carboxylic group of acid and 1.0 to 1.2 mol of hydroxyl group of glycol.
Claim 8
Dependent Claim 34 words
Paint compositions for indicating irradiation dose according to claim 1, in which said reductive discoloring substance includes at least one member selected from the group consisting of cobalt naphthenate, cobalt octenate and iron naphthenate.
Claim 9
Dependent Claim 33 words
Paint compositions for indicating irradiation dose according to claim 1, in which said reducing dyestuff includes one member selected from the group consisting of benzene-azonaphthylamine, paradiethylaminoazobenzene, Aniline Boue, Aniline Yellow and Indigo Carmine.

References Cited (Backward Citations)

US2873210A Cited
US2979472A Cited
US3290499A Cited
US3471422A Cited
US3390121A Cited
US3527722A Cited
US3488305A Cited
US3536916A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-22 1979-03-24 1979-09-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-22 1983-03-24 1983-09-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-22 1987-03-24 1987-09-23 $7700.00 Window Closed / Lapsed

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