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US4061700A Expired / Lapsed US ⏱️ 0.0 years remaining

Fugitive binder for nuclear fuel materials

Assignee: General Electric Co
•
Filing: 1975-09-10
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Granted: 1977-12-06
•
Expires: 1995-09-10
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Abstract

Abstract A process for fabricating a body of a nuclear fuel material has the steps of admixing the nuclear fuel material in powder form with a binder of a compound or its hydration products containing ammonium cations and anions selected from the group consisting of carbonate anions, bicarbonate anions, carbamate anions and mixtures of such anions, forming the resulting mixture into a green body such as by die pressing, heating the green body to decompose substantially all of the binder into gases, further heating the body to produce a sintered body, and cooling the sintered body in a controlled atmosphere. Preferred binders used in the practice of this invention include ammonium bicarbonate, ammonium carbonate, ammonium bicarbonate carbamate, ammonium sesquicarbonate, ammonium carbamate and mixtures thereof. This invention includes a composition of matter in the form of a compacted structure suitable for sintering comprising a mixture of a nuclear fuel material and a binder of a compound or its hydration products containing ammonium cations and anions selected from the group consisting of carbonate anions, bicarbonate anions, carbamate anions and mixtures of such anions.

Inventors

  • 👤 Timothy Joseph Gallivan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 14:04
CPC Classifications
G; G21; G21C; G21C3/00; G21C3/42; G21C3/58; G21C3/62; G21C3/623; Y; Y02; Y02E; Y02E30/00; Y02E30/30

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 169 words
A process for sintering a body of nuclear fuel material comprising the steps of a. admixing the nuclear fuel material in a particulate form with a binder having a particle size less than 400 mesh so as to achieve a uniform dispersal of said binder in the nuclear fuel material so that said binder and said nuclear fuel material undergo adhesion, said binder being comprised of ammonium bicarbonate, ammonium bicarbonate carbamate, ammonium sesquicarbonate, ammonium carbamate and mixtures thereof, b. forming the resulting mixture by pressing into a green body having a density ranging from about 30% to about 70% of theoretical density, c. heating said green body at a temperature sufficient to decompose substantially all of the binder into gases that enter an atmosphere maintained over said green body, d. heating the body at a temperature sufficient to produce a sintered body and further decompose any binder residues that enter the atmosphere maintained over said body, and e. cooling the sintered body in the atmosphere maintained over said body.
Claim 2
Dependent Claim 169 words
A process for sintering a body of nuclear fuel material comprising the steps of a. admixing the nuclear fuel material in a particulate form with a binder having a particle size less than 400 mesh so as to achieve a uniform dispersal of said binder in the nuclear fuel material so that said binder and said nuclear fuel material undergo adhesion, said binder being comprised of ammonium bicarbonate, ammonium bicarbonate carbamate, ammonium sesquicarbonate, ammonium carbamate and mixtures thereof, b. forming the resulting mixture by pressing into a green body having a density ranging from about 30% to about 70% of theoretical density, c. heating said green body at a temperature sufficient to decompose substantially all of the binder into gases that enter an atmosphere maintained over said green body, d. heating the body at a temperature sufficient to produce a sintered body and further decompose any binder residues that enter the atmosphere maintained over said body, and e. cooling the sintered body in the atmosphere maintained over said body.
Claim 3
Dependent Claim 32 words
A process according to claim 1 in which the admixing step is conducted to give from about 0.5 to about 7.0 weight percent binder in the mixture with the nuclear fuel material.
Claim 4
Dependent Claim 20 words
A process according to claim 1 in which the nuclear fuel material is comprised of uranium dioxide and plutonium dioxide.
Claim 5
Dependent Claim 15 words
A process according to claim 1 in which the nuclear fuel material is uranium dioxide.
Claim 6
Dependent Claim 13 words
A process according to claim 1 in which the binder is ammonium bicarbonate.
Claim 7
Dependent Claim 14 words
A process according to claim 1 in which the binder is ammonium bicarbonate carbamate.
Claim 8
Dependent Claim 15 words
A process according to claim 1 in which the nuclear fuel material is uranium oxide.
Claim 9
Dependent Claim 13 words
A process according to claim 1 in which the binder is ammonium sesquicarbonate.
Claim 10
Dependent Claim 13 words
A process according to claim 1 in which the binder is ammonium carbamate.

References Cited (Backward Citations)

US3330889A Cited
US3312631A Cited
US3345437A Cited
US3728421A Cited
US3812050A Cited
US3953286A Cited
US3963828A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-12-05 1981-06-06 1981-12-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-12-05 1985-06-06 1985-12-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-12-05 1989-06-06 1989-12-06 $7700.00 Window Closed / Lapsed

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