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US4063880A Expired / Lapsed US ⏱️ 0.0 years remaining

Concentrated disazo dye-surfactant solution

Assignee: EIDP Inc
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Filing: 1975-11-06
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Granted: 1977-12-20
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Expires: 1995-11-06
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Abstract

Abstract An improved aqueous-organic solvent solution, having a pH between 10 and 13, of the disazo dye ##STR1## wherein X is a cation, preferably the sodium or lithium cation, having therein a combination of I. 0.1% to 10%, by total weight, of a particular anionic surfactant, and Ii. 0.1% to 10.0%, by total weight, of a particular nonionic surfactant.

Inventors

  • 👤 Victor Tullio

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 03:31
CPC Classifications
C; C09; C09B; C09B31/00; C09B31/02; C09B31/06; C09B31/061; C09B31/068; C09B31/072; C09B67/00; C09B67/0071; C09B67/0072; C09B67/0073; D; D06; D06P; D06P1/00; D06P1/39; D06P1/90; D06P1/92; D06P1/928; Y; Y10; Y10S; Y10S8/00; Y10S8/904; Y10S8/905; Y10S8/908; Y10S8/912; Y10S8/937

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 300 words
An improved aqueous-organic solvent solution having a pH between 10 and 13, of the disazo dye ##STR7## wherein X is a cation selected from the group sodium, potassium, lithium, and ammonium, the improvement comprising the presence in the dye solution of a combination of i. 0.1% to 10.0%, by total weight, of an anionic surfactant, and ii. 0.1% to 10.0%, by total weight, of a nonionic surfactant, the ratio of anionic surfactant to nonionic surfactant being between 1 to 20 and 17 to 1, the dye solutin having a dye concentration in the range of 15% to 25% based on the total weight of the solution, said solution being nongelling upon dilution with water, the anionic surfactant being a water-soluble salt of at least one member of the group consisting of substituted benzenesulfonic acid salt, substituted naphthalenesulfonic acid salt, and sulfonated naphthaleneformaldehyde condensate salt, the nonionic surfactant being selected from at least one member of the group consisting of condensates of a. C 4 to C 24 alkyl primary amines and at least 5 moles of propylene oxide, b. C 4 to C 24 alkyl primary amines and at least 5 moles of ethylene oxide, c. C 12 to C 24 alcohols and at least 15 moles of ethylene oxide, d. C 12 to C 24 alcohols and at least 5 moles of propylene oxide, e. C 4 to C 24 alcohols and at least 8 moles of ethylene oxide and 2 moles of propylene oxide, f. alkyl phenols and at least 8 moles of ethylene oxide, and g. ethylene oxide and polypropylene ether glycol which is derived from propylene glycol and propylene oxide said glycol having a molecular weight from about 1,000 to 10,000, said condensate having a proportion derived from ethylene oxide of 20 to 80 weight percent.
Claim 2
Dependent Claim 300 words
An improved aqueous-organic solvent solution having a pH between 10 and 13, of the disazo dye ##STR7## wherein X is a cation selected from the group sodium, potassium, lithium, and ammonium, the improvement comprising the presence in the dye solution of a combination of i. 0.1% to 10.0%, by total weight, of an anionic surfactant, and ii. 0.1% to 10.0%, by total weight, of a nonionic surfactant, the ratio of anionic surfactant to nonionic surfactant being between 1 to 20 and 17 to 1, the dye solutin having a dye concentration in the range of 15% to 25% based on the total weight of the solution, said solution being nongelling upon dilution with water, the anionic surfactant being a water-soluble salt of at least one member of the group consisting of substituted benzenesulfonic acid salt, substituted naphthalenesulfonic acid salt, and sulfonated naphthaleneformaldehyde condensate salt, the nonionic surfactant being selected from at least one member of the group consisting of condensates of a. C 4 to C 24 alkyl primary amines and at least 5 moles of propylene oxide, b. C 4 to C 24 alkyl primary amines and at least 5 moles of ethylene oxide, c. C 12 to C 24 alcohols and at least 15 moles of ethylene oxide, d. C 12 to C 24 alcohols and at least 5 moles of propylene oxide, e. C 4 to C 24 alcohols and at least 8 moles of ethylene oxide and 2 moles of propylene oxide, f. alkyl phenols and at least 8 moles of ethylene oxide, and g. ethylene oxide and polypropylene ether glycol which is derived from propylene glycol and propylene oxide said glycol having a molecular weight from about 1,000 to 10,000, said condensate having a proportion derived from ethylene oxide of 20 to 80 weight percent.
Claim 3
Dependent Claim 103 words
The dye solution of claim 1 wherein the nonionic surfactant is selected from at least one member of the group consisting of condensates of b. C 4 to C 24 alkyl primary amines and at least 5 moles of ethylene oxide, e. C 4 to C 24 alcohols and at least 8 moles of ethylene oxide and 2 moles of propylene oxide, and g. ethylene oxide and polypropylene ether glycol derived from propylene glycol and propylene oxide said glycol having a molecular weight from about 1,000 to 10,000, said condensate having a proportion derived from ethylene oxide of 20 to 80 weight percent.
Claim 4
Dependent Claim 44 words
The dye solution of claim 2 wherein the nonionic surfactant is (b), said surfactant being a condensate of about 50 moles of ethylene oxide per mole of amine, said amine being essentially a mixture of C 16 and C 18 straight chain saturated amines.
Claim 5
Dependent Claim 22 words
The dye solution of claim 3 wherein the nonionic surfactant is C 16-18 H 33-37 NH(CH 2 CH 2 O) 50 H.
Claim 6
Dependent Claim 35 words
The dye solution of claim 2 wherein the nonionic surfactant is (g), said surfactant having a molecular weight of said glycol of about 1200 and a proportion derived from ethylene oxide of 20 weight percent.
Claim 7
Dependent Claim 12 words
The dye solution of claim 1 wherein the anionic surfactant is ##STR8##
Claim 8
Dependent Claim 12 words
The dye solution of claim 2 wherein the anionic surfactant is ##STR9##
Claim 9
Dependent Claim 12 words
The dye solution of claim 3 wherein the anionic surfactant is ##STR10##
Claim 10
Dependent Claim 12 words
The dye solution of claim 4 wherein the anionic surfactant is ##STR11##
Claim 11
Dependent Claim 12 words
The dye solution of claim 5 wherein the anionic surfactant is ##STR12##
Claim 12
Dependent Claim 63 words
The dye solution of claim 6 wherein the nonionic surfactant is C 16-18 h 33-37 nh(ch 2 ch 2 o) 50 h, and the condensate of ethylene oxide and polypropylene ether glycol which is derived from propylene glycol and propylene oxide said glycol having a molecular weight of about 1200, said condensate having a proportion derived from ethylene oxide of 20 weight percent.

References Cited (Backward Citations)

US3203753A Cited
US3153564A Cited
US3288552A Cited
US3622264A Cited
US3658456A Cited
US3957425A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-12-19 1981-06-20 1981-12-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-12-19 1985-06-20 1985-12-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-12-19 1989-06-20 1989-12-20 $7700.00 Window Closed / Lapsed

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